公开(公告)号：US10086365B2

公开(公告)日：2018-10-02

申请号：US12198459

申请日：2008-08-26

申请人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard A. Bley ,  Jesse W. Taylor ,  Sara L. Rolfe ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard A. Bley ,  Jesse W. Taylor ,  Sara L. Rolfe ,  Harold A. Wright

IPC分类号： B01J37/03 ,  B01J23/78 ,  B01J21/00 ,  C10G2/00 ,  B01J21/08

摘要： A method of strengthening a precipitated unsupported iron catalyst by: preparing a precipitated unsupported iron catalyst containing copper and potassium; adding a solution comprising a structural promoter to the previously prepared catalyst; drying the mixture; and calcining the dried catalyst. A method for preparing an iron catalyst, the method comprising: precipitating a catalyst precursor comprising iron phases selected from hydroxides, oxides, and carbonates; adding a promoter to the catalyst precursor to yield a promoted precursor; drying the promoted precursor to yield dried catalyst; and calcining the dried catalyst, wherein the catalyst further comprises copper and potassium. A method of preparing a strengthened precipitated iron catalyst comprising: co-precipitating iron, copper, magnesium, and aluminum; washing the precipitate; alkalizing the precipitate; and drying the precipitate to yield a dried catalyst precursor. The dried catalyst precursor may be calcined and treated with a gas comprising carbon monoxide.

公开(公告)号：US20090062108A1

公开(公告)日：2009-03-05

申请号：US12198459

申请日：2008-08-26

申请人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard A. Bley ,  Jesse W. Taylor ,  Sara L. Rolfe ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard A. Bley ,  Jesse W. Taylor ,  Sara L. Rolfe ,  Harold A. Wright

IPC分类号： B01J23/72 ,  B01J21/06 ,  B01J23/02 ,  B01J31/28

CPC分类号： B01J23/78 ,  B01J21/005 ,  B01J21/08 ,  B01J37/03 ,  C10G2/331 ,  C10G2300/70

摘要： A method of strengthening a precipitated unsupported iron catalyst by: preparing a precipitated unsupported iron catalyst containing copper and potassium; adding a solution comprising a structural promoter to the previously prepared catalyst; drying the mixture; and calcining the dried catalyst.A method for preparing an iron catalyst, the method comprising: precipitating a catalyst precursor comprising iron phases selected from hydroxides, oxides, and carbonates; adding a promoter to the catalyst precursor to yield a promoted precursor; drying the promoted precursor to yield dried catalyst; and calcining the dried catalyst, wherein the catalyst further comprises copper and potassium.A method of preparing a strengthened precipitated iron catalyst comprising: co-precipitating iron, copper, magnesium, and aluminum; washing the precipitate; alkalizing the precipitate; and drying the precipitate to yield a dried catalyst precursor. The dried catalyst precursor may be calcined and treated with a gas comprising carbon monoxide.

摘要翻译： 一种通过以下方法强化沉淀的无载体铁催化剂：制备沉淀的含铜和钾的无载体铁催化剂; 向先前制备的催化剂中加入包含结构促进剂的溶液; 干燥混合物; 并煅烧干燥的催化剂。 一种制备铁催化剂的方法，所述方法包括：沉淀包含选自氢氧化物，氧化物和碳酸盐的铁相的催化剂前体; 向催化剂前体中加入促进剂以产生促进的前体; 干燥促进的前体以产生干燥的催化剂; 并煅烧所述干燥的催化剂，其中所述催化剂还包含铜和钾。 一种制备强化沉淀铁催化剂的方法，包括：共沉淀铁，铜，镁和铝; 洗涤沉淀物; 使沉淀物碱化; 并干燥沉淀物，得到干燥的催化剂前体。 干燥的催化剂前体可以被煅烧并用包含一氧化碳的气体处理。

公开(公告)号：US07879756B2

公开(公告)日：2011-02-01

申请号：US12189424

申请日：2008-08-11

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

摘要翻译： 公开了一种生产用于催化一氧化碳氢化的铁催化剂的方法。 该方法包括与某些先前的方法相比，使用减少量的铁进行铁溶解。 将所得酸性铁混合物加热而不沸腾，得到Fe2 + :Fe3 +比率在约0.01％：99.99％至约100％:0％（wt：wt）范围内的硝酸盐溶液。 与某些先前的方法相比，铁相在较低温度下沉淀。 将回收的催化剂前体干燥并定尺寸以形成尺寸分布在10微米至100微米之间的颗粒。 在实施方案中，硝酸溶液中的Fe 2+：Fe 3+比可以在约3％：97％至约30％:70％（wt：wt）的范围内，并且煅烧的催化剂可以包含磁赤铁矿：赤铁矿 约1％：99％至约70％：30％。

公开(公告)号：US08138115B2

公开(公告)日：2012-03-20

申请号：US12713358

申请日：2010-02-26

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： B01J23/00

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

摘要翻译： 公开了一种生产用于催化一氧化碳氢化的铁催化剂的方法。 该方法包括与某些先前的方法相比，使用减少量的铁进行铁溶解。 将所得酸性铁混合物加热而不沸腾，得到Fe2 + :Fe3 +比率在约0.01％：99.99％至约100％:0％（wt：wt）范围内的硝酸盐溶液。 与某些先前的方法相比，铁相在较低温度下沉淀。 将回收的催化剂前体干燥并定尺寸以形成尺寸分布在10微米至100微米之间的颗粒。 在实施方案中，硝酸溶液中的Fe 2+：Fe 3+比可以在约3％：97％至约30％:70％（wt：wt）的范围内，并且煅烧的催化剂可以包含磁赤铁矿：赤铁矿 约1％：99％至约70％：30％。

公开(公告)号：US07968611B2

公开(公告)日：2011-06-28

申请号：US12713807

申请日：2010-02-26

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： C07C27/00 ,  B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%: 99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

摘要翻译： 公开了一种生产用于催化一氧化碳氢化的铁催化剂的方法。 该方法包括与某些先前的方法相比，使用减少量的铁进行铁溶解。 将所得酸性铁混合物加热而不沸腾，得到Fe2 + :Fe3 +比率在约0.01％：99.99％至约100％:0％（wt：wt）范围内的硝酸盐溶液。 与某些先前的方法相比，铁相在较低温度下沉淀。 将回收的催化剂前体干燥并定尺寸以形成尺寸分布在10微米至100微米之间的颗粒。 在实施方案中，硝酸溶液中的Fe 2+：Fe 3+比可以在约3％：97％至约30％:70％（wt：wt）的范围内，并且煅烧的催化剂可以包含磁赤铁矿：赤铁矿 约1％：99％至约70％：30％。

公开(公告)号：US20100152036A1

公开(公告)日：2010-06-17

申请号：US12713358

申请日：2010-02-26

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： B01J23/745 ,  B01J23/72

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

摘要翻译： 公开了一种生产用于催化一氧化碳氢化的铁催化剂的方法。 该方法包括与某些先前的方法相比，使用减少量的铁进行铁溶解。 将所得酸性铁混合物加热而不沸腾，得到Fe2 + :Fe3 +比率在约0.01％：99.99％至约100％:0％（wt：wt）范围内的硝酸盐溶液。 与某些先前的方法相比，铁相在较低温度下沉淀。 将回收的催化剂前体干燥并定尺寸以形成尺寸分布在10微米至100微米之间的颗粒。 在实施方案中，硝酸溶液中的Fe 2+：Fe 3+比可以在约3％：97％至约30％:70％（wt：wt）的范围内，并且煅烧的催化剂可以包含磁赤铁矿：赤铁矿 约1％：99％至约70％：30％。

公开(公告)号：US20090069451A1

公开(公告)日：2009-03-12

申请号：US12189424

申请日：2008-08-11

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： C07C27/06 ,  B01J23/72

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

摘要翻译： 公开了一种生产用于催化一氧化碳氢化的铁催化剂的方法。 该方法包括与某些先前的方法相比，使用减少量的铁进行铁溶解。 将所得酸性铁混合物加热而不沸腾，得到Fe2 + :Fe3 +比率在约0.01％：99.99％至约100％:0％（wt：wt）范围内的硝酸盐溶液。 与某些先前的方法相比，铁相在较低温度下沉淀。 将回收的催化剂前体干燥并定尺寸以形成尺寸分布在10微米至100微米之间的颗粒。 在实施方案中，硝酸溶液中的Fe 2+：Fe 3+比可以在约3％：97％至约30％:70％（wt：wt）的范围内，并且煅烧的催化剂可以包含磁赤铁矿：赤铁矿 约1％：99％至约70％：30％。

公开(公告)号：US20100152307A1

公开(公告)日：2010-06-17

申请号：US12713807

申请日：2010-02-26

申请人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Jesse W. Taylor ,  Pandurang V. Nikrad ,  Sara L. Rolfe ,  Olga P. Ionkina ,  Dawid J. Duvenhage ,  Harold A. Wright

IPC分类号： C07C27/06

CPC分类号： B01J23/78 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/031

摘要： A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.

公开(公告)号：US20090111684A1

公开(公告)日：2009-04-30

申请号：US12272960

申请日：2008-11-18

申请人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard Bley ,  Jesse W. Taylor ,  Bahman Rejai ,  Sara Rolfe ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard Bley ,  Jesse W. Taylor ,  Bahman Rejai ,  Sara Rolfe ,  Harold A. Wright

IPC分类号： B01J23/72 ,  B01J21/06 ,  B01J27/20 ,  B01J31/28 ,  B01J23/02

CPC分类号： B01J37/18 ,  B01J21/08 ,  B01J23/745 ,  B01J23/78 ,  B01J37/03 ,  C10G2/332 ,  C10G2300/4006 ,  C10G2300/703

摘要： A method of activating an iron Fischer-Tropsch catalyst by introducing an inert gas into a reactor comprising a slurry of the catalyst at a first temperature, increasing the reactor temperature from the first temperature to a second temperature at a first ramp rate, wherein the second temperature is in the range of from about 150° C. to 250° C., introducing synthesis gas having a ratio of H2:CO to the reactor at a space velocity, and increasing the reactor temperature from the second temperature to a third temperature at a second ramp rate, wherein the third temperature is in the range of from about 270° C. to 300° C. The iron Fischer-Tropsch catalyst may be a precipitated unsupported iron catalyst, production of which is also provided.

摘要翻译： 一种通过将惰性气体引入反应器中来激活铁费 - 托催化剂的方法，所述反应器包括在第一温度下的催化剂浆料，以第一升高速率将反应器温度从第一温度升至第二温度，其中第二 温度在约150℃至250℃的范围内，以空间速度将具有H 2 :CO比例的合成气引入反应器，并将反应器温度从第二温度升至第三温度 第二斜坡率，其中第三温度在约270℃至300℃的范围内。费 - 托催化剂铁可以是沉淀的未负载的铁催化剂，也提供其生产。

公开(公告)号：US07915193B2

公开(公告)日：2011-03-29

申请号：US12272960

申请日：2008-11-18

申请人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard Bley ,  Jesse W. Taylor ,  Bahman Rejai ,  Sara Rolfe ,  Harold A. Wright

发明人： Belma Demirel ,  Charles B. Benham ,  Dan Fraenkel ,  Richard Bley ,  Jesse W. Taylor ,  Bahman Rejai ,  Sara Rolfe ,  Harold A. Wright

IPC分类号： B01J23/42

CPC分类号： B01J37/18 ,  B01J21/08 ,  B01J23/745 ,  B01J23/78 ,  B01J37/03 ,  C10G2/332 ,  C10G2300/4006 ,  C10G2300/703

摘要： A method of activating an iron Fischer-Tropsch catalyst by introducing an inert gas into a reactor comprising a slurry of the catalyst at a first temperature, increasing the reactor temperature from the first temperature to a second temperature at a first ramp rate, wherein the second temperature is in the range of from about 150° C. to 250° C., introducing synthesis gas having a ratio of H2:CO to the reactor at a space velocity, and increasing the reactor temperature from the second temperature to a third temperature at a second ramp rate, wherein the third temperature is in the range of from about 270° C. to 300° C. The iron Fischer-Tropsch catalyst may be a precipitated unsupported iron catalyst, production of which is also provided.

摘要翻译： 一种通过将惰性气体引入反应器中来激活铁费 - 托催化剂的方法，所述反应器包括在第一温度下的催化剂浆料，以第一升高速率将反应器温度从第一温度升至第二温度，其中第二 温度在约150℃至250℃的范围内，以空间速度将具有H 2 :CO比例的合成气引入反应器，并将反应器温度从第二温度升至第三温度 第二斜坡率，其中第三温度在约270℃至300℃的范围内。费 - 托催化剂铁可以是沉淀的未负载的铁催化剂，也提供其生产。