Diphosphines containing silane groups, immobilized diphosphines and the
use thereof as hydrogenation catalysts
    3.
    发明授权
    Diphosphines containing silane groups, immobilized diphosphines and the use thereof as hydrogenation catalysts 失效
    含有硅烷基团的二膦,固定化二膦及其作为氢化催化剂的用途

    公开(公告)号:US5306853A

    公开(公告)日:1994-04-26

    申请号:US78696

    申请日:1993-06-17

    摘要: Compounds of formula II ##STR1## wherein the groups (R.sub.1).sub.2 P(CH.sub.2).sub.m bzw.n are in o- or m-position to each other and the substituents R.sub.1 are identical or different radicals, m and n are each independently of the other 0 or 1, R.sub.1 is linear or branched C.sub.1 -C.sub.12 alkyl, unsubstituted C.sub.5 -C.sub.6 cycloalkyl or C.sub.5 -C.sub.6 cycloalkyl which is substituted by C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, or is phenyl or benzyl, or both substituents R.sub.1 in a group (R.sub.1).sub.2 P together are o,o'-diphenylene, --R.sub.2 --X-- is a bond or --(C.sub.x H.sub.2x --O).sub.y --, or X-- is O-- and R.sub.2 is C.sub.1 -C.sub.6 alkylene, x is an integer from 2 to 6 and y is an integer from 2 to 6, R.sub.3 is C.sub.2 -C.sub.18 alkylene, phenylene or benzylene, and R.sub.4 is C.sub.1 -C.sub.6 alkyl or phenyl, can be applied to solid carriers, such as silica gel or aerosils, and complexed with rhodium or iridium compounds. These materials are heterogeneous and separable catalysts for the asymmetrical hydrogenation of prochiral compounds containing carbon double bonds or carbon/hetero atom double bonds, for example ketones and imines.

    摘要翻译: 式(II)化合物其中基团(R 1)2 P(CH 2)m bzw.n彼此是邻位或间位,取代基R 1是相同或不同的基团,m和n各自为 独立于另一个0或1,R 1是被C 1 -C 4烷基或C 1 -C 4烷氧基取代的直链或支链C 1 -C 12烷基,未被取代的C 5 -C 6环烷基或C 5 -C 6环烷基,或者是苯基或苄基,或两个基团中的两个取代基R 1 (R1)2P一起为o,邻二亚苯基,-R2-X-为键或 - (CxH2x-O)y-或X-为O-,R2为C1-C6亚烷基,x为2的整数 至6,y为2至6的整数,R 3为C 2 -C 18亚烷基,亚苯基或亚苯基,且R 4为C 1 -C 6烷基或苯基,可用于固体载体如硅胶或气溶胶,并与铑或 铱化合物。 这些材料是用于不对称氢化含有双键或碳/杂原子双键的前手性化合物的非均相和可分离的催化剂,例如酮和亚胺。

    Diphosphines containing silane groups, immobilise diphosphines and the
use thereof as hydrogenation catalysts
    6.
    发明授权
    Diphosphines containing silane groups, immobilise diphosphines and the use thereof as hydrogenation catalysts 失效
    含有硅烷基团的二羟基磷灰石,硫化二磷酸酯及其作为氢化催化剂的用途

    公开(公告)号:US5244857A

    公开(公告)日:1993-09-14

    申请号:US823517

    申请日:1992-01-21

    摘要: Compounds of formula II ##STR1## wherein the groups (R.sub.1).sub.2 P(CH.sub.2).sub.m and n are in o- or m-position to each other and the substituents R.sub.1 are identical or different radicals, m and n are each independently of the other 0 or 1, R.sub.1 is linear or branched C.sub.1 -C.sub.12 alkyl, unsubstituted C.sub.5 -C.sub.6 cycloalkyl or C.sub.5 -C.sub.6 cycloalkyl which is substituted by C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, or is phenyl or benzyl, or both substituents R.sub.1 in a group (R.sub.1).sub.2 P together are o,o'-diphenylene, --R.sub.2 --X-- is a bond or --(C.sub.x H.sub.2x --O).sub.y --, or X-- is O-- and R.sub.2 is C.sub.1 -C.sub.6 alkylene, x is an integer from 2 to 6 and y is an integer from 2 to 6, R.sub.3 is C.sub.2 -C.sub.18 alkylene, phenylene or benzylene, and R.sub.4 is C.sub.1 -C.sub.6 alkyl or phenyl, can be applied to solid carriers, such as silica gel or aerosils, and complexed with rhodium or iridium compounds. These materials are heterogeneous and separable catalysts for the asymmetrical hydrogenation of prochiral compounds containing carbon double bonds or carbon/hetero atom double bonds, for example ketones and imines.

    摘要翻译: 式(II)化合物其中基团(R 1)2 P(CH 2)m和n彼此相邻或相邻位置,并且取代基R 1是相同或不同的基团,m和n各自独立地为 的另一个0或1,R 1是被C 1 -C 4烷基或C 1 -C 4烷氧基取代的直链或支链C 1 -C 12烷基,未取代的C 5 -C 6环烷基或C 5 -C 6环烷基,或是苯基或苄基,或两个取代基R 1 R1)2P一起是o,o'-二亚苯基,-R 2 -X-是键或 - (C x H 2 O-O)y - ,或X是O-,R 2是C 1 -C 6亚烷基,x是从2到 6,y为2〜6的整数,R3为C2-C18亚烷基,亚苯基或亚苯基,R4为C1-C6烷基或苯基,可用于固体载体如硅胶或气溶胶,并与铑或铱络合 化合物。 这些材料是用于不对称氢化含有双键或碳/杂原子双键的前手性化合物的非均相和可分离的催化剂,例如酮和亚胺。

    Plug-in connector for printed circuits
    7.
    发明授权
    Plug-in connector for printed circuits 失效
    用于印刷电路的插入式连接器

    公开(公告)号:US08043110B2

    公开(公告)日:2011-10-25

    申请号:US12760057

    申请日:2010-04-14

    IPC分类号: H01R4/24

    摘要: A plug connector for printed circuit boards includes a number of contact elements positioned in a housing. The contact elements each have two connection ends and an intermediate contact positioned between the two ends, where one connection end is in the form of an insulation displacement contact for connecting wires. The insulation displacement contacts are supported on the housing, so that the contact elements are held captively in the housing when connection forces act on the insulation displacement contacts.

    摘要翻译: 用于印刷电路板的插头连接器包括定位在壳体中的多个接触元件。 接触元件各自具有两个连接端和位于两端之间的中间触点,其中一个连接端为用于连接导线的绝缘位移触点的形式。 绝缘位移触头支撑在壳体上,使得当连接力作用在绝缘位移触点上时,接触元件被保持在壳体中。

    WIRE TERMINAL BLOCK AND METHOD FOR PRODUCTION OF A WIRE TERMINAL BLOCK WITH GEL FILLER
    8.
    发明申请
    WIRE TERMINAL BLOCK AND METHOD FOR PRODUCTION OF A WIRE TERMINAL BLOCK WITH GEL FILLER 审中-公开
    电线端子块及其制造方法,用于制造带有凝胶填料的电线端子块

    公开(公告)号:US20110130039A1

    公开(公告)日:2011-06-02

    申请号:US12921955

    申请日:2009-01-21

    申请人: Manfred Muller

    发明人: Manfred Muller

    IPC分类号: H01R13/40 H01R43/16

    摘要: The invention relates to a core-connecting terminal strip (1) and to a method for producing a core-connecting terminal strip (1) with gel filling, the core-connecting terminal strip (1) comprising at least one two-part housing (2, 3), in which core connection contacts (5) are arranged, the housing (2, 3) forming cavities, which are filled with a dielectric gel (10), the gel (10) changing its viscosity, the gel (10) being introduced into the housing (2, 3) in at least two temporally separate steps, the time between the steps being selected in such a way that the viscosity of the gel (10) of the preceding step has changed.

    摘要翻译: 本发明涉及一种芯连接端子条(1)和一种用于制造具有凝胶填充物的芯连接端子条(1)的方法,所述芯连接端子条(1)包括至少一个两部分壳体 2,3),其中布置有芯连接触点(5),形成空腔的壳体(2,3)填充有电介质凝胶(10),凝胶(10)改变其粘度,凝胶(10 )在至少两个时间上分离的步骤中引入到壳体(2,3)中,步骤之间的时间被选择为使得前一步骤的凝胶(10)的粘度已经改变。

    Plug-in connector for printed circuits
    9.
    发明授权
    Plug-in connector for printed circuits 失效
    用于印刷电路的插入式连接器

    公开(公告)号:US07717732B2

    公开(公告)日:2010-05-18

    申请号:US11547453

    申请日:2005-03-19

    IPC分类号: H01R4/24

    摘要: The invention relates to a plug-in connector for printed circuits, comprising a plurality of contact elements, whereby said contact elements have two connecting faces each. The one connecting face is configured as an insulation displacement contact for connecting cores and the other connecting face is configured as a tuning fork contact for contacting contact surfaces on a printed circuit. The insulation displacement contacts of the contact elements can be inserted into a plastic housing. At least one lower edge of the insulation displacement contacts is supported on the plastic housing so that the contact elements are captivated in the plastic housing when connecting forces act upon the insulation displacement contacts. The plastic housing comprises at least one chamber-type area. The tuning fork contacts are completely received by the plastic housing in the longitudinal direction. The contact element is configured as a two-part element, a first part of the contact element comprising the insulation displacement contact and the second part comprising the tuning fork contact. One contact arm each is positioned on both parts of the contact element and the two contact arms interact to give a disconnector.

    摘要翻译: 本发明涉及一种用于印刷电路的插入式连接器,包括多个接触元件,由此所述接触元件各具有两个连接面。 一个连接面被配置为用于连接芯的绝缘位移触点,另一个连接面被配置为用于接触印刷电路上的接触表面的音叉触点。 接触元件的绝缘位移触点可插入塑料外壳中。 绝缘位移触点的至少一个下边缘被支撑在塑料外壳上,使得当连接力作用于绝缘位移触点时,接触元件被吸收在塑料外壳中。 塑料外壳包括至少一个室型区域。 音叉接触件由塑料外壳沿纵向完全接收。 接触元件被配置为两部分元件,接触元件的第一部分包括绝缘位移触点,第二部分包括音叉触点。 一个接触臂各自定位在接触元件的两个部分上,并且两个接触臂相互作用以产生隔离开关。

    Low-viscosity, radiation-curable urethane binder dispersions with high solids contents
    10.
    发明申请
    Low-viscosity, radiation-curable urethane binder dispersions with high solids contents 审中-公开
    低粘度,可辐射固化的聚氨酯粘合剂分散体,固体含量高

    公开(公告)号:US20060094819A1

    公开(公告)日:2006-05-04

    申请号:US11264078

    申请日:2005-11-01

    IPC分类号: C08G18/08

    摘要: The present invention relates to water-free and cosolvent-free binder compositions A) containing of a mixture of A1) at least one emulsifier-free, hydrophobic binder containing groups which can be polymerized by high-energy radiation and A2) at least one hydrophilic unsaturated polyester resin containing the reaction product of a) at least one unsaturated dicarboxylic acid and/or an anhydride thereof, b) at least one polyalkylene oxide compound having a number average molecular weight of 106 to 2000, at least 2 hydroxyl end groups and at least 2 oxyalkylene units, wherein at least 50% of the oxyalkylene units are oxyethylene units, and c) at least one hydroxy-functional compound containing at least one polymerizable unsaturated group per molecule selected from vinyl, allyl, methacrylic and acrylic groups. The present invention also relates to aqueous dispersions containing the binder compositions A), to a process for preparing an aqueous dispersion containing the binder dispersion, to a process for diluting the binder composition with tap water, to producing coatings from the aqueous dispersions and to the use of the binder compositions for preparing coating, adhesive or sealant compositions.

    摘要翻译: 本发明涉及无水和无溶剂的粘合剂组合物A),其包含A1)至少一种不含乳化剂的疏水性粘合剂,其含有能够通过高能量辐射聚合的基团和A2)至少一种亲水性 含有a)至少一种不饱和二羧酸和/或其酸酐的反应产物的不饱和聚酯树脂,b)至少一种数均分子量为106至2000的聚环氧烷化合物,至少2个羟基端基和 至少2个氧化烯单元,其中至少50%的氧化烯单元是氧化乙烯单元,和c)至少一种含有至少一个选自乙烯基,烯丙基,甲基丙烯酸和丙烯酸基团的每个分子的可聚合不饱和基团的羟基官能化合物。 本发明还涉及含有粘合剂组合物A)的水分散体,制备含有粘合剂分散体的水性分散体的方法,用于用自来水稀释粘合剂组合物的方法,从水性分散体生产涂料, 使用粘合剂组合物来制备涂料,粘合剂或密封剂组合物。