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    Synthesis of acylarylenes and hyperbranched poly(aclarylene)s by metal-free cyclotrimerization of alkynes
    1.
    发明授权
    Synthesis of acylarylenes and hyperbranched poly(aclarylene)s by metal-free cyclotrimerization of alkynes 有权
    通过不含金属的炔炔环化三聚法合成酰基亚芳基和超支化聚（亚丙烯基）

    公开(公告)号：US08436118B2

    公开(公告)日：2013-05-07

    申请号：US12451527

    申请日：2008-03-04

    申请人： Benzhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Matthias Haeussler ,  Wing Yip Lam

    发明人： Benzhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Matthias Haeussler ,  Wing Yip Lam

    IPC分类号： C08F138/00 ,  C08F38/00 ,  C07C15/00 ,  C07C15/02

    CPC分类号： C08G63/20 ,  C08G63/00

    摘要： The present invention provides a new metal-free cyclotrimerization reaction of alkynes to produce a 1,3,5-triacylarylene or 1,3,5-triacylbenzene. This reaction is catalyzed by secondary amines, is strictly regioselective, highly functionality-tolerant, and the resulting product can be obtained in high yields. This reaction can be further applied for the preparation of novel branched (co)polymers bearing the triacylarylenes as structural units. The preparation of the (co)polymers is carried out as a one-pot single-step reaction procedure, giving branched oligomers and polymers in high yields up to 90%. The produced (co)polymers are also processible, easily film-forming, and thermally stable.

    摘要翻译： 本发明提供了一种新的无金属的炔炔环化三聚反应，产生1,3,5-三酰基亚芳基或1,3,5-三酰基苯。 该反应由仲胺催化，是严格区域选择性的，具有高度的官能度 - 耐受性，所得产物可以高产率获得。 该反应可以进一步用于制备具有三酰基亚芳基作为结构单元的新型支链（共）聚合物。 （共）聚合物的制备是作为一锅一步反应方法进行的，以高产率提供高达90％的支链低聚物和聚合物。 生产的（共）聚合物也是可加工的，容易成膜和热稳定的。

    SYNTHESIS OF ACYLARYLENES AND HYPERBRANCHED POLY(ACLARYLENE)S BY METAL-FREE CYCLOTRIMERIZATION OF ALKYNES
    2.
    发明申请
    SYNTHESIS OF ACYLARYLENES AND HYPERBRANCHED POLY(ACLARYLENE)S BY METAL-FREE CYCLOTRIMERIZATION OF ALKYNES 有权
    通过金属无环烷基化方法合成乙烯和高分子聚（丙烯）

    公开(公告)号：US20100129757A1

    公开(公告)日：2010-05-27

    申请号：US12451527

    申请日：2008-03-04

    申请人： Benzhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Matthias Haeussler ,  Wing Yip Lam

    发明人： Benzhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Matthias Haeussler ,  Wing Yip Lam

    IPC分类号： G03F7/20 ,  C08G63/78 ,  C08G63/00 ,  C08G73/00

    CPC分类号： C08G63/20 ,  C08G63/00

    摘要： The present invention provides a new metal-free cyclotrimerization reaction of alkynes to produce a 1,3,5-triacylarylene or 1,3,5-triacylbenzene. This reaction is catalyzed by secondary amines, is strictly regioselective, highly functionality-tolerant, and the resulting product can be obtained in high yields. This reaction can be further applied for the preparation of novel branched (co)polymers bearing the triacylarylenes as structural units. The preparation of the (co)polymers is carried out as a one-pot single-step reaction procedure, giving branched oligomers and polymers in high yields up to 90%. The produced (co)polymers are also processible, easily film-forming, and thermally stable.

    摘要翻译： 本发明提供了一种新的无金属的炔炔环化三聚反应，产生1,3,5-三酰基亚芳基或1,3,5-三酰基苯。 该反应由仲胺催化，是严格区域选择性的，具有高度的官能度 - 耐受性，所得产物可以高产率获得。 该反应可以进一步用于制备具有三酰基亚芳基作为结构单元的新型支链（共）聚合物。 （共）聚合物的制备是作为一锅一步反应方法进行的，以高产率提供高达90％的支链低聚物和聚合物。 生产的（共）聚合物也是可加工的，容易成膜和热稳定的。

    SULFUR-CONTAINING MACROMOLECULES AND METHODS FOR THEIR PREPARATION
    3.
    发明申请
    SULFUR-CONTAINING MACROMOLECULES AND METHODS FOR THEIR PREPARATION 有权
    含硫的大分子及其制备方法

    公开(公告)号：US20120148958A1

    公开(公告)日：2012-06-14

    申请号：US13391186

    申请日：2010-08-06

    申请人： Benzhong Tang ,  Ka wai Jim ,  Anjun Qin ,  Wing Yip Lam ,  Jianzhao Liu

    发明人： Benzhong Tang ,  Ka wai Jim ,  Anjun Qin ,  Wing Yip Lam ,  Jianzhao Liu

    IPC分类号： C08F128/04 ,  G03F7/20

    CPC分类号： C08G75/025 ,  C08G75/045

    摘要： A sulfur-containing macromolecule and a method of preparing the sulfur-containing macromolecule comprising a polymerization step are provided, where the sulfur-containing macromolecule contains internal units of formula (I) and the polymerization step is formula (II) wherein n is greater than 1, said precursor comprises alkyne having one or more acetylene groups and thiol having one or more thiol groups; and R is remainder of said thiol excluding said thiol groups, R′ is remainder of said alkyne excluding said acetylene groups, and R and R′ are selected from organic or organometallic groups.

    摘要翻译： 提供含硫高分子和制备包含聚合步骤的含硫高分子的方法，其中含硫高分子含有式（I）的内部单元，聚合步骤为式（II），其中n大于 1，所述前体包括具有一个或多个乙炔基的炔烃和具有一个或多个硫醇基团的硫醇; 并且R是除所述硫醇基之外的所述硫醇的剩余部分，R'是除所述乙炔基之外的所述炔烃的剩余部分，R和R'选自有机或有机金属基团。

    Sulfur-containing macromolecules and methods for their preparation
    4.
    发明授权
    Sulfur-containing macromolecules and methods for their preparation 有权
    含硫大分子及其制备方法

    公开(公告)号：US08859698B2

    公开(公告)日：2014-10-14

    申请号：US13391186

    申请日：2010-08-06

    申请人： Benzhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Wing Yip Lam ,  Jianzhao Liu

    发明人： Benzhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Wing Yip Lam ,  Jianzhao Liu

    IPC分类号： C08G12/30 ,  C08G75/04

    CPC分类号： C08G75/025 ,  C08G75/045

    摘要： A sulfur-containing macromolecule and a method of preparing the sulfur-containing macromolecule comprising a polymerization step are provided, where the sulfur-containing macromolecule contains internal units of formula (I) and the polymerization step is formula (II) wherein n is greater than 1, said precursor comprises alkyne having one or more acetylene groups and thiol having one or more thiol groups; and R is remainder of said thiol excluding said thiol groups, R′ is remainder of said alkyne excluding said acetylene groups, and R and R′ are selected from organic or organometallic groups.

    摘要翻译： 提供含硫高分子和制备包含聚合步骤的含硫高分子的方法，其中含硫高分子含有式（I）的内部单元，聚合步骤为式（II），其中n大于 1，所述前体包括具有一个或多个乙炔基的炔烃和具有一个或多个硫醇基团的硫醇; 并且R是除所述硫醇基之外的所述硫醇的剩余部分，R'是除所述乙炔基之外的所述炔烃的剩余部分，R和R'选自有机或有机金属基团。

    Preparation of hyperbranched poly(triazole)s by in situ click polymerization and adhesive containing the same
    5.
    发明授权
    Preparation of hyperbranched poly(triazole)s by in situ click polymerization and adhesive containing the same 有权
    通过原位点击聚合制备超支化聚（三唑），并含有它们的粘合剂

    公开(公告)号：US08524858B2

    公开(公告)日：2013-09-03

    申请号：US12984886

    申请日：2011-01-05

    申请人： Benzhong Tang ,  Youhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Wing Yip Lam ,  Jie Li

    发明人： Benzhong Tang ,  Youhong Tang ,  Ka Wai Jim ,  Anjun Qin ,  Wing Yip Lam ,  Jie Li

    IPC分类号： C08G73/06 ,  C08G73/00

    CPC分类号： C08G73/08 ,  C09J5/02 ,  C09J179/06 ,  C09J2400/163 ,  C09J2400/166 ,  C09J2479/02

    摘要： Provided is a high temperature-resistant metal adhesive containing hyperbranched poly(triazole)s synthesized by in situ azide/alkyne click polymerization. Also provided is a method for preparing the same adhesives by in situ click polymerization of azide and alkyne monomers on metal substrates. The method is optimized to get high adhesive strength at room temperature or elevated temperatures by analyzing the effects of monomer ratio, curing temperature and time, and annealing temperature and time. The hyberbranched poly(triazole)s adhesive has comparable or better temperature resistance compared with known high temperature epoxy metal adhesives, and it is the first high temperature metal adhesive using hyperbranched poly(triazole)s prepared by in situ azide/alkyne click polymerization.

    摘要翻译： 提供含有通过原位叠氮化物/炔烃聚合合成的超支化聚（三唑）的耐高温金属粘合剂。 还提供了通过在金属基底上原位点击叠氮化物和炔单体来制备相同粘合剂的方法。 该方法通过分析单体比例，固化温度和时间以及退火温度和时间的影响，在室温或高温下得到高粘合强度。 与已知的高温环氧金属粘合剂相比，支链聚（三唑）粘合剂具有相当或更好的耐温性，并且是使用通过原位叠氮化物/炔烃聚合制备的超支化聚（三唑）的第一种高温金属粘合剂。

    Luminogen compounds and the use of the same for biosensing and cellular imaging
    7.
    发明授权
    Luminogen compounds and the use of the same for biosensing and cellular imaging 有权
    光亮剂化合物及其用途用于生物传感和细胞成像

    公开(公告)号：US09475768B2

    公开(公告)日：2016-10-25

    申请号：US13422374

    申请日：2012-03-16

    申请人： Benzhong Tang ,  Yang Liu ,  Wing Yip Lam ,  Yong Yu

    发明人： Benzhong Tang ,  Yang Liu ,  Wing Yip Lam ,  Yong Yu

    IPC分类号： C07D207/448 ,  C09B57/00 ,  C07D207/444 ,  C09B69/00

    CPC分类号： C07D207/444 ,  C07D207/448 ,  C09B57/00 ,  C09B69/008 ,  Y10T436/182

    摘要： Provided herein are a luminogen compound of formula (I) including a AIE luminophore moiety conjugated with a maleimide moiety and a use of the same for detecting thiol groups in biomolecules. Also provided is a dye molecule, a biosensor or a bioprobe comprising the luminogen compound of formula (I) in use for detecting thiol groups in biomolecules. The detection method of the present subject matter not only has high thio-selectivity and sensitivity, but also is rapid, convenient and handy.

    摘要翻译： 本文提供式（I）的发光剂化合物，其包含与马来酰亚胺部分缀合的AIE发光体部分，以及用于检测生物分子中的硫醇基团的用途。 还提供了染料分子，生物传感器或生物探针，其包含用于检测生物分子中硫醇基团的式（I）的发光剂化合物。 本发明的检测方法不仅具有高硫选择性和灵敏度，而且快速，方便，方便。

    LUMINOGEN COMPOUNDS AND THE USE OF THE SAME FOR BIOSENSING AND CELLULAR IMAGING
    8.
    发明申请
    LUMINOGEN COMPOUNDS AND THE USE OF THE SAME FOR BIOSENSING AND CELLULAR IMAGING 有权
    发光化合物及其使用与生物传感和细胞成像相同

    公开(公告)号：US20120237964A1

    公开(公告)日：2012-09-20

    申请号：US13422374

    申请日：2012-03-16

    申请人： Benzhong TANG ,  Yang Liu ,  Wing Yip Lam ,  Yong Yu

    发明人： Benzhong TANG ,  Yang Liu ,  Wing Yip Lam ,  Yong Yu

    IPC分类号： G01N21/64 ,  C09B62/343 ,  C07D207/448

    CPC分类号： C07D207/444 ,  C07D207/448 ,  C09B57/00 ,  C09B69/008 ,  Y10T436/182

    摘要： Provided herein are a luminogen compound of formula (I) including a AIE luminophore moiety conjugated with a maleimide moiety and a use of the same for detecting thiol groups in biomolecules. Also provided is a dye molecule, a biosensor or a bioprobe comprising the luminogen compound of formula (I) in use for detecting thiol groups in biomolecules. The detection method of the present subject matter not only has high thio-selectivity and sensitivity, but also is rapid, convenient and handy.

    摘要翻译： 本文提供式（I）的发光剂化合物，其包含与马来酰亚胺部分缀合的AIE发光体部分，以及用于检测生物分子中的硫醇基团的用途。 还提供了染料分子，生物传感器或生物探针，其包含用于检测生物分子中硫醇基团的式（I）的发光剂化合物。 本发明的检测方法不仅具有高硫选择性和灵敏度，而且快速，方便，方便。