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23 条记录 (耗时 0.042 秒)

    Polymerization of C2-C8-alk-1-enes by means of a Ziegler-Natta
    6.
    发明授权
    Polymerization of C2-C8-alk-1-enes by means of a Ziegler-Natta 失效
    通过齐格勒 - 纳塔聚合C2-C8-烷-1-烯的方法

    公开(公告)号：US06174969B1

    公开(公告)日：2001-01-16

    申请号：US09108780

    申请日：1998-07-02

    申请人： Meinolf Kersting ,  Gerald Lutz ,  Franz Langhauser

    发明人： Meinolf Kersting ,  Gerald Lutz ,  Franz Langhauser

    IPC分类号： C08F238

    CPC分类号： C08F297/083 ,  B01J19/1862 ,  B01J19/1881 ,  B01J2219/00103 ,  B01J2219/0011 ,  C08F10/00 ,  C08F10/06 ,  C08F297/08 ,  C08F2/34 ,  C08F2/001

    摘要： C2-C8-Alk-1-enes are polymerized by means of a Ziegler-Natta catalyst system in a reactor cascade comprising at least two reactors, a homo- or copolymer of C2-C8-alk-1-enes being prepared in a reactor RA, upstream of which one or more further reactors may be connected, the reaction mixture being discharged from RA and transferred to a subsequent reactor RB and the polymerization in RB and in the reactors which may be connected to RB being carried out in the presence of a liquid or dissolved regulator for regulating the catalyst activity, by a process in which the regulator is added to the reaction mixture after discharge from RA and before entry into RB, and an apparatus for polymerizing C2-C8-alk-1-enes by means of the novel process is described.

    摘要翻译： C2-C8-烷-1-烯通过齐格勒 - 纳塔催化剂体系在包含至少两个反应器的反应器级联中聚合，在反应器中制备的C2-C8-烷-1-烯的均聚物或共聚物 RA，其上可以连接一个或多个另外的反应器，反应混合物从RA排出并转移到随后的反应器RB中，并且在RB中和可连接到RB的反应器中的聚合在存在下进行 用于调节催化剂活性的液体或溶解的调节剂，其中调节剂在从RA排出之后并且在进入RB之前加入到反应混合物中的方法，以及通过装置聚合C2-C8-烷-1-烯的装置 描述了新颖的方法。

    Random propylene copolymers
    8.
    发明授权
    Random propylene copolymers 失效
    无规丙烯共聚物

    公开(公告)号：US5744567A

    公开(公告)日：1998-04-28

    申请号：US763839

    申请日：1996-12-04

    申请人： Stephan Huffer ,  Meinolf Kersting ,  Franz Langhauser ,  Rainer Alexander Werner ,  Patrik Muller ,  Jurgen Kerth

    发明人： Stephan Huffer ,  Meinolf Kersting ,  Franz Langhauser ,  Rainer Alexander Werner ,  Patrik Muller ,  Jurgen Kerth

    IPC分类号： C08F4/658 ,  C08F4/02 ,  C08F4/64 ,  C08F4/654 ,  C08F210/06 ,  C08F210/16 ,  D01F6/06 ,  C08F10/06

    CPC分类号： C08F210/16 ,  C08F210/06

    摘要： Random propylene copolymers containing copolymerized C.sub.2 -C.sub.10 -alk-1-enes are obtainable by polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C.sub.2 -C.sub.10 -alk-1-enes are polymerized with one another at from 50.degree. to 100.degree. C. at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.

    摘要翻译： 含有共聚的C 2 -C 10 - 烷-1-烯的无规丙烯共聚物可通过丙烯和C 2 -C 10 - 烯-1-烯的齐聚反应获得，该齐格勒 - 纳塔催化剂体系包含含钛的固体组分a） 镁，卤素，硅胶作为载体的化合物和作为电子给体化合物的羧酸酯，以及作为助催化剂的铝化合物b）和另外的电子给体化合物c），其中丙烯和C 2 -C 10 - 烷基 -1-烯烃在50至100℃的压力下彼此聚合，并且平均停留时间为0.5至5小时，并且在含钛固体组分中使用的载体为 平均粒径为5〜200μm，一次粒子的平均粒径为1〜10μm，平均粒径为1〜10μm的空隙或通道的硅胶，其空隙 或通道基于t的体积的宏观比例 他的总粒子在5〜20％的范围内。

    Process for producing improved random propylene copolymers
    9.
    发明授权
    Process for producing improved random propylene copolymers 失效
    制备改进的无规丙烯共聚物的方法

    公开(公告)号：US6013742A

    公开(公告)日：2000-01-11

    申请号：US969278

    申请日：1997-11-13

    申请人： Stephan Huffer ,  Meinolf Kersting ,  Franz Langhauser ,  Rainer Alexander Werner ,  Patrik Muller ,  Jurgen Kerth

    发明人： Stephan Huffer ,  Meinolf Kersting ,  Franz Langhauser ,  Rainer Alexander Werner ,  Patrik Muller ,  Jurgen Kerth

    IPC分类号： C08F4/658 ,  C08F4/02 ,  C08F4/64 ,  C08F4/654 ,  C08F210/06 ,  C08F210/16 ,  D01F6/06 ,  C08F4/18

    CPC分类号： C08F210/16 ,  C08F210/06

    摘要： A process for preparing random propylene copolymers containing copolymerized C.sub.2 -C.sub.10 -alk-1-enes by polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C.sub.2 -C.sub.10 -alk-1-enes are polymerized with one another at from 50 to 100.degree. C. at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.

    摘要翻译： 在含有含钛固体组分a的齐格勒 - 纳塔催化剂体系存在下，通过丙烯和C 2 -C 10 - 烷-1-烯的聚合制备含共聚的C 2 -C 10 - 烷-1-烯的无规丙烯共聚物的方法 ），其包含镁，卤素，硅胶作为载体的化合物和作为电子给体化合物的羧酸酯，以及作为助催化剂的铝化合物b）和另外的电子给体化合物c），其中丙烯和C 2 -C 10 α-烷-1-烯在50至100℃下以15至40巴的压力和0.5至5小时的平均停留时间彼此聚合，并且在含钛固体组分中使用的载体 是平均粒径为5〜200μm，一次粒子的平均粒径为1〜10μm，平均粒径为1〜10μm的通道的硅胶，其中， 空隙或通道具有基于体积的宏观比例 总颗粒在5至20％的范围内。

    Random propylene copolymers
    10.
    发明授权
    Random propylene copolymers 有权
    无规丙烯共聚物

    公开(公告)号：US07026421B2

    公开(公告)日：2006-04-11

    申请号：US10971079

    申请日：2004-10-25

    申请人： David Appleyard ,  Franz Langhauser ,  Murray Horton ,  Roland Hingmann ,  Günther Schweier ,  Volker Rauschenberger ,  Ingolf Hennig ,  Dieter Lilge ,  Werner Schöne ,  Meinolf Kersting

    发明人： David Appleyard ,  Franz Langhauser ,  Murray Horton ,  Roland Hingmann ,  Günther Schweier ,  Volker Rauschenberger ,  Ingolf Hennig ,  Dieter Lilge ,  Werner Schöne ,  Meinolf Kersting

    IPC分类号： C08F210/06 ,  C08F210/08

    CPC分类号： D01F6/30 ,  C08F210/06 ,  C08F210/16 ,  Y10T428/31938 ,  C08F4/6546 ,  C08F210/08 ,  C08F2500/12

    摘要： Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4–C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4–C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.

    摘要翻译： 丙烯与具有至多碳原子的其它1-烯烃的无规共聚物，如果丙烯共聚物中存在的共聚单体中唯一的共聚单体为共聚单体，其共聚单体的含量为0.7-1.4重量％，或其共聚单体的含量为 如果至少一个C 4 -C 10 - 1-烯烃作为共聚单体存在，其冷二甲苯可溶成分为 如果乙烯作为丙烯共聚物中的共聚单体存在，则其重量为1.0至2.5重量％，或者如果仅存在共聚单体为C 4 - 4，则冷二甲苯可溶成分为0.75-2.0重量％ 描述了用于制备膜，纤维或模制品的方法，以及薄膜，纤维和模制品本身以及双轴的方法制备丙烯的无规共聚物的方法。 由这种类型的无规丙烯共聚物制成的拉伸薄膜及其生产方法。