Catalyst systems of the Ziegler-Natta type
    9.
    发明授权
    Catalyst systems of the Ziegler-Natta type 失效
    齐格勒 - 纳塔型催化剂系统

    公开(公告)号:US06200922B1

    公开(公告)日:2001-03-13

    申请号:US08869761

    申请日:1997-06-05

    IPC分类号: B01J2106

    摘要: The catalyst systems comprise as active constituents a) a titanium-containing solid component comprising a compound of titanium, a compound of magnesium, a halogen, an inorganic oxide as support and a carboxylic ester as electron donor compound, and also, as cocatalyst, b) an aluminum compound and c) optionally a further electron donor compound, wherein the inorganic oxide used has a pH of from 1 to 6, an average particle diameter of from 5 to 200 &mgr;m, an average primary particle diameter of from 1 to 20 &mgr;M and voids or channels having an average diameter of from 0.1 to 20 &mgr;m and a macroscopic share of the volume of the overall particle within the range from 5 to 30%.

    摘要翻译: 催化剂体系包括作为活性成分的含钛固体组分,其包含钛化合物,镁化合物,卤素,作为载体的无机氧化物和作为电子给体化合物的羧酸酯的化合物,以及作为助催化剂的b) 铝化合物和任选的另外的电子给体化合物,其中使用的无机氧化物的pH为1至6,平均粒径为5至200μm,平均一次粒径为1至20μm,空隙 或平均直径为0.1-20μm的通道,并且整个颗粒的体积的宏观份额在5至30%的范围内。

    Catalyst systems of the Ziegler-Natta type
    10.
    发明授权
    Catalyst systems of the Ziegler-Natta type 失效
    齐格勒 - 纳塔型催化剂系统

    公开(公告)号:US06524995B2

    公开(公告)日:2003-02-25

    申请号:US09750715

    申请日:2001-01-02

    IPC分类号: B01J2302

    摘要: Catalyst systems of the Ziegler-Natta type comprise as active constituents a) a solid component comprising a compound of titanium or vanadium, a compound of magnesium, a particulate inorganic oxide as support and an internal electron donor compound, and as cocatalyst b) an aluminum compound and c) if desired, a further, external electron donor compound, wherein the particulate, inorganic oxide used has a specific surface area of from 350 to 1000 m2/g and a mean particle diameter {overscore (D)} in the range from 5 to 60 &mgr;m and comprises particles which are composed of primary particles having a mean particle diameter {overscore (d)} in the range from 1 to 10 &mgr;m and contain voids or channels between the primary particles, where the macroscopic proportion of voids or channels having a diameter of greater than 1 &mgr;m in the particles of the inorganic oxides is in the range from 5 to 30% by volume and the molar ratio of the compound of magnesium to the particulate, inorganic oxide is from 0.5:1 to 2.0:1.

    摘要翻译: 齐格勒 - 纳塔型的催化剂体系包括作为活性成分的a)包含钛或钒的化合物的固体组分,镁的化合物,作为载体的颗粒状无机氧化物和内部电子给体化合物,以及作为助催化剂)铝化合物和 ),其中所用的颗粒状无机氧化物的比表面积为350〜1000m2 / g,平均粒径(超芯(D在5〜60μm的范围内)和 包含由平均粒径(超芯(d在1-10μm范围内)并且在初级颗粒之间含有空隙或通道的初级颗粒组成的颗粒,其中空隙或通道的宏观比例具有大于1的直径 无机氧化物颗粒中的母体在5至30体积%的范围内,镁与颗粒的无机氧化物的摩尔比为0.5:1至 2.0:1。