摘要:
A sealable coextruded film is made from at least one outer layer and from at least one base layer, where the outer layer is composed of a propylene terpolymer comprising from 80 to 99.5 mol % of structural units derived from propylene, from 0.2 to 15 mol % of structural units derived from ethene or from a C4-C6 1-olefin (I) and from 0.3 to 15 mol % of structural units derived from another C4-C12 1-olefin (II) different from the C4-C6 1-olefin (I), and where the propylene terpolymer has been prepared using metallocene catalysts.
摘要:
A process for preparing a supported transition metal catalyst comprising a particulate organic or inorganic support material, a transition metal complex and a compound capable of forming metallocenium ions comprises the following process steps: a) contacting a solution of a compound capable of forming metallocenium ions with a second solvent in which this compound is only sparingly soluble, in the presence of the support material, b) removing at least part of the solvent from the support material and c) contacting a solution of a mixture of a compound capable of forming metallocenium ions and a transition metal complex with a second solvent in which this mixture is only sparingly soluble, in the presence of the support material obtained as described in a) and b).
摘要:
Propene terpolymers consist of from 80 to 99.5 mol % of structural units derived from propene, from 0.1 to 15 mol % of structural units derived from ethene or a C4-C6-1-olefin (I) and from 0.1 to 15 mol % of structural units derived from a further C4-C12-1-olefin (II) which is different from the C4-C6-1-olefin (I), which propene terpolymers have a proportion of regioregular ′1-2′-inserted propene units corresponding to the formula (1) [ ′ 1 - 2 ′ ] [ ′ 1 - 2 ′ ] + [ ′ 2 - 1 ′ ] + [ ′ 1 - 3 ′ ] ( 1 ) of more than 0.99, have a melting point (TM), determined from the DSC peak maximum, of less than 135° C. and a weight average molecular weight (MW) of more than 80,000 g/mol and have a xylene-soluble proportion (XS) in % by weight of the propene terpolymer which obeys the following inequality (2) XS≦1411.21 exp(−0.0591 TM[° C.])−0.05 (2).
摘要:
Injection stretch blow molded containers are obtainable from olefin polymers, comprising homopolymers of propylene or copolymers of propylene with other C2-C10-alk-1-enes, which are obtainable by polymerizing the corresponding monomers with metallocene catalysts. Processes for producing injection stretch blow molded containers from olefin polymers, and also the use of olefin polymers for producing injection stretch blow molded containers, are described.
摘要:
The invention relates to a method for producing a supported catalyst which contains metal, or a supported catalyst constituent which contains metal by impregnating a supporting material with an impregnating solution containing the metal constituent, whereby the impregnating solution flows through the supporting material.
摘要:
In a process for preparing a metal-containing supported catalyst or a metal-containing supported catalyst component by impregnation of a support material with an impregnation solution comprising the metal component, the impregnation solution flows through the support material.
摘要:
In a process for the polymerization of C2-C8-alk-1-enes by means of a Ziegler-Natta catalyst system, in which polymerization is carried out from the gas phase in at least one reaction zone at from 40 to 120° C. and pressures of from 1 to 100 bar, the pressure and temperature in the reaction zone are set so that an operating point formed by these parameters in a pressure-temperature diagram is located at from 0.2 to 5.0 bar below the dew line of the respective reaction mixture above which condensation of the C2-C8-alk-1-enes occurs.
摘要:
A semicrystalline propylene polymer composition with good suitability for producing biaxially oriented films and prepared by polymerizing propylene, ethylene and/or C4-C18-1-alkenes, where at least 50 mol % of the monomer units present arise from the polymerization of propylene. Also described is the use of the semicrystalline propylene polymer composition for producing films, fibers or moldings, the films, fibers and moldings made from these compositions, biaxially stretched films made from the semicrystalline propylene polymer compositions, and also a method for characterizing the semicrystalline propylene polymer compositions.
摘要:
The catalyst systems comprise as active constituents a) a titanium-containing solid component comprising a compound of titanium, a compound of magnesium, a halogen, an inorganic oxide as support and a carboxylic ester as electron donor compound, and also, as cocatalyst, b) an aluminum compound and c) optionally a further electron donor compound, wherein the inorganic oxide used has a pH of from 1 to 6, an average particle diameter of from 5 to 200 &mgr;m, an average primary particle diameter of from 1 to 20 &mgr;M and voids or channels having an average diameter of from 0.1 to 20 &mgr;m and a macroscopic share of the volume of the overall particle within the range from 5 to 30%.
摘要:
Catalyst systems of the Ziegler-Natta type comprise as active constituents a) a solid component comprising a compound of titanium or vanadium, a compound of magnesium, a particulate inorganic oxide as support and an internal electron donor compound, and as cocatalyst b) an aluminum compound and c) if desired, a further, external electron donor compound, wherein the particulate, inorganic oxide used has a specific surface area of from 350 to 1000 m2/g and a mean particle diameter {overscore (D)} in the range from 5 to 60 &mgr;m and comprises particles which are composed of primary particles having a mean particle diameter {overscore (d)} in the range from 1 to 10 &mgr;m and contain voids or channels between the primary particles, where the macroscopic proportion of voids or channels having a diameter of greater than 1 &mgr;m in the particles of the inorganic oxides is in the range from 5 to 30% by volume and the molar ratio of the compound of magnesium to the particulate, inorganic oxide is from 0.5:1 to 2.0:1.