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    Arthropodicidal phosphorus-containing heterocycles
    3.
    发明授权
    Arthropodicidal phosphorus-containing heterocycles 失效
    类节肢动物的含磷杂环

    公开(公告)号：US4695563A

    公开(公告)日：1987-09-22

    申请号：US870043

    申请日：1986-06-03

    申请人： Bernd-Wieland Kruger ,  Wolfgang Behrenz ,  Benedikt Becker ,  Bernhard Homeyer ,  Wilhelm Stendel

    发明人： Bernd-Wieland Kruger ,  Wolfgang Behrenz ,  Benedikt Becker ,  Bernhard Homeyer ,  Wilhelm Stendel

    IPC分类号： A01N57/36 ,  C07F9/6571 ,  C07F9/6578 ,  C07F9/21

    CPC分类号： C07F9/6578 ,  A01N57/36 ,  C07F9/657154 ,  C07F9/65785

    摘要： Novel arthropodicidally active compounds of the formula ##STR1## in which R represents amino or optionally substituted radicals from the series comprising alkyl, alkylamino, methyl-alkylamino, alkoxy, alkenyloxy and alkylthio,R.sup.1 to R.sup.8 are identical or different and represent hydrogen or optionally halogen-substituted radicals from the series comprising alkyl, alkenyl, alkoxyalkyl and alkylthioalkyl, or represent halogen, nitro or dialkylaminoalkyl or represent optionally substituted phenyl or benzyl, and two of the radicals R.sup.1 to R.sup.8, together with the carbon atom or atoms to which they are bonded, may furthermore form an optionally substituted monocyclic or bicyclic ring, andn represents zero or 1.intermediates therefor wherein R is replaced by Cl are also novel.

    摘要翻译： 其中R表示包含烷基，烷基氨基，甲基 - 烷基氨基，烷氧基，烯氧基和烷硫基的系列中的氨基或任选取代的基团的新型节肢动物活性化合物，其中R代表氨基或任选取代的基团，R 1至R 8相同或不同，表示氢或任选的卤素 或者代表任意取代的苯基或苄基，以及其中两个基团R 1 -R 8与它们所代表的碳原子或原子一起形成的烷基，链烯基，烷氧基烷基和烷硫基烷基， 还可以形成任选取代的单环或双环，并且n表示0或1，其中R由Cl代替的中间体也是新的。

    2-Thi-1,3,2-oxazaphospholanes
    4.
    发明授权
    2-Thi-1,3,2-oxazaphospholanes 失效

    公开(公告)号：US4387060A

    公开(公告)日：1983-06-07

    申请号：US202906

    申请日：1980-11-03

    申请人： Hellmut Hoffmann ,  Bernd-Wieland Kruger ,  Wolfgang Behrenz

    发明人： Hellmut Hoffmann ,  Bernd-Wieland Kruger ,  Wolfgang Behrenz

    IPC分类号： A01N57/36 ,  C07F9/6584 ,  C07F9/24 ,  A01N57/26

    CPC分类号： C07F9/65844 ,  A01N57/36

    摘要： In a synergistic pesticidal composition comprising (1) a pesticidally active compound and (2) a synergizing agent in amount sufficient to synergize the pesticidal activity of the pesticidally active compound, the improvement which comprises employing as the synergizing agent a 2-(thi)oxo-1,3,2-oxazaphospholane of the formula ##STR1## in which X represents oxygen or sulphur,R represents an optionally substituted alkyl, alkenyl, alkynyl, phenyl, alkoxy, alkenoxy, alkynoxy, alkylthio, aralkoxy, amino, mono- or di-alkylamino, heterocyclic amino, N-alkyl-N-aryl-amino, phenoxy or phenylthio radical,R.sup.1 represents hydrogen, optionally substituted alkyl, aralkyl, alkenyl, alkynyl or dialkylaminoalkyl,R.sup.2 represents hydrogen, alkylthioalkyl, or optionally substituted alkyl or aralkyl, or R.sup.1 and R.sup.2 together represent alkylene,R.sup.3 represents hydrogen or alkyl andR.sup.4 represents hydrogen, alkyl, or phenyl.

    摘要翻译： 在一种协同杀虫组合物中，其包含（1）农药活性化合物和（2）足以协同农药活性化合物杀虫活性的量的协同剂，其改进包括使用2-（硫代）氧代 其中X表示氧或硫，R表示任选取代的烷基，烯基，炔基，苯基，烷氧基，链烯氧基，炔氧基，烷硫基，芳烷氧基，氨基，单或二烷氧基， 二烷基氨基，杂环氨基，N-烷基-N-芳基 - 氨基，苯氧基或苯硫基，R 1表示氢，任选取代的烷基，芳烷基，烯基，炔基或二烷基氨基烷基，R 2表示氢，烷硫基烷基或任选取代的烷基或芳烷基 ，或者R 1和R 2一起表示亚烷基，R 3表示氢或烷基，R 4表示氢，烷基或苯基。

    (Thio)(dithio-phosphates(phosphonates), processes for their preparation, and their use in pest-combating agents
    5.
    发明授权
    (Thio)(dithio-phosphates(phosphonates), processes for their preparation, and their use in pest-combating agents 失效
    （Thio）（二硫代磷酸酯（膦酸酯）），其制备方法及其在抗虫剂中的应用

    公开(公告)号：US4511562A

    公开(公告)日：1985-04-16

    申请号：US404249

    申请日：1982-08-02

    申请人： Bernd-Wieland Kruger ,  Wolfgang Behrenz

    发明人： Bernd-Wieland Kruger ,  Wolfgang Behrenz

    IPC分类号： A01N57/02 ,  C07F9/09 ,  C07F9/165 ,  C07F9/20 ,  C07F9/24 ,  C07F9/26 ,  C07F9/40 ,  C07F9/42 ,  A01N57/00 ,  A01N57/16 ,  A01N57/26 ,  A01N65/00

    CPC分类号： C07F9/425 ,  A01N57/02 ,  C07F9/091 ,  C07F9/1651 ,  C07F9/1653 ,  C07F9/20 ,  C07F9/2408 ,  C07F9/26 ,  C07F9/4075 ,  C07F9/4087

    摘要： Pesticidal dicyanohydrin (thiono)(dithio)-phosphates(phosphonates) of the general formula ##STR1## in which X represents oxygen or sulphur,R represents an optionally substituted radical selected from alkyl, alkenyl, alkinyl, aryl, aralkyl, alkoxy, aryloxy, aralkoxy, alkylthio, arylthio, aralkylthio, alkylamino (mono- and dialkylamino), arylamino and aralkylamino, andR.sup.1 and R.sup.2 are identical or different and individually represent a hydrogen atom, an optionally substituted radical selected from alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl and aryl, or an optionally substituted heterocyclic radical,are new and are particularly effective in combating pests, such as insects and acarids, in synergistic combinations with other compounds which are active against arthropods.

    摘要翻译： 通式为（I）的农药二氰醇（二硫）磷酸酯（膦酸酯），其中X表示氧或硫，R表示任选取代的选自烷基，烯基，炔基，芳基，芳烷基，烷氧基 ，芳氧基，芳烷氧基，烷硫基，芳硫基，芳烷硫基，烷基氨基（单和二烷基氨基），芳基氨基和芳烷基氨基，R 1和R 2相同或不同，并且各自表示氢原子，任选取代的选自烷基，烯基，炔基， 环烷基，环烯基，芳烷基，芳烯基和芳基，或任选取代的杂环基是新的，并且特别有效地与防治节肢动物活性的其它化合物协同组合地对抗害虫，例如昆虫和螨虫。

    2-(thi)oxo-1,3,2-oxazaphospholanes as synergizing agents for pesticides
    6.
    发明授权
    2-(thi)oxo-1,3,2-oxazaphospholanes as synergizing agents for pesticides 失效
    2-（thi）氧代-1,3,2-氧氮杂磷杂环己烷作为农药的协同作用剂

    公开(公告)号：US4609646A

    公开(公告)日：1986-09-02

    申请号：US581470

    申请日：1984-02-17

    申请人： Hellmut Hoffmann ,  Bernd-Wieland Kruger ,  Wolfgang Behrenz

    发明人： Hellmut Hoffmann ,  Bernd-Wieland Kruger ,  Wolfgang Behrenz

    IPC分类号： A01N57/36 ,  C07F9/6584 ,  C07F9/24

    CPC分类号： C07F9/65844 ,  A01N57/36

    摘要： In a synergistic pesticidal composition comprising (1) a pesticidally active compound and (2) a synergizing agent in amount sufficient to synergize the pesticidal activity of the pesticidally active compound, the improvement which comprises employing as the syngerizing agent a 2-(thi)oxo-1,3,2-oxazaphospholane of the formula ##STR1## in which X represents oxygen or sulphur,R represents an optionally substituted alkyl, alkenyl, alkynyl, phenyl, alkoxy, alkenoxy, alkynoxy, alkylthio, aralkoxy, amino, mono- or di-alkylamino, heterocyclic amino, N-alky-N-aryl-amino, phenoxy or phenylthio radical,R.sup.1 represents hydrogen, optionally subsituted alkyl, aralkyl, alkenyl, alkynyl or dialkylaminoalkyl,R.sup.2 represents hydrogen, alkylthioalkyl; or optionally substituted alkyl or aralkyl, or R.sup.1 and R.sup.2 together represent alkylene,R.sup.3 represents hydrogen or alkyl andR.sup.4 represents hydrogen, alkyl, or phenyl.

    摘要翻译： 在一种协同杀虫组合物中，其包含（1）杀虫活性化合物和（2）足以协同杀虫活性化合物杀虫活性的量的协同剂，其改进包括使用2-（硫代）氧代 其中X表示氧或硫，R表示任选取代的烷基，烯基，炔基，苯基，烷氧基，链烯氧基，炔氧基，烷硫基，芳烷氧基，氨基，单或二烷氧基， 二烷基氨基，杂环氨基，N-烷基-N-芳基 - 氨基，苯氧基或苯硫基，R 1表示氢，任选取代的烷基，芳烷基，烯基，炔基或二烷基氨基烷基，R 2表示氢，烷硫基烷基; 或任选取代的烷基或芳烷基，或R 1和R 2一起表示亚烷基，R 3表示氢或烷基，R 4表示氢，烷基或苯基。

    Cyclopropylmethyl(ene) ethers and arthropocidal use thereof
    7.
    发明授权
    Cyclopropylmethyl(ene) ethers and arthropocidal use thereof 失效
    环丙基甲基（烯）醚及其联合作用

    公开(公告)号：US4575516A

    公开(公告)日：1986-03-11

    申请号：US576073

    申请日：1984-02-01

    申请人： Bernd-Wieland Kruger ,  Uwe Priesnitz ,  Gerhard Jager ,  Wolfgang Behrenz

    发明人： Bernd-Wieland Kruger ,  Uwe Priesnitz ,  Gerhard Jager ,  Wolfgang Behrenz

    IPC分类号： C07C43/17 ,  A01N31/04 ,  A01N33/08 ,  C07C17/20 ,  C07C17/269 ,  C07C41/00 ,  C07C43/172 ,  C07C67/00 ,  C07C213/00 ,  C07C217/44 ,  C07C313/00 ,  C07C323/04 ,  C07C43/15 ,  A01N43/00 ,  C07C43/162 ,  C07C43/166

    CPC分类号： C07C43/172 ,  A01N31/04 ,  C07C17/208 ,  C07C17/269

    摘要： Substituted cyclopropylmethyl(ene) ethers of the formula ##STR1## in which X.sup.1 and X.sup.2 are identical or different and represent halogen,R.sup.1 represents hydrogen or alkyl,R.sup.2 and R.sup.3 are identical or different and represent hydrogen, alkyl, optionally substituted aryl, halogenoalkyl, hetero-alkyl, alkoxyalkyl, alkylthioalkyl, optionally substituted alkenoxyalkyl, optionally substituted alkinoxyalkyl or (di)alkylaminoalkyl,R.sup.4 represents hydrogen or alkyl,R.sup.5 and R.sup.6 are identical or different and represent hydrogen or optionally substituted radicals from the series comprising alkyl, aryl and aralkyl andR represents a trihalogenoalkenyl, alkinyl or iodoalkinyl radical,exhibit some arthropodicidal activity and synergize other known arthropodicides.

    摘要翻译： 取代的式“IMAGE”的环丙基甲基（烯）醚，其中X 1和X 2相同或不同并且表示卤素，R 1表示氢或烷基，R 2和R 3相同或不同，表示氢，烷基，任选取代的芳基，卤代烷基， 杂烷基，烷氧基烷基，烷硫基烷基，任选取代的烯氧基烷基，任选取代的烷氧基烷基或（二）烷基氨基烷基，R 4表示氢或烷基，R 5和R 6相同或不同，代表氢或任选取代的基团，包括烷基，芳基和芳烷基 R代表三卤代烯基，炔基或碘链烯基，表现出一些节肢动物活性，并协同其他已知的节肢动物杀虫剂。

    2-(Thi)oxo-1,3,2-oxazaphospholanes as synergizing agents for pesticides
    8.
    发明授权
    2-(Thi)oxo-1,3,2-oxazaphospholanes as synergizing agents for pesticides 失效
    2-（Thi）氧代-1,3,2-氧氮杂磷杂环己烷作为农药的协同作用剂

    公开(公告)号：US4473558A

    公开(公告)日：1984-09-25

    申请号：US401461

    申请日：1982-07-26

    申请人： Hellmut Hoffmann ,  Bernd-Wieland Kruger ,  Wolfgang Behrenz

    发明人： Hellmut Hoffmann ,  Bernd-Wieland Kruger ,  Wolfgang Behrenz

    IPC分类号： A01N57/36 ,  C07F9/6584 ,  A01N65/00 ,  A01N57/00 ,  A01N57/26

    CPC分类号： C07F9/65844 ,  A01N57/36

    摘要： In a synergistic pesticidal composition comprising (1) a pesticidally active compound and (2) a synergizing agent in amount sufficient to synergize the pesticidal activity of the pesticidally active compound, the improvement which comprises employing as the synergizing agent a 2-(thi)oxo-1,3,2-oxazaphospholane of the formula ##STR1## in which X represents oxygen or sulphur,R represents an optionally substituted alkyl, alkenyl, alkynyl, phenyl, alkoxy, alkenoxy, alkynoxy, alkylthio, aralkoxy, amino, mono- or di-alkylamino, heterocyclic amino, N-alkyl-N-aryl-amino, phenoxy or phenylthio radical,R.sup.1 represents hydrogen, optionally substituted alkyl, aralkyl, alkenyl, alkynyl or dialkylaminoalkyl,R.sup.2 represents hydrogen, alkylthioalkyl, or optionally substituted alkyl or aralkyl, or R.sup.1 and R.sup.2 together represent alkylene,R.sup.3 represents hydrogen or alkyl andR.sup.4 represents hydrogen, alkyl, or phenyl.

    摘要翻译： 在一种协同杀虫组合物中，其包含（1）农药活性化合物和（2）足以协同农药活性化合物杀虫活性的量的协同剂，其改进包括使用2-（硫代）氧代 其中X表示氧或硫，R表示任选取代的烷基，烯基，炔基，苯基，烷氧基，链烯氧基，炔氧基，烷硫基，芳烷氧基，氨基，单或二烷氧基， 二烷基氨基，杂环氨基，N-烷基-N-芳基 - 氨基，苯氧基或苯硫基，R 1表示氢，任选取代的烷基，芳烷基，烯基，炔基或二烷基氨基烷基，R 2表示氢，烷硫基烷基或任选取代的烷基或芳烷基 ，或者R 1和R 2一起表示亚烷基，R 3表示氢或烷基，R 4表示氢，烷基或苯基。

    Pest-combating agents containing phosphorus-heterocyclic compounds
    10.
    发明授权
    Pest-combating agents containing phosphorus-heterocyclic compounds 失效
    含有磷杂环化合物的抗虫剂

    公开(公告)号：US4678777A

    公开(公告)日：1987-07-07

    申请号：US762979

    申请日：1985-08-06

    申请人： Bernd-Wieland Kruger ,  Hellmut Hoffmann ,  Ernst Roos ,  Wolfgang Behrenz

    发明人： Bernd-Wieland Kruger ,  Hellmut Hoffmann ,  Ernst Roos ,  Wolfgang Behrenz

    IPC分类号： A01N57/36 ,  C07F9/6571

    CPC分类号： C07F9/657181 ,  A01N57/36 ,  C07F9/657118 ,  C07F9/657127 ,  C07F9/657154

    摘要： An arthropodicidal composition comprising an arthropodicidally effective amount of an arthropodicidally active compound and a synergistically effective amount of at least one compound of the formula ##STR1## in which A is amino, alkylamino, dialkylamino or N-alkyl-N-arylamino, or an optionally substituted alkyl, alkenyl, alkoxy, alkenyloxy, alkylthio, aralkyl, aralkoxy, phenyl, phenoxy or phenylthio radical,R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 each independently is hydrogen, or an optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl or alkylthioalkyl radical, or is halogen, nitro or dialkylaminoalkyl, or is optionally substituted phenyl or benzyl, or two of the radicals R.sup.1 to R.sup.8, together with the carbon atom or atoms to which they are bonded form an optionally substituted monocyclic or bicyclic ring andn and m each independently is 0 or 1.

    摘要翻译： 一种节肢动物杀伤组合物，其包含节肢动物节肢动物有效量的节肢动物杀虫活性化合物和协同有效量的至少一种下式的化合物，其中A是氨基，烷基氨基，二烷基氨基或N-烷基-N-芳基氨基，或任选地 取代的烷基，烯基，烷氧基，烯氧基，烷硫基，芳烷基，芳烷氧基，苯基，苯氧基或苯硫基，R1，R2，R3，R4，R5，R6，R7和R8各自独立地为氢或任选卤素取代的烷基， 烯基，烷氧基烷基或烷硫基烷基，或为卤素，硝基或二烷基氨基烷基，或任选取代的苯基或苄基，或两个基团R 1至R 8与它们所连接的碳原子或原子一起形成任选取代的单环或 双环，n和m各自独立地为0或1。