公开(公告)号：US4228026A

公开(公告)日：1980-10-14

申请号：US39116

申请日：1979-05-15

申请人： Braja D. Mookherjee ,  Richard A. Wilson ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Jacob Kiwala ,  Frederick L. Schmitt ,  Edward J. Granda

发明人： Braja D. Mookherjee ,  Richard A. Wilson ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Jacob Kiwala ,  Frederick L. Schmitt ,  Edward J. Granda

IPC分类号： C11B9/00 ,  C11D3/50 ,  C11D9/44

CPC分类号： C11B9/0034 ,  C11D3/50

摘要： Processes and compositions are described for the use as detergent aroma imparting, augmenting or enhancing materials of 3-hydroxy-1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-1-butanone having the structure: ##STR1## and perfume compositions containing same.

摘要翻译： 描述了用作洗涤剂香气赋予，增强或增强具有结构的3-羟基-1-（2,6,6-三甲基-1,3-环己二烯-1-基）-1-丁酮的材料的方法和组合物 ：＆lt; IMAGE＆gt;和含有它们的香水组合物。

公开(公告)号：US4235247A

公开(公告)日：1980-11-25

申请号：US942529

申请日：1978-09-15

申请人： Braja D. Mookherjee ,  Richard A. Wilson ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Jacob Kiwala ,  Frederick L. Schmitt ,  Edward J. Granda

发明人： Braja D. Mookherjee ,  Richard A. Wilson ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Jacob Kiwala ,  Frederick L. Schmitt ,  Edward J. Granda

IPC分类号： A24B15/34 ,  A24B15/30

CPC分类号： A24B15/34

摘要： Described herein is a method for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of adding to said smoking tobacco an organoleptic property-modifying quantity of a compound having the structure: ##STR1##

摘要翻译： 本文描述了一种用于增强或增强烟草香气或味道的方法，包括向所述吸烟烟草中加入具有以下结构的化合物的感官特性改性量的步骤：

公开(公告)号：US4335002A

公开(公告)日：1982-06-15

申请号：US169678

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  C11B9/00 ,  A23L1/226 ,  A23L2/26 ,  A61K7/46

CPC分类号： C11B9/0015 ,  A23L27/2024 ,  A24B15/32

摘要： Described are cis-3-hexenyl derivatives having the generic structure: ##STR1## wherein R is one of the moieties: ##STR2## which are useful in foodstuffs, flavorings, fragrances, perfumed articles (e.g. anionic, cationic or nonionic detergents, dryer-added fabric softener articles and cosmetic powders) and smoking tobacco flavorings; processes for producing such cis-3-hexenyl derivatives and products produced according to such processes which include chemical compounds in addition to said cis-3-hexenyl derivatives.

摘要翻译： 描述了具有以下通用结构的顺式-3-己烯基衍生物：其中R是部分之一：可用于食品，调味品，香料，加香制品（例如阴离子，阳离子或非离子型洗涤剂 ，干燥剂添加织物柔软剂制品和化妆品粉末）和吸烟烟草调味剂; 制备这种顺式-3-己烯基衍生物的方法和根据这些方法生产的产物，除了所述顺式-3-己烯基衍生物外，还包括化学化合物。

公开(公告)号：US4312766A

公开(公告)日：1982-01-26

申请号：US169813

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  D06M13/16 ,  A61K7/46 ,  D06M13/18 ,  D06M13/20

CPC分类号： A24B15/32 ,  A23L27/2024

摘要： Described are cis-3-hexenyl derivatives having the generic structure: ##STR1## wherein R is one of the moieties: ##STR2## which are useful in foodstuffs, flavorings, fragrances, perfumed articles (e.g. anionic, cationic or nonionic detergents, dryer-added fabric softener articles and cosmetic powders) and smoking tobacco flavorings; processes for producing such cis-3-hexenyl derivatives and products produced according to such processes which include chemical compounds in addition to said cis-3-hexenyl derivatives.

摘要翻译： 描述了具有以下通用结构的顺式-3-己烯基衍生物：其中R是可用于食品，调味品，香料，加香制品（例如阴离子，阳离子或非离子洗涤剂，干燥剂 - 添加织物柔软剂制品和化妆粉）和吸烟烟草调味剂; 制备这种顺式-3-己烯基衍生物的方法和根据这些方法生产的产物，除了所述顺式-3-己烯基衍生物外，还包括化学化合物。

公开(公告)号：US4319586A

公开(公告)日：1982-03-16

申请号：US169901

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  A24B3/12

CPC分类号： A24B15/32 ,  A23L27/2024

摘要： Described are processes for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of intimately admixing with smoking tobacco an aroma or taste augmenting or enhancing quantity of at least one substance selected from the group consisting of:A. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, trans-2-hexenal, and cis-3-hexenol;B. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenyl formate and trans-2-hexenal;C. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenol, cis-3-hexenyl formate and trans-2-hexenal; andD. Cis-3-hexenyl methyl ether.Also described are smoking tobacco compositions produced according to the above process. Also described are smoking tobacco articles comprising a cylindrically shaped body of smoking tobacco; in intimate contact with said cylindrically shaped body along its length, a wrapper; and in intimate contact with one end of said cylindrically shaped body, a filter; and in intimate contact with either said filter, said wrapper or said cylindrically shaped body at least one substance selected from the group consisting of:A. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, trans-2-hexenal, and cis-3-hexenol;B. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenyl formate and trans-2-hexenal;C. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenol, cis-3-hexenyl formate and trans-2-hexenal; andD. Cis-3-hexenyl methyl ether.

摘要翻译： 描述了用于增强或增强烟草的香气或味道的方法，其包括与吸烟烟草充分混合的香味或味道增强或增加量的选自以下的物质的步骤：A.物质组合物 基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，反式-2-己烯醛和顺式-3-己烯醇组成; B.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物; C.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯醇，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物。 和D.Cis-3-己烯基甲基醚。 还描述了根据上述方法制备的烟草烟草组合物。 还描述了包括吸烟烟草的圆柱形体的烟草制品; 沿其长度与所述圆柱形体紧密接触，包裹物; 并且与所述圆柱形体的一端紧密接触，过滤器; 并且与所述过滤器，所述包装物或所述圆柱形主体紧密接触至少一种选自以下的物质：A.主要由顺式-3-己烯醛，顺式-3-己烯基 - 顺式 - 3-己烯酸酯，反式-2-己烯醛和顺式-3-己烯醇; B.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物; C.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯醇，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物。 和D.Cis-3-己烯基甲基醚。

公开(公告)号：US4267066A

公开(公告)日：1981-05-12

申请号：US169812

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  C11D3/50 ,  C11D9/44

CPC分类号： A24B15/32 ,  A23L27/2024 ,  A23L27/2026 ,  C11D3/50 ,  C11D9/442

摘要： Described is a process for augmenting or enhancing the aroma of solid or liquid anionic, cationic or nonionic detergent comprising the step of intimately admixing with a solid or liquid anionic, cationic or nonionic detergent base an aroma augmenting or enhancing quantity of at least one substrate selected from the group consisting of:A. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, trans-2-hexenal, and cis-3-hexenol;B. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenyl formate and trans-2-hexenal;C. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenol, cis-3-hexenyl formate and trans-2-hexenal; andD. Cis-3-hexenyl methyl ether.

摘要翻译： 描述了一种用于增强或增强固体或液体阴离子，阳离子或非离子洗涤剂的香气的方法，其包括与固体或液体阴离子，阳离子或非离子洗涤剂基质充分混合或增强量的至少一种选择的底物的步骤 由以下组成：A.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，反式-2-己烯醛和顺式-3-己烯醇组成的物质组合物; B.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物; C.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯醇，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物。 和D.Cis-3-己烯基甲基醚。

公开(公告)号：US4280933A

公开(公告)日：1981-07-28

申请号：US169902

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  A61K7/46

CPC分类号： A24B15/32 ,  A23L27/2024

摘要： Described are cis-3-hexenyl derivatives having the generic structure: ##STR1## wherein R is one of the moieties: ##STR2## which are useful in foodstuffs, flavorings, fragrances, perfumed articles (e.g. anionic, cationic or nonionic detergents, dryer-added fabric softener articles and cosmetic powders) and smoking tobacco flavorings; processes for producing such cis-3-hexenyl derivatives and products produced according to such processes which include chemical compounds in addition to said cis-3-hexenyl derivatives.

摘要翻译： 描述了具有以下通用结构的顺式-3-己烯基衍生物：其中R是可用于食品，调味品，香料，加香制品（例如阴离子，阳离子或非离子洗涤剂，干燥剂 - 添加织物柔软剂制品和化妆粉）和吸烟烟草调味剂; 制备这种顺式-3-己烯基衍生物的方法和根据这些方法生产的产物，除了所述顺式-3-己烯基衍生物外，还包括化学化合物。

公开(公告)号：US4241098A

公开(公告)日：1980-12-23

申请号：US85707

申请日：1979-10-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  A23L1/226

CPC分类号： A24B15/32 ,  A23L27/2024 ,  A23L27/2026

摘要： Described is a method for augmenting or enhancing the aroma or flavor of a foodstuff comprising adding to the foodstuff from 0.05 up to about 500 parts per million of a mixture of cis-3-hexenal, trans-2-hexenal, cis-3-hexenyl formate, cis-3-hexenol and cis-3-hexenyl-cis-3-hexenoate prepared by the process of reacting cis-3-hexenol with pyridinium chlorochromate.

摘要翻译： 描述了一种用于增强或增强食品香气或风味的方法，包括向食品中加入0.05至约500ppm的顺式-3-己烯醛，反式-2-己烯醛，顺式-3-己烯 通过使顺式-3-己烯醇与氯铬酸吡啶鎓反应制备的甲酸，顺式-3-己烯醇和顺式-3-己烯基 - 顺式-3-己烯酸酯。

公开(公告)号：US4278098A

公开(公告)日：1981-07-14

申请号：US119858

申请日：1980-02-08

申请人： Richard A. Wilson ,  William L. Schreiber ,  Braja D. Mookherjee ,  Jacob Kiwala ,  Joaquin F. Vinals ,  Manfred H. Vock ,  Gilbert Stork ,  Frederick L. Schmitt

发明人： Richard A. Wilson ,  William L. Schreiber ,  Braja D. Mookherjee ,  Jacob Kiwala ,  Joaquin F. Vinals ,  Manfred H. Vock ,  Gilbert Stork ,  Frederick L. Schmitt

IPC分类号： A24B15/30 ,  A24B15/34 ,  C07C29/09 ,  C07C29/40 ,  C07C29/68 ,  C07C33/14 ,  C11B9/00 ,  A24B3/12 ,  A24B15/36

CPC分类号： C11B9/0034 ,  A24B15/34 ,  C07C29/09 ,  C07C29/40 ,  C07C29/68 ,  C07C33/14 ,  C07C403/08 ,  C07B2200/09 ,  C07C2101/16

摘要： Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, smoking tobacco flavor and aroma and perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, smoking tobacco, perfume and perfumed article aroma and/or flavor imparting materials of 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanol and -1,3-cyclohexadiene-1-methanol derivatives or one or more of their geometric or stereoisomers as defined by the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; the dashed line is a carbon-carbon double bond or a carbon-carbon single bond; with the proviso that when R.sub.1 is hydrogen, the dashed line is a carbon-carbon double bond.Addition of one or more of the 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols or -1,3-cyclohexadiene-1-methanols of our invention to consumable materials is indicated to produce:A. In foodstuffs, chewing gums, toothpastes and medicinal products, sweet, camphoraceous, damascenone, raspberry-like, raspberry juice-like, rosey, woody/ionone-like, oriental, tobacco-like, tea-like, grape-like, fruity and ionone-like aromas and flavor notes;B. In perfumes, colognes and perfumed articles, leathery, hay, woody, mustard, minty, spicey (clove) and pulegone-like aromas and hay/tobacco and honey ionone-like topnotes with safronal-like nuances; andC. In tobaccos and tobacco flavors, a sweet-musty, hay-tobacco-like, fruity-raspberry, ionone-like aroma prior to smoking and a fruity tobacco-like, Virginia tobacco-like aroma on smoking both in the main stream and in the side stream.

摘要翻译： 描述了用于食品，口香糖，牙膏和药用产品风味和香气，吸烟烟草风味和香气以及香料和香料制品香气增强，增强和赋予组合物的方法和组合物; 以及2,6,6-三甲基-α-（异）丙烯基-1-环己烯-1-甲醇的食品，口香糖，牙膏，药用产品，吸烟烟草，香料和香料制品香气和/或调味材料，以及 -1,3-环己二烯-1-甲醇衍生物或其一般结构定义的其几何或立体异构体中的一种或多种：其中R 1，R 2或R 3中的一个为甲基，R 1，R 2和R 3中的另外两个为 表示氢; 虚线是碳 - 碳双键或碳 - 碳单键; 条件是当R1是氢时，虚线是碳 - 碳双键。 将本发明的一种或多种2,6,6-三甲基-α-（异）丙烯-1-环己烯-1-甲醇或-1,3-环己二烯-1-甲醇添加到消耗材料中被指示产生 ：A.在食品，口香糖，牙膏和药用产品中，甜，樟脑，大马士革，覆盆子样，覆盆子汁，玫瑰，木/紫罗兰酮样，东方，烟草状，茶状，葡萄状 ，水果和紫罗兰酮样香气和风味香气; B.香水，古龙水和香水制品，革质，干草，木质，芥末，小茴香，香料（丁香）和香菇样香气和干草/烟草和蜂蜜类似紫罗兰酮的顶峰，具有丰富的细微差别; 在烟草和烟草香料中，在吸烟之前是一种甜味，干草烟样，果香 - 覆盆子，类胡萝卜素的香气，并且在主流中吸烟时具有类似烟草般的弗吉尼亚烟草样香气 并在旁边的流。

公开(公告)号：US4275087A

公开(公告)日：1981-06-23

申请号：US120102

申请日：1980-02-08

申请人： Richard A. Wilson ,  William L. Schreiber ,  Braja D. Mookherjee ,  Jacob Kiwala ,  Joaquin F. Vinals ,  Manfred H. Vock ,  Gilbert Stork ,  Frederick L. Schmitt

发明人： Richard A. Wilson ,  William L. Schreiber ,  Braja D. Mookherjee ,  Jacob Kiwala ,  Joaquin F. Vinals ,  Manfred H. Vock ,  Gilbert Stork ,  Frederick L. Schmitt

IPC分类号： A23L27/20 ,  A24B15/34 ,  C07C29/09 ,  C07C29/40 ,  C07C29/68 ,  C07C33/14 ,  C11B9/00 ,  A23L1/226 ,  A23L1/235

CPC分类号： C11B9/0034 ,  A24B15/34 ,  C07C29/09 ,  C07C29/40 ,  C07C29/68 ,  C07C33/14 ,  C07C403/08 ,  C07B2200/09 ,  C07C2101/16

摘要： Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, smoking tobacco flavor and aroma and perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, smoking tobacco, perfume and perfumed article aroma and/or flavor imparting materials of 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanol and -1,3-cyclohexadiene-1-methanol derivatives or one or more of their geometric or stereoisomers as defined by the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; the dashed line is a carbon-carbon double bond or a carbon-carbon single bond; with the proviso that when R.sub.1 is hydrogen, the dashed line is a carbon-carbon double bond.

摘要翻译： 描述了用于食品，口香糖，牙膏和药用产品风味和香气，吸烟烟草风味和香气以及香料和香料制品香气增强，增强和赋予组合物的方法和组合物; 以及2,6,6-三甲基-α-（异）丙烯基-1-环己烯-1-甲醇的食品，口香糖，牙膏，药用产品，吸烟烟草，香料和香料制品香气和/或调味材料，以及 -1,3-环己二烯-1-甲醇衍生物或其一般结构定义的其几何或立体异构体中的一种或多种：其中R 1，R 2或R 3中的一个为甲基，R 1，R 2和R 3中的另外两个为 表示氢; 虚线是碳 - 碳双键或碳 - 碳单键; 条件是当R1是氢时，虚线是碳 - 碳双键。