公开(公告)号：US4228026A

公开(公告)日：1980-10-14

申请号：US39116

申请日：1979-05-15

申请人： Braja D. Mookherjee ,  Richard A. Wilson ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Jacob Kiwala ,  Frederick L. Schmitt ,  Edward J. Granda

发明人： Braja D. Mookherjee ,  Richard A. Wilson ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Jacob Kiwala ,  Frederick L. Schmitt ,  Edward J. Granda

IPC分类号： C11B9/00 ,  C11D3/50 ,  C11D9/44

CPC分类号： C11B9/0034 ,  C11D3/50

摘要： Processes and compositions are described for the use as detergent aroma imparting, augmenting or enhancing materials of 3-hydroxy-1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-1-butanone having the structure: ##STR1## and perfume compositions containing same.

摘要翻译： 描述了用作洗涤剂香气赋予，增强或增强具有结构的3-羟基-1-（2,6,6-三甲基-1,3-环己二烯-1-基）-1-丁酮的材料的方法和组合物 ：＆lt; IMAGE＆gt;和含有它们的香水组合物。

公开(公告)号：US4235247A

公开(公告)日：1980-11-25

申请号：US942529

申请日：1978-09-15

申请人： Braja D. Mookherjee ,  Richard A. Wilson ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Jacob Kiwala ,  Frederick L. Schmitt ,  Edward J. Granda

发明人： Braja D. Mookherjee ,  Richard A. Wilson ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Jacob Kiwala ,  Frederick L. Schmitt ,  Edward J. Granda

IPC分类号： A24B15/34 ,  A24B15/30

CPC分类号： A24B15/34

摘要： Described herein is a method for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of adding to said smoking tobacco an organoleptic property-modifying quantity of a compound having the structure: ##STR1##

摘要翻译： 本文描述了一种用于增强或增强烟草香气或味道的方法，包括向所述吸烟烟草中加入具有以下结构的化合物的感官特性改性量的步骤：

公开(公告)号：US4335002A

公开(公告)日：1982-06-15

申请号：US169678

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  C11B9/00 ,  A23L1/226 ,  A23L2/26 ,  A61K7/46

CPC分类号： C11B9/0015 ,  A23L27/2024 ,  A24B15/32

摘要： Described are cis-3-hexenyl derivatives having the generic structure: ##STR1## wherein R is one of the moieties: ##STR2## which are useful in foodstuffs, flavorings, fragrances, perfumed articles (e.g. anionic, cationic or nonionic detergents, dryer-added fabric softener articles and cosmetic powders) and smoking tobacco flavorings; processes for producing such cis-3-hexenyl derivatives and products produced according to such processes which include chemical compounds in addition to said cis-3-hexenyl derivatives.

摘要翻译： 描述了具有以下通用结构的顺式-3-己烯基衍生物：其中R是部分之一：可用于食品，调味品，香料，加香制品（例如阴离子，阳离子或非离子型洗涤剂 ，干燥剂添加织物柔软剂制品和化妆品粉末）和吸烟烟草调味剂; 制备这种顺式-3-己烯基衍生物的方法和根据这些方法生产的产物，除了所述顺式-3-己烯基衍生物外，还包括化学化合物。

公开(公告)号：US4312766A

公开(公告)日：1982-01-26

申请号：US169813

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  D06M13/16 ,  A61K7/46 ,  D06M13/18 ,  D06M13/20

CPC分类号： A24B15/32 ,  A23L27/2024

摘要： Described are cis-3-hexenyl derivatives having the generic structure: ##STR1## wherein R is one of the moieties: ##STR2## which are useful in foodstuffs, flavorings, fragrances, perfumed articles (e.g. anionic, cationic or nonionic detergents, dryer-added fabric softener articles and cosmetic powders) and smoking tobacco flavorings; processes for producing such cis-3-hexenyl derivatives and products produced according to such processes which include chemical compounds in addition to said cis-3-hexenyl derivatives.

摘要翻译： 描述了具有以下通用结构的顺式-3-己烯基衍生物：其中R是可用于食品，调味品，香料，加香制品（例如阴离子，阳离子或非离子洗涤剂，干燥剂 - 添加织物柔软剂制品和化妆粉）和吸烟烟草调味剂; 制备这种顺式-3-己烯基衍生物的方法和根据这些方法生产的产物，除了所述顺式-3-己烯基衍生物外，还包括化学化合物。

公开(公告)号：US4280933A

公开(公告)日：1981-07-28

申请号：US169902

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  A61K7/46

CPC分类号： A24B15/32 ,  A23L27/2024

摘要： Described are cis-3-hexenyl derivatives having the generic structure: ##STR1## wherein R is one of the moieties: ##STR2## which are useful in foodstuffs, flavorings, fragrances, perfumed articles (e.g. anionic, cationic or nonionic detergents, dryer-added fabric softener articles and cosmetic powders) and smoking tobacco flavorings; processes for producing such cis-3-hexenyl derivatives and products produced according to such processes which include chemical compounds in addition to said cis-3-hexenyl derivatives.

摘要翻译： 描述了具有以下通用结构的顺式-3-己烯基衍生物：其中R是可用于食品，调味品，香料，加香制品（例如阴离子，阳离子或非离子洗涤剂，干燥剂 - 添加织物柔软剂制品和化妆粉）和吸烟烟草调味剂; 制备这种顺式-3-己烯基衍生物的方法和根据这些方法生产的产物，除了所述顺式-3-己烯基衍生物外，还包括化学化合物。

公开(公告)号：US4241098A

公开(公告)日：1980-12-23

申请号：US85707

申请日：1979-10-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  A23L1/226

CPC分类号： A24B15/32 ,  A23L27/2024 ,  A23L27/2026

摘要： Described is a method for augmenting or enhancing the aroma or flavor of a foodstuff comprising adding to the foodstuff from 0.05 up to about 500 parts per million of a mixture of cis-3-hexenal, trans-2-hexenal, cis-3-hexenyl formate, cis-3-hexenol and cis-3-hexenyl-cis-3-hexenoate prepared by the process of reacting cis-3-hexenol with pyridinium chlorochromate.

摘要翻译： 描述了一种用于增强或增强食品香气或风味的方法，包括向食品中加入0.05至约500ppm的顺式-3-己烯醛，反式-2-己烯醛，顺式-3-己烯 通过使顺式-3-己烯醇与氯铬酸吡啶鎓反应制备的甲酸，顺式-3-己烯醇和顺式-3-己烯基 - 顺式-3-己烯酸酯。

公开(公告)号：US4319586A

公开(公告)日：1982-03-16

申请号：US169901

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  A24B3/12

CPC分类号： A24B15/32 ,  A23L27/2024

摘要： Described are processes for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of intimately admixing with smoking tobacco an aroma or taste augmenting or enhancing quantity of at least one substance selected from the group consisting of:A. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, trans-2-hexenal, and cis-3-hexenol;B. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenyl formate and trans-2-hexenal;C. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenol, cis-3-hexenyl formate and trans-2-hexenal; andD. Cis-3-hexenyl methyl ether.Also described are smoking tobacco compositions produced according to the above process. Also described are smoking tobacco articles comprising a cylindrically shaped body of smoking tobacco; in intimate contact with said cylindrically shaped body along its length, a wrapper; and in intimate contact with one end of said cylindrically shaped body, a filter; and in intimate contact with either said filter, said wrapper or said cylindrically shaped body at least one substance selected from the group consisting of:A. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, trans-2-hexenal, and cis-3-hexenol;B. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenyl formate and trans-2-hexenal;C. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenol, cis-3-hexenyl formate and trans-2-hexenal; andD. Cis-3-hexenyl methyl ether.

摘要翻译： 描述了用于增强或增强烟草的香气或味道的方法，其包括与吸烟烟草充分混合的香味或味道增强或增加量的选自以下的物质的步骤：A.物质组合物 基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，反式-2-己烯醛和顺式-3-己烯醇组成; B.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物; C.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯醇，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物。 和D.Cis-3-己烯基甲基醚。 还描述了根据上述方法制备的烟草烟草组合物。 还描述了包括吸烟烟草的圆柱形体的烟草制品; 沿其长度与所述圆柱形体紧密接触，包裹物; 并且与所述圆柱形体的一端紧密接触，过滤器; 并且与所述过滤器，所述包装物或所述圆柱形主体紧密接触至少一种选自以下的物质：A.主要由顺式-3-己烯醛，顺式-3-己烯基 - 顺式 - 3-己烯酸酯，反式-2-己烯醛和顺式-3-己烯醇; B.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物; C.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯醇，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物。 和D.Cis-3-己烯基甲基醚。

公开(公告)号：US4267066A

公开(公告)日：1981-05-12

申请号：US169812

申请日：1980-07-17

申请人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

发明人： Cynthia J. Mussinan ,  Braja D. Mookherjee ,  Manfred H. Vock ,  Frederick L. Schmitt ,  Edward J. Granda ,  Joaquin F. Vinals ,  Jacob Kiwala

IPC分类号： A23L27/20 ,  A24B15/32 ,  C11D3/50 ,  C11D9/44

CPC分类号： A24B15/32 ,  A23L27/2024 ,  A23L27/2026 ,  C11D3/50 ,  C11D9/442

摘要： Described is a process for augmenting or enhancing the aroma of solid or liquid anionic, cationic or nonionic detergent comprising the step of intimately admixing with a solid or liquid anionic, cationic or nonionic detergent base an aroma augmenting or enhancing quantity of at least one substrate selected from the group consisting of:A. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, trans-2-hexenal, and cis-3-hexenol;B. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenyl formate and trans-2-hexenal;C. A composition of matter consisting essentially of cis-3-hexenal, cis-3-hexenyl-cis-3-hexenoate, cis-3-hexenol, cis-3-hexenyl formate and trans-2-hexenal; andD. Cis-3-hexenyl methyl ether.

摘要翻译： 描述了一种用于增强或增强固体或液体阴离子，阳离子或非离子洗涤剂的香气的方法，其包括与固体或液体阴离子，阳离子或非离子洗涤剂基质充分混合或增强量的至少一种选择的底物的步骤 由以下组成：A.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，反式-2-己烯醛和顺式-3-己烯醇组成的物质组合物; B.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物; C.基本上由顺式-3-己烯醛，顺式-3-己烯基 - 顺式-3-己烯酸酯，顺式-3-己烯醇，顺式-3-己烯甲酸酯和反式-2-己烯醛组成的物质组合物。 和D.Cis-3-己烯基甲基醚。

公开(公告)号：US4211242A

公开(公告)日：1980-07-08

申请号：US851727

申请日：1977-11-15

申请人： Braja D. Mookherjee ,  Robert W. Trenkle ,  Richard A. Wilson ,  Frederick L. Schmitt ,  Manfred H. Vock ,  Edward J. Granda ,  Joacquin Vinals ,  Jacob Kiwala ,  William L. Schreiber

发明人： Braja D. Mookherjee ,  Robert W. Trenkle ,  Richard A. Wilson ,  Frederick L. Schmitt ,  Manfred H. Vock ,  Edward J. Granda ,  Joacquin Vinals ,  Jacob Kiwala ,  William L. Schreiber

IPC分类号： A23L27/20 ,  A23L27/29 ,  A24B3/12 ,  A24B15/34 ,  A61K8/00 ,  A61K8/35 ,  A61Q11/00 ,  A61Q13/00 ,  C07C45/67 ,  C07C45/69 ,  C07C45/72 ,  C07C49/543 ,  C07C49/573 ,  C07C67/00 ,  C07C401/00 ,  C07C403/00 ,  C07C403/16 ,  C11B9/00

CPC分类号： C11D3/0084 ,  A24B15/34 ,  C07C403/16 ,  C07C45/67 ,  C07C45/69 ,  C07C45/72 ,  C07C49/543 ,  C07C49/573 ,  C11B9/0034 ,  C07B2200/09 ,  C07C2101/16

摘要： Described is a process for augmenting or enhancing the aroma and taste of a smoking tobacco comprising adding to said smoking tobacco an organoleptic property modifying quantity of a composition of matter comprising more than 50% trans,trans-.DELTA.-damascone and in addition a process for augmenting or enhancing the aroma and taste of a smoking tobacco comprising adding to said smoking tobacco in an organoleptic property modifying quantity a product produced according to the process of (i) reacting 1-alpha-acetyl-2-alpha,6,6-trimethyl-3-cyclohexene with strong base in aqueous ethanol at reflux thereby producing 1-alpha-acetyl-2-beta,6,6-trimethyl-3-cyclohexene; (ii) reacting the 1-alpha-acetyl-2-beta,6,6-trimethyl-3-cyclohexene with n-methyl aniline Grignard thereby forming a first organometallic compound; (iii) reacting said first organometallic compound with acetaldehyde thereby forming a second organometallic compound; (iv) reacting said second organometallic compound with acid in order to hydrolyze said second organometallic compound thereby forming a hydroxy ketone having the structure: ##STR1## in admixture with other compounds; (v) dehydrating said hydroxy ketone in admixture with other compounds thereby forming a mixture having a major proportion of trans, trans-.DELTA.-damascone having the structure: ##STR2## in admixture with cis, trans-.DELTA.-damascone having the structure: ##STR3## and in admixture with other compounds; and in addition smoking tobacco products containing same.

摘要翻译： 描述了一种用于增强或增强吸烟烟草的香气和味道的方法，包括向所述吸烟烟草中添加包含超过50％反式，反式 - △ - 马斯酮酮的物质组合物的感官特性改性量，另外还包括 增加或增强烟草的香气和味道，其包括向所述吸烟烟草中加入感官特性调节量，根据以下方法生产的产物：（i）使1-α-乙酰基-2-α，6,6-三甲基 -3-环己烯与强碱在乙醇水溶液中反应，从而产生1-α-乙酰基-2-β，6,6-三甲基-3-环己烯; （ii）使1-α-乙酰基-2-β6,6-三甲基-3-环己烯与正甲基苯胺格氏试剂反应，从而形成第一有机金属化合物; （iii）使所述第一有机金属化合物与乙醛反应，从而形成第二有机金属化合物; （iv）使所述第二有机金属化合物与酸反应以水解所述第二有机金属化合物，从而形成具有以下结构的羟基酮：与其它化合物混合; （v）使所述羟基酮与其它化合物混合，从而形成具有以下结构的具有以下结构的具有以下结构的反式，反式 - 三氯乙酸 - 马来酰肼的主要比例的混合物：＆lt; IMAGE＆gt;与具有以下结构的顺式，反式 - IMAGE>并与其他化合物混合; 以及含有相同烟草制品的烟草制品。

公开(公告)号：US4198309A

公开(公告)日：1980-04-15

申请号：US23443

申请日：1979-03-23

申请人： Braja D. Mookherjee ,  Robert W. Trenkle ,  Richard A. Wilson ,  Frederick L. Schmitt ,  Manfred H. Vock ,  Edward J. Granda ,  Joaquin Vinals ,  Jacob Kiwala ,  William L. Schreiber

发明人： Braja D. Mookherjee ,  Robert W. Trenkle ,  Richard A. Wilson ,  Frederick L. Schmitt ,  Manfred H. Vock ,  Edward J. Granda ,  Joaquin Vinals ,  Jacob Kiwala ,  William L. Schreiber

IPC分类号： A24B15/34 ,  C07C45/67 ,  C07C45/69 ,  C07C45/72 ,  C07C49/543 ,  C07C49/573 ,  C11B9/00 ,  C11D3/50 ,  C11D9/44

CPC分类号： C11D3/0084 ,  A24B15/34 ,  C07C403/16 ,  C07C45/67 ,  C07C45/69 ,  C07C45/72 ,  C07C49/543 ,  C07C49/573 ,  C11B9/0034 ,  C07B2200/09 ,  C07C2101/16

摘要： Described is a process for augmenting or enhancing the aroma of a nonionic, anionic or cationic solid or liquid detergent comprising the step of intimately admixing with a solid or liquid anionic, cationic or nonionic detergent base a composition comprising from about 80% up to about 98% of trans, trans-delta-damascone and from about 2% up to about 20% of cis, trans-delta-damascone or substantially pure trans, trans-delta-damascone.

摘要翻译： 描述了用于增强或增强非离子，阴离子或阳离子固体或液体洗涤剂香气的方法，其包括与固体或液体阴离子，阳离子或非离子洗涤剂基质紧密混合的步骤，该组合物包含约80％至约98 ％，反式三角洲大马士革和约2％至约20％的顺式，反式δ-大黄酮或基本上纯的反式，跨三角大黄素。