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1.发明授权Trans,trans-.DELTA.-damascone, mixtures containing major proportions of same, processes for preparing same and organoleptic uses thereof 失效反式，反式DELTA-哈马斯酮，主要比例相同的混合物，制备方法和感官用途
公开(公告)号：US4334098A
公开(公告)日：1982-06-08
申请号：US23323
申请日：1979-03-23
申请人： Braja D. Mookherjee , Robert W. Trenkle , Richard A. Wilson , Frederick L. Schmitt , Manfred H. Vock , Edward J. Granda , Joaquin Vinals , Jacob Kiwala , William L. Schreiber
发明人： Braja D. Mookherjee , Robert W. Trenkle , Richard A. Wilson , Frederick L. Schmitt , Manfred H. Vock , Edward J. Granda , Joaquin Vinals , Jacob Kiwala , William L. Schreiber
IPC分类号： A24B15/34 , C07C45/67 , C07C45/69 , C07C45/72 , C07C49/543 , C07C49/573 , C07C403/00 , C11B9/00 , C07C45/66 , C07C45/45
CPC分类号： C11D3/0084 , A24B15/34 , C07C403/16 , C07C45/67 , C07C45/69 , C07C45/72 , C07C49/543 , C07C49/573 , C11B9/0034 , C07B2200/09 , C07C2101/16
摘要： Described is the compound trans, trans-.DELTA.-damascone and mixtures of trans, trans-.DELTA.-damascone and its isomer, cis, trans-.DELTA.-damascone is in a major proportion, a process for preparing same and processes for adding such trans, trans-.DELTA.-damascone or such mixtures containing high proportions of trans, trans-.DELTA.-damascone to consumable materials whereby:(i) In foodstuffs, medicinal products, chewing gums, toothpastes and chewing tobacco, sweet, floral, rose-like, raspberry-like, fruity, cooked plum, grape juice-like, apple juice-like and winey aroma and flavor characteristics are augmented or enhanced;(ii) In perfumes, perfumed articles and colognes, rose, berry, apple, green and sweet floral notes are imparted, augmented and/or enhanced; and(iii) In tobaccos, tobacco flavor, substitute tobaccos and substitute tobacco flavor and aroma imparting, enhancing or augmenting compositions, floral, musty, hay-tea-like, sweet and fruity aroma and taste nuances both prior to and on smokingand flavor compositions and perfume compositions containing trans, trans-.DELTA.-damascone and mixtures containing a high proportion of trans, trans-.DELTA.-damascone and a low proportion of cis, trans-.DELTA.-damascone or no cis, trans-.DELTA.-damascone.
摘要翻译： 描述了化合物反式，反式 - DELTA-马来酰肼和反式，反式 - DELTA-马来昔酮及其异构体的混合物，顺式，反式 - DELTA-阿糖胞苷是主要的比例，其制备方法和加入这种反式， （DELTA） - 大马士革或含有高比例的反式，反式 - DELTA-哈司斯坦消费材料的混合物，其中：（i）在食品，药用产品，口香糖，牙膏和咀嚼烟草中，甜，花，玫瑰状，覆盆子 果实，水果，熟李子，葡萄汁，苹果汁和葡萄酒的香气和风味特征得到增强或增强; （ii）在香水，香水制品和古龙水，玫瑰，浆果，苹果，绿色和甜美的花香纸被赋予，增强和/或增强; 和（iii）在烟草，烟草风味，烟草代用品和替代烟草香精和香气赋予，增强或增加组合物，花卉，霉味，干草样，甜味和果香香气和味道之间的吸烟和风味的细微差别 组合物和香料组合物，其含有反式，反式 - DELTA-马来酰肼和含有高比例的反式，反式 - DELTA-慢性阻滞剂和低比例的顺式，反式 - DELTA-慢性阻滞剂或不含顺式，
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2.发明授权Use of trans, trans-.DELTA.-damascone and mixtures containing 80% or more of trans, trans-.DELTA.-damascone in augmenting or enhancing the aroma of a detergent 失效使用反式，反式DELTA-哈马斯酮和含有80％或更多的反式，反 - DELTA-哈马斯酮的混合物以增强或增强洗涤剂的香味
公开(公告)号：US4198309A
公开(公告)日：1980-04-15
申请号：US23443
申请日：1979-03-23
申请人： Braja D. Mookherjee , Robert W. Trenkle , Richard A. Wilson , Frederick L. Schmitt , Manfred H. Vock , Edward J. Granda , Joaquin Vinals , Jacob Kiwala , William L. Schreiber
发明人： Braja D. Mookherjee , Robert W. Trenkle , Richard A. Wilson , Frederick L. Schmitt , Manfred H. Vock , Edward J. Granda , Joaquin Vinals , Jacob Kiwala , William L. Schreiber
IPC分类号： A24B15/34 , C07C45/67 , C07C45/69 , C07C45/72 , C07C49/543 , C07C49/573 , C11B9/00 , C11D3/50 , C11D9/44
CPC分类号： C11D3/0084 , A24B15/34 , C07C403/16 , C07C45/67 , C07C45/69 , C07C45/72 , C07C49/543 , C07C49/573 , C11B9/0034 , C07B2200/09 , C07C2101/16
摘要： Described is a process for augmenting or enhancing the aroma of a nonionic, anionic or cationic solid or liquid detergent comprising the step of intimately admixing with a solid or liquid anionic, cationic or nonionic detergent base a composition comprising from about 80% up to about 98% of trans, trans-delta-damascone and from about 2% up to about 20% of cis, trans-delta-damascone or substantially pure trans, trans-delta-damascone.
摘要翻译： 描述了用于增强或增强非离子，阴离子或阳离子固体或液体洗涤剂香气的方法，其包括与固体或液体阴离子，阳离子或非离子洗涤剂基质紧密混合的步骤，该组合物包含约80％至约98 ％，反式三角洲大马士革和约2％至约20％的顺式，反式δ-大黄酮或基本上纯的反式，跨三角大黄素。
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3.发明授权Use in smoking tobacco compositions and smoking tobacco articles of 1-acyl-2,6,6-trimethylcyclohexene derivatives 失效用于吸烟烟草组合物和吸烟烟草制品的1-酰基-2,6,6-三甲基环己烯衍生物
公开(公告)号：US4215704A
公开(公告)日：1980-08-05
申请号：US39158
申请日：1979-05-15
申请人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
发明人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
CPC分类号： A24B15/34
摘要： A process is described for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of adding to smoking tobacco a composition consisting essentially of an organoleptic modifying quantity of at least one 1-acetyl-2,2,6-trimethylcyclohexene having a structure selected from the group consisting of: ##STR1## also described are smoking tobacco articles comprising smoking tobacco and in intimate contact with said smoking tobacco a composition containing an organoleptic property modifying quantity of at least one 1-acetyl-2,6,6-cyclohexene derivative having a structure selected from the group consisting of: ##STR2##
摘要翻译： 描述了一种用于增强或增强吸烟烟草的香气或味道的方法，包括以下步骤：向吸烟烟草添加组合物，该组合物基本上由至少一种具有至少一种1-乙酰基-2,2,6-三甲基环己烯的感官改性量组成，其具有 结构选自：
+ TR 还描述了包括吸烟烟草和与所述吸烟烟草紧密接触的吸烟烟草制品，该组合物含有感官特性修饰量的至少一种1-乙酰基-2 ，具有选自以下的结构的6,6-环己烯衍生物：＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt; -
4.发明授权Detergent compositions containing 1-acyl-2,6,6-trimethylcyclohexene derivatives and processes for preparing same 失效含有1-酰基-2,6,6-三甲基环己烯衍生物的洗涤剂组合物及其制备方法
公开(公告)号：US4210553A
公开(公告)日：1980-07-01
申请号：US39194
申请日：1979-05-15
申请人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
发明人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
CPC分类号： C07C403/16 , A24B15/34 , C07C45/42 , C07C45/62 , C11B9/0034 , C11D3/50 , C07C2101/16
摘要： Described is a process for augmenting or enhancing the aroma of solid or liquid anionic, cationic or nonionic detergent compositions comprising adding to a solid or liquid anionic, cationic or nonionic detergent base, an aroma augmenting or enhancing quantity of at least one of the compounds having a structure: ##STR1## whereby sweet, floral, fruity, rose-like, minty/camphoraceous aromas with floral, hay-like, musty backgrounds and tobacco nuances are augmented, enhanced or imparted.
摘要翻译： 描述了一种用于增强或增强固体或液体阴离子，阳离子或非离子洗涤剂组合物的香气的方法，其包括向固体或液体阴离子，阳离子或非离子洗涤剂基质中加入香气增强或增强量的至少一种具有 一种结构：
增加，增强或赋予甜美，花香，水果，玫瑰状，微小/樟脑香味的花香，干草样，发霉的背景和烟草的细微差别。 -
5.发明授权Perfume compositions containing 1-acyl-2,6,6-trimethylcyclohexene derivatives 失效含有1-酰基-2,6,6-三甲基环己烯衍生物的香料组合物
公开(公告)号：US4217252A
公开(公告)日：1980-08-12
申请号：US039193
申请日：1979-05-15
申请人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
发明人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
CPC分类号： C07C403/16 , A24B15/34 , C07C45/42 , C07C45/62 , C11B9/0034 , C11D3/50 , C07C2101/16 , Y10S514/97 , Y10S514/975
摘要： Described is a process for augmenting or enhancing the aroma of a perfume composition as well as perfume and cologne compositions containing a mixture consisting essentially of compounds having the structures: ##STR1## and wherein the mixture contains 30% of the compounds having the structures; ##STR2## and 60% of the compound having the structure: ##STR3##
摘要翻译： 描述了一种用于增强或增强香料组合物香气的方法，以及包含基本上由具有以下结构的化合物组成的混合物的香料和科隆组合物：其中混合物含有30％的化合物 具有结构; ＆lt; IMAGE＆gt;和60％具有以下结构的化合物：
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6.发明授权Process for augmenting or enhancing the aroma or taste of a foodstuff by adding to a foodstuff a mixture of 1-acyl-2,6,6-trimethylcyclohexene derivatives 失效通过向食品中加入1-酰基-2,6,6-三甲基环己烯衍生物的混合物来增加或增强食品的香气或味道的方法
公开(公告)号：US4209542A
公开(公告)日：1980-06-24
申请号：US39360
申请日：1979-05-15
申请人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
发明人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
CPC分类号： C11D3/50 , A24B15/34 , C07C45/42 , C07C45/62 , C11B9/0034
摘要： Described is a process for augmenting or enhancing the aroma or taste of a foodstuff by adding to said foodstuff a mixture of compounds having the structures: ##STR1## wherein said mixture contains 30% of the compounds having the structures: ##STR2## and 60% of the compound having the structure: ##STR3##
摘要翻译： 描述了通过向所述食品中加入具有以下结构的化合物的混合物来增强或增强食品的香味或味道的方法：其中所述混合物含有30％的具有以下结构的化合物：
和具有以下结构的化合物的60％： -
7.发明授权1-Acyl-2,6,6-trimethylcyclohexene derivatives, processes for producing same, intermediates therefor and organoleptic uses thereof 失效1-酰基-2,6,6-三甲基环己烯衍生物，其制备方法，其中间体及其感官用途
公开(公告)号：US4196306A
公开(公告)日：1980-04-01
申请号：US39153
申请日：1979-05-15
申请人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
发明人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
CPC分类号： C07C403/16 , A24B15/34 , C07C45/42 , C07C45/62 , C11B9/0034 , C11D3/50 , C07C2101/16
摘要： Process intermediates are described herein having the generic structure: ##STR1## wherein X is selected from the group consisting of chloro, bromo and iodo; R.sub.3 is hydrogen or does not represent any group; wherein one of the wavy lines is a carbon-carbon double bond and the other of the wavy lines is a carbon-carbon single bond; with the proviso that when the .DELTA..sup.2,3 bond is a carbon-carbon double bond, then R.sub.3 is hydrogen and R.sub.3 and the moiety: ##STR2## are so juxtaposed that the molecule having the structure: ##STR3## exists in two different isomeric forms; a "+" form and "-" form.
摘要翻译： 本文描述了具有通用结构的方法中间体：其中X选自氯，溴和碘; R3是氢或不表示任何基团; 其中波浪线之一是碳 - 碳双键，另一条波浪线是碳 - 碳单键; 条件是当DELTA 2,3键是碳 - 碳双键时，则R3是氢，R3和部分：＆lt; IMAGE＆gt;与以下结构并列：具有以下结构的分子：
存在于两种不同的异构体 形式; 一个“+”形式和“ - ”形式。 -
8.发明授权1-Acyl-2,6,6-trimethylcyclohexene derivatives, processes for producing same, intermediates therefor and organoleptic uses thereof 失效1-酰基-2,6,6-三甲基环己烯衍生物，其制备方法，其中间体及其感官用途
公开(公告)号：US4172850A
公开(公告)日：1979-10-30
申请号：US965418
申请日：1978-12-01
申请人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
发明人： Robert W. Trenkle , Braja D. Mookherjee , Robin Kasper , Manfred H. Vock , Joaquin Vinals , Jacob Kiwala , Frederick L. Schmitt
CPC分类号： C07C403/16 , A24B15/34 , C07C45/42 , C07C45/62 , C11B9/0034 , C11D3/50 , C07C2101/16
摘要： Described is a process for preparing several 1-acyl-2,6,6-trimethylcyclohexene derivatives defined by the generic structure: ##STR1## wherein R.sub.1 is hydrogen or ethylidene having the structure:[H.sub.3 C--C.dbd. ;R.sub.2 is hydrogen or no group; one of the wavy lines is a carbon-carbon double bond and the other of the wavy lines is a carbon-carbon single bond; with the proviso that when the .DELTA..sup.2,3 bond (as shown by the wavy line between the "2" and the "3" position of the ring) is a carbon-carbon double bond, then R.sub.2 is hydrogen and R.sub.2 and the moiety: ##STR2## are so juxtaposed that the molecule having the structure: ##STR3## exists in two different isomeric forms, a "+" form and a "-" form, using as a precursor, 2,6,6-trimethyl-1-acetyl-1,3-cyclohexadiene having the structure: ##STR4##
摘要翻译： 描述了制备由以下通式结构定义的若干个1-酰基-2,6,6-三甲基环己烯衍生物的方法：其中R 1是氢或具有以下结构的亚乙基：
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9.发明授权Use of novel oxyhydrocarbylnorbornane derivatives for augmenting or enhancing the aroma of detergents 失效新型羟基烃基降冰片烷衍生物用于增强或增强洗涤剂的香气
公开(公告)号：US4208297A
公开(公告)日：1980-06-17
申请号：US32900
申请日：1979-04-24
申请人： Kenneth K. Light , James M. Sanders , Manfred H. Vock , Edward J. Shuster , Joaquin Vinals , William L. Schreiber , John B. Hall , Denis E. Hruza, Sr. , Venkatesh Kamath , Braja D. Mookherjee , Ching Y. Tseng , Mark A. Sprecker
发明人： Kenneth K. Light , James M. Sanders , Manfred H. Vock , Edward J. Shuster , Joaquin Vinals , William L. Schreiber , John B. Hall , Denis E. Hruza, Sr. , Venkatesh Kamath , Braja D. Mookherjee , Ching Y. Tseng , Mark A. Sprecker
IPC分类号： A23L27/20 , C07C31/137 , C07D303/04 , C11B9/00 , C11D3/50 , C11D9/44
CPC分类号： C11D3/0084 , A23L27/203 , C07C31/137 , C07D303/04 , C11B9/0046 , C11D3/50
摘要： Described is a process for augmenting or enhancing the aroma of a solid or liquid anionic, cationic or nonionic detergent comprising the step of intimately admixing with a solid or liquid cationic, anionic or nonionic detergent base and aroma augmenting or enhancing quantity of at least oxyhydrocarbylnorbornane having the structure: ##STR1## wherein X is carbonyl or carbinyl having the structures, respectively: ##STR2## and wherein at least one of the dashed lines is a carbon-carbon single bond and the other of the dashed lines is a carbon-carbon single bond or a carbon-carbon double bond.
摘要翻译： 描述了一种用于增强或增强固体或液体阴离子，阳离子或非离子洗涤剂的香味的方法，其包括与固体或液体阳离子，阴离子或非离子洗涤剂基质紧密混合的步骤和增强或增加至少含有羟基烃基降冰片烷的步骤，其具有 其结构：其中X是具有以下结构的羰基或碳基：分别为：＆lt; IMAGE＆gt;其中至少一个虚线为碳 - 碳单键，另一个虚线为碳 - 碳单键 键或碳 - 碳双键。
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公开(公告)号：US4136208A
公开(公告)日：1979-01-23
申请号：US860137
申请日：1977-12-13
申请人： Kenneth K. Light , James M. Sanders , Manfred H. Vock , Edward J. Shuster , Joaquin Vinals , William L. Schreiber , John B. Hall , Denis E. Hruza, Sr. , Venkatesh Kamath , Braja D. Mookherjee , Ching Y. Tseng , Mark A. Sprecker
发明人： Kenneth K. Light , James M. Sanders , Manfred H. Vock , Edward J. Shuster , Joaquin Vinals , William L. Schreiber , John B. Hall , Denis E. Hruza, Sr. , Venkatesh Kamath , Braja D. Mookherjee , Ching Y. Tseng , Mark A. Sprecker
IPC分类号： A23L27/20 , A24B15/34 , A24D3/14 , C07C29/09 , C07C29/17 , C07C29/40 , C07C29/42 , C07C29/68 , C07C31/137 , C07C33/12 , C07C45/29 , C07C45/30 , C07C45/58 , C07C45/62 , C07C45/66 , C07C45/67 , C07C45/68 , C07C45/74 , C07C49/323 , C07C49/35 , C07C49/557 , C07C49/577 , C07D301/14 , C07D303/04 , C11B9/00 , C11D3/50 , C11D9/44 , A23L1/226
CPC分类号： C11D3/0084 , A23L27/203 , A24B15/345 , A24D3/14 , C07C29/09 , C07C29/17 , C07C29/40 , C07C29/42 , C07C29/68 , C07C31/137 , C07C33/12 , C07D301/14 , C07D303/04 , C11B9/0046 , C11D3/50 , C11D9/442 , C07C2102/42 , Y10S514/974
摘要： Norbornane Derivatives are used in foodstuffs and flavorings. Specifically, 3,3-dimethyl-2-pentanoylnorbornane and 2-butyrl-3,3-dimethylnorbornane are used.
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