公开(公告)号：US06677265B1

公开(公告)日：2004-01-13

申请号：US09595634

申请日：2000-06-16

申请人： Brian Kneale ,  James E. Boone ,  Steven P. Diefenbach ,  Cecil P. Loechelt ,  John C. Prindle, Jr.

发明人： Brian Kneale ,  James E. Boone ,  Steven P. Diefenbach ,  Cecil P. Loechelt ,  John C. Prindle, Jr.

IPC分类号： C08F402

CPC分类号： C08F10/02 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/02 ,  C08F2/06 ,  C08F4/6492 ,  C08F2500/18

摘要： The process features concurrent feeds into the liquid phase of a prepolymerization reaction mixture. These feeds are: a) separate continuous or substantially continuous feeds of (i) a polymerizable vinylolefin, and (ii) a solution in an organic liquid solvent of a metallocene and an aluminoxane and/or metallocene-aluminoxane reaction product; or b) separate continuous or substantially continuous feeds of (i) a polymerizable vinylolefin, (iii) a metallocene optionally in an organic liquid solvent or diluent, and (iv) an aluminoxane optionally in an organic liquid solvent or diluent; or c) separate continuous or substantially continuous feeds of (i) and (ii) and at least one of (iii) and (iv). Particles of catalytically-active, prepolymerized, self-supported olefin polymerization catalyst composition are formed in the reaction medium. The metallocene used as the feed or in making up the feed has at least one polymerizable olefinic substituent in the molecule.

摘要翻译： 该方法同时进料到预聚合反应混合物的液相中。 这些进料是：a）分离的连续或基本上连续的进料，其中（i）可聚合的含氟烯烃，和（ii）金属茂和铝氧烷和/或茂金属 - 铝氧烷反应产物的有机液体溶剂中的溶液; （i）可聚合的烯烃，（iii）任选在有机液体溶剂或稀释剂中的茂金属，和（iv）任选在有机液体溶剂或稀释剂中的铝氧烷的连续或基本上连续的进料; （i）和（ii）和（iii）和（iv）中的至少一种的单独的连续或基本上连续的进料。在反应介质中形成催化活性的，预聚合的，自负载的烯烃聚合催化剂组合物的颗粒 。 用作原料或用于补充原料的茂金属在分子中具有至少一个可聚合的烯属取代基。

公开(公告)号：US06198003B1

公开(公告)日：2001-03-06

申请号：US09295622

申请日：1999-04-20

申请人： Kaung-Far Lin ,  James E. Boone ,  Michael D. Matthews ,  John C. Prindle, Jr. ,  Sharon D. Booth McGee

发明人： Kaung-Far Lin ,  James E. Boone ,  Michael D. Matthews ,  John C. Prindle, Jr. ,  Sharon D. Booth McGee

IPC分类号： C07C31908

CPC分类号： C07C319/14 ,  C07C319/08 ,  C07C321/04 ,  C07C321/14

摘要： A highly efficient method of producing alkyl mercaptan and/or dialkyl monosulfides which involves employing carbon dioxide as an internal coolant is described. Only negligible amounts of carbonyl sulfide were formed. In addition, relatively easy separation of carbon dioxide from the reaction mixture facilitates an efficient coolant recycle process, giving a simple and effective mode of temperature control.

摘要翻译： 描述了使用二氧化碳作为内部冷却剂的高效制备烷基硫醇和/或二烷基一硫化物的方法。 仅形成可忽略量的羰基硫化物。 此外，相对容易地从反应混合物中分离二氧化碳有助于有效的冷却剂再循环过程，提供简单且有效的温度控制模式。

公开(公告)号：US06469212B1

公开(公告)日：2002-10-22

申请号：US09531210

申请日：2000-03-20

申请人： John C. Prindle, Jr. ,  Michael W. Easson ,  James Dee Palmer ,  Jason G. Jones ,  Max K. Mortensen ,  James E. Boone

发明人： John C. Prindle, Jr. ,  Michael W. Easson ,  James Dee Palmer ,  Jason G. Jones ,  Max K. Mortensen ,  James E. Boone

IPC分类号： C07C20900

CPC分类号： C07C209/86 ,  C07C211/50

摘要： A mixture comprised of about 60-85% of 2,4-toluenediamine (2,4-TDA) and about 15-40% of 2,6-toluenediamine (2,6-TDA) is melted, the temperature of the mixture is lowered to a 2,4-TDA nucleation temperature, and the temperature of the mixture is gradually reduced from the nucleation temperature to about 65 to about 70° C. The resultant mixture is in the form of a solids phase enriched in 2,4-TDA, and a novel and useful liquid phase enriched in 2,6-TDA. These phases are separated. Preferably the solids are further purified by “sweating” them and removing the sweated liquid impurities. The sweated liquid can be recycled together with another charge of a mixture comprised of 2,4-TDA and 2,6-TDA. 2,4-TDA can be produced with a purity of 96-99%.

摘要翻译： 将由约60-85％的2,4-甲苯二胺（2,4-TDA）和约15-40％的2,6-甲苯二胺（2,6-TDA）组成的混合物熔化，混合物的温度为 降低至2,4-TDA成核温度，并且混合物的温度从成核温度逐渐降低至约65至约70℃。所得混合物为富含2,4-二甲酸的固体相的形式， TDA，以及富含2,6-TDA的新型有用的液相。 这些阶段是分开的。 优选地，通过将​​它们“出汗”并除去出汗的液体杂质来进一步纯化固体。 可以将出汗的液体与另一种由2,4-TDA和2,6-TDA组成的混合物一起再循环。 可以生产纯度为96-99％的2,4-TDA。

公开(公告)号：US5811470A

公开(公告)日：1998-09-22

申请号：US921205

申请日：1997-08-27

申请人： John C. Prindle, Jr. ,  Christopher J. Nalepa ,  Govindarajulu Kumar

发明人： John C. Prindle, Jr. ,  Christopher J. Nalepa ,  Govindarajulu Kumar

IPC分类号： C08K5/36 ,  C08J9/04 ,  C08K3/06 ,  C08K5/49 ,  C08K13/02 ,  C08L25/02 ,  C08L25/04 ,  C08K5/5397 ,  C08K5/50 ,  C08K5/523 ,  C08K5/5317

CPC分类号： C08K3/06 ,  C08K5/49

摘要： Compositions and methods are described wherein a styrenic polymer is rendered flame retardant by incorporation therein before, during or after its formation, a combination of (a) at least one organic phosphorus additive that (i) is halogen-free, and (ii) is composed solely of carbon, hydrogen, and phosphorus, and optionally and preferably one or more of the elements nitrogen, oxygen, and sulfur; and (b) elemental sulfur; in proportions such that (i) the sulfur content from b) is less than 2 percent by weight of the weight of the styrenic polymer plus the weight of a) and b), and (ii) the styrenic polymer plus ingredients a) and b) can provide test specimens which exhibit an LOI of at least 24 if tested in accordance with ASTM Standard Test Method D 2863-87.

摘要翻译： 描述了组合物和方法，其中苯乙烯类聚合物通过在其形成之前，期间或之后并入其中而形成阻燃剂，（a）至少一种有机磷添加剂（i）不含卤素，和（ii） 仅由碳，氢和磷组成，并且任选且优选地包括氮，氧和硫中的一种或多种元素; 和（b）元素硫; 其比例使得（i）b）中的硫含量小于苯乙烯聚合物重量的2重量％加上a）和b）的重量，和（ii）苯乙烯聚合物加成分a）和b ）可以提供根据ASTM标准测试方法D 2863-87测试的显示LOI至少为24的测试样品。

公开(公告)号：US06509434B1

公开(公告)日：2003-01-21

申请号：US09528837

申请日：2000-03-20

申请人： William R. Brown ,  John C. Prindle, Jr. ,  Gregory H. Lambeth

发明人： William R. Brown ,  John C. Prindle, Jr. ,  Gregory H. Lambeth

IPC分类号： C08G1832

CPC分类号： C08G18/3868 ,  C08G18/10

摘要： Mixtures of isomeric alkylthiated mononuclear aromatic amines comprising in the range of about 30 to about 70 mole percent of (i) at least one 3,5-di(alkyl-thio)-2,6-diamino-1-alkylbenzene and in the range of about 30 to about 70 mole percent of at least one 3,5-di(alkylthio)-2,4-diamino-1-alkylbenzene, such mixture containing at least about 90 mole percent of (i) and (ii), and optionally containing up to 10 mole percent of one or more isomers of (i) and/or (ii). An alkyl group may be present as a substituent in lieu of a hydrogen atom in the remaining ring position. These mixtures are useful as curatives or extenders in processes for making polyurethanes, polyurethane-ureas, and polyureas.

摘要翻译： 异构烷基化的单核芳香族胺的混合物，其包含（i）至少一种3,5-二（烷基 - 硫代）-2,6-二氨基-1-烷基苯的约30至约70摩尔％范围内， 约30至约70摩尔％的至少一种3,5-二（烷硫基）-2,4-二氨基-1-烷基苯，该混合物含有至少约90摩尔％的（ⅰ）和（ⅱ），和 任选地含有至多10摩尔％的（i）和/或（ii）的一种或多种异构体。 烷基可以作为取代基代替其余环位置上的氢原子。 这些混合物可用作制备聚氨酯，聚氨酯 - 脲和聚脲的方法中的固化剂或增量剂。