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1.发明授权Coated metal substrates and methods for preparing and inhibiting corrosion of the same 有权涂覆金属基材及其制备和抑制其腐蚀的方法公开(公告)号：US06312812B1
公开(公告)日：2001-11-06
申请号：US09469259
申请日：1999-12-21
IPC分类号： B32B2736
CPC分类号： B05D7/51 , B05D7/14 , B05D7/16 , B05D7/54 , B05D2202/10 , B05D2701/40 , B23K35/226 , C08G59/18 , C08G59/4071 , C08G59/50 , C08G59/56 , C09D5/082 , C09D5/084 , C09D5/24 , C23C2/26 , C23C22/34 , C23C22/48 , C23C22/83 , C23C28/00 , C23C30/00 , C25D13/20 , Y10T428/31507
摘要： The present invention provides a metal substrate coated with a first pretreatment composition including a transition element-containing material having one or more Group IIIB elements, Group IVB elements, lanthanide series elements or mixtures thereof; and a second pretreatment composition including a reaction product of at least one epoxy-functional material or derivative thereof and at least phosphorus-containing material, amine-containing material and/or sulfur-containing material deposited upon the first pretreatment composition. If desired, the first and second pretreatment compositions can be combined into a single pretreatment.
摘要翻译： 本发明提供涂覆有第一预处理组合物的金属基材，其包含含有一种或多种IIIB族元素，IVB族元素，镧系元素或其混合物的含过渡金属的材料; 以及第二预处理组合物，其包含至少一种环氧官能材料或其衍生物和至少含磷材料，沉积在第一预处理组合物上的含胺材料和/或含硫材料的反应产物。 如果需要，第一和第二预处理组合物可以组合成单一预处理。
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公开(公告)号：US06984674B2
公开(公告)日：2006-01-10
申请号：US10803391
申请日：2004-03-18
申请人： Ralph C. Gray , Ellor James Van Buskirk , Michael J. Pawlik , Richard M. Nugent, Jr. , Dennis W. Jones , Kathleen M. Coldren , Steven D. Perrine , James E. Jones
发明人： Ralph C. Gray , Ellor James Van Buskirk , Michael J. Pawlik , Richard M. Nugent, Jr. , Dennis W. Jones , Kathleen M. Coldren , Steven D. Perrine , James E. Jones
CPC分类号： B23K35/226 , C08G59/304 , C09D163/00
摘要： A curable coating composition is disclosed comprising a resinous binder comprising (a) a reaction product of an epoxy-containing polymer with a compound containing phosphorus acid groups, the reaction product having reactive functional groups, and (b) a curing agent having functional groups reactive with the functional groups of (a). An electroconductive pigment is dispersed in (a) such that the weight ratio of the electroconductive pigment to (a) plus (b) is within the range of 0.5 to 9.0:1. When the curable coating composition is deposited and cured on a metal substrate, the cured coating is weldable.
摘要翻译： 公开了一种可固化涂料组合物，其包含树脂粘合剂，其包含（a）含环氧基的聚合物与含有磷酸基团的化合物的反应产物，所述反应产物具有反应性官能团，和（b）具有官能团的固化剂反应性 与（a）的功能组。 导电性颜料分散在（a）中，导电性颜料与（a）加（b）的重量比在0.5〜9.0:1的范围内。 当可固化涂料组合物在金属基材上沉积和固化时，固化的涂层是可焊接的。
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3.发明授权公开(公告)号：US07282266B2
公开(公告)日：2007-10-16
申请号：US10882756
申请日：2004-06-30
申请人： Michael J. Pawlik , Dennis W. Jones , Ralph C. Gray , Richard M. Nugent, Jr. , Steven D. Perrine
发明人： Michael J. Pawlik , Dennis W. Jones , Ralph C. Gray , Richard M. Nugent, Jr. , Steven D. Perrine
IPC分类号： B32B15/092 , B32B27/38 , C08L63/00
CPC分类号： C09D5/08 , C08G59/1488 , C08G59/4071 , C09D163/00 , Y10T428/265 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31678 , C08L2666/16 , C08L2666/40
摘要： A corrosion resistant, alkali resistant coating composition is disclosed. The composition comprises a binder comprising a reaction product of an epoxy-containing material and a phosphorus-containing material together with a curing agent. Aminoplasts, especially melamine-based aminoplasts, are particularly suitable curing agents. A source of silicon can optionally be included. The compositions also provide excellent adhesion and can be used with or without a weldable primer. The compositions are applied to and cured on a metal substrate.
摘要翻译： 公开了耐腐蚀，耐碱的涂料组合物。 组合物包含含有含环氧材料和含磷材料与固化剂的反应产物的粘合剂。 氨基塑料，特别是三聚氰胺类氨基塑料，是特别合适的固化剂。 可以可选地包括硅源。 组合物还提供优异的粘合性，并且可以与或不与可焊接的底漆一起使用。 将组合物施加到金属基材上并在其上固化。
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4.发明授权Weldable, coated metal substrates and methods for preparing and inhibiting corrosion of the same 有权可焊接的涂覆金属基材及其制备和抑制其腐蚀的方法公开(公告)号：US06777034B2
公开(公告)日：2004-08-17
申请号：US10170856
申请日：2002-06-13
IPC分类号： B05D300
CPC分类号： C23C28/00 , B05D7/16 , B05D2701/40 , B23K35/226 , C08G59/4071 , C08G59/50 , C08G59/56 , C09D5/24 , Y10T428/12549 , Y10T428/1259 , Y10T428/12799 , Y10T428/31504 , Y10T428/31511 , Y10T428/31522 , Y10T428/31529 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： The present invention provides a weldable, coated metal substrate having a pretreatment coating including a reaction product of at least one epoxy-functional material and at least one phosphorus-containing material or amine-containing material and a weldable coating having an electroconductive pigment and a binder deposited thereon.
摘要翻译： 本发明提供了一种可焊接的涂覆金属基材，其具有预处理涂层，其包括至少一种环氧官能材料和至少一种含磷材料或含胺材料的反应产物和具有导电颜料和粘合剂的可焊接涂层 沉积在其上。
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5.发明授权Weldable coating of phosphated epoxy polymer, curing agent and electroconductive pigment 失效磷化环氧聚合物，固化剂和导电颜料的可焊接涂层公开(公告)号：US06750274B2
公开(公告)日：2004-06-15
申请号：US09858280
申请日：2001-05-16
申请人： Ralph C. Gray , Ellor James Van Buskirk , Michael J. Pawlik , Richard M. Nugent, Jr. , Dennis W. Jones , Kathleen M. Coldren , Steven D. Perrine , James E. Jones
发明人： Ralph C. Gray , Ellor James Van Buskirk , Michael J. Pawlik , Richard M. Nugent, Jr. , Dennis W. Jones , Kathleen M. Coldren , Steven D. Perrine , James E. Jones
IPC分类号： C08K304
CPC分类号： B23K35/226 , C08G59/304 , C09D163/00
摘要： A curable coating composition is disclosed comprising a resinous binder comprising (a) a reaction product of an epoxy-containing polymer with a compound containing phosphorus acid groups, the reaction product having reactive functional groups, and (b) a curing agent having functional groups reactive with the functional groups of (a). An electroconductive pigment is dispersed in (a) such that the weight ratio of the electroconductive pigment to (a) plus (b) is within the range of 0.5 to 9.0:1. When the curable coating composition is deposited and cured on a metal substrate, the cured coating is weldable.
摘要翻译： 公开了一种可固化涂料组合物，其包含树脂粘合剂，其包含（a）含环氧基的聚合物与含有磷酸基团的化合物的反应产物，所述反应产物具有反应性官能团，和（b）具有官能团的固化剂反应性 与（a）的功能组。 导电性颜料分散在（a）中，导电性颜料与（a）加（b）的重量比在0.5〜9.0:1的范围内。 当可固化涂料组合物在金属基材上沉积和固化时，固化的涂层是可焊接的。
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6.发明授权公开(公告)号：US06440580B1
公开(公告)日：2002-08-27
申请号：US09203833
申请日：1998-12-01
IPC分类号： B32B1508
CPC分类号： C23C28/00 , B05D7/16 , B05D2701/40 , B23K35/226 , C08G59/4071 , C08G59/50 , C08G59/56 , C09D5/24 , Y10T428/12549 , Y10T428/1259 , Y10T428/12799 , Y10T428/31504 , Y10T428/31511 , Y10T428/31522 , Y10T428/31529 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： The present invention provides a weldable, coated metal substrate having a pretreatment coating including a reaction product of at least one epoxy-functional material and at least one phosphorus-containing material or amine-containing material and a weldable coating having an electroconductive pigment and a binder deposited thereon.
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7.发明授权Layer of reaction product of epoxy and phosphorus materials and curing agent on substrate 有权环氧树脂和磷材料的反应产物层和基材上的固化剂层公开(公告)号：US07476444B2
公开(公告)日：2009-01-13
申请号：US11521823
申请日：2006-09-15
申请人： Michael J. Pawlik , Dennis W. Jones , Ralph C. Gray , Richard M Nugent, Jr. , Yves Le Disert , Laurent Deronne
发明人： Michael J. Pawlik , Dennis W. Jones , Ralph C. Gray , Richard M Nugent, Jr. , Yves Le Disert , Laurent Deronne
CPC分类号： C09D5/08 , C08G59/1488 , C08G59/4071 , C09D163/00 , Y10T428/265 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31678 , C08L2666/16 , C08L2666/40
摘要： A corrosion resistant, alkali resistant coating composition is disclosed. The composition comprises a binder comprising a reaction product of an epoxy-containing material and a phosphorus-containing material together with a curing agent. Aminoplasts, especially melamine-based aminoplasts, are particularly suitable curing agents. A source of silicon can optionally be included. The compositions also provide excellent adhesion and can be used with or without a weldable primer. The compositions are applied to and cured on a metal substrate.
摘要翻译： 公开了耐腐蚀，耐碱的涂料组合物。 组合物包含含有含环氧材料和含磷材料与固化剂的反应产物的粘合剂。 氨基塑料，特别是三聚氰胺类氨基塑料，是特别合适的固化剂。 可以可选地包括硅源。 组合物还提供优异的粘合性，并且可以与或不与可焊接的底漆一起使用。 将组合物施加到金属基材上并在其上固化。
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8.发明授权Aqueous composition of reaction product of epoxy and phosphorus materials with curing agent 有权环氧和磷材料与固化剂的反应产物的水性组成公开(公告)号：US07345101B2
公开(公告)日：2008-03-18
申请号：US11346484
申请日：2006-02-02
申请人： Michael J. Pawlik , Dennis W. Jones , Ralph C. Gray , Richard M. Nugent, Jr. , Yves Le Disert , Laurent Deronne
发明人： Michael J. Pawlik , Dennis W. Jones , Ralph C. Gray , Richard M. Nugent, Jr. , Yves Le Disert , Laurent Deronne
IPC分类号： C08K3/20 , C08L63/00 , C08L63/02 , C09D163/00 , C09D163/02
CPC分类号： C08G59/304 , C08G59/1488 , C09D5/08 , C09D5/084 , C09D163/00 , Y10T428/31511 , C08L2666/40
摘要： A corrosion resistant, alkali resistant coating composition is disclosed. The composition comprises a binder comprising a reaction product of an epoxy-containing material and a phosphorus-containing material together with a curing agent. Aminoplasts, especially melamine-based aminoplasts, are particularly suitable curing agents. A source of silicon can optionally be included. The compositions also provide excellent adhesion and can be used with or without a weldable primer. The compositions are applied to and cured on a metal substrate.
摘要翻译： 公开了耐腐蚀，耐碱的涂料组合物。 组合物包含含有含环氧材料和含磷材料与固化剂的反应产物的粘合剂。 氨基塑料，特别是三聚氰胺类氨基塑料，是特别合适的固化剂。 可以可选地包括硅源。 组合物还提供优异的粘合性，并且可以与或不与可焊接的底漆一起使用。 将组合物施加到金属基材上并在其上固化。
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9.发明授权公开(公告)号：US07141619B2
公开(公告)日：2006-11-28
申请号：US10880942
申请日：2004-06-30
申请人： Michael J. Pawlik , Dennis W. Jones , Ralph C. Gray , Richard M Nugent, Jr. , Yves Le Disert , Laurent Deronne
发明人： Michael J. Pawlik , Dennis W. Jones , Ralph C. Gray , Richard M Nugent, Jr. , Yves Le Disert , Laurent Deronne
CPC分类号： C09D5/08 , C08G59/1488 , C08G59/4071 , C09D163/00 , Y10T428/265 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31678 , C08L2666/16 , C08L2666/40
摘要： A corrosion resistant, alkali resistant coating composition is disclosed. The composition comprises a binder comprising a reaction product of an epoxy-containing material and a phosphorus-containing material together with a curing agent. Aminoplasts, especially melamine-based aminoplasts, are particularly suitable curing agents. A source of silicon can optionally be included. The compositions also provide excellent adhesion and can be used with or without a weldable primer. The compositions are applied to and cured on a metal substrate.
摘要翻译： 公开了耐腐蚀，耐碱的涂料组合物。 组合物包含含有含环氧材料和含磷材料与固化剂的反应产物的粘合剂。 氨基塑料，特别是三聚氰胺类氨基塑料，是特别合适的固化剂。 可以可选地包括硅源。 组合物还提供优异的粘合性，并且可以与或不与可焊接的底漆一起使用。 将组合物施加到金属基材上并在其上固化。
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公开(公告)号：US06187849B1
公开(公告)日：2001-02-13
申请号：US09276203
申请日：1999-03-25
IPC分类号： C08L9106
CPC分类号： C08K5/17 , C09D5/008 , C09D123/08 , C09D191/06 , C09D191/08 , C08L91/06 , C08L23/00
摘要： Disclosed is a temporary, protective dry lubricating coating composition which when deposited and dried on a metallic substrate, is removable by contacting with an aqueous alkaline cleaning solution. The coating composition comprises (a) a wax present in an amount up to 20 weight percent; (b) a base-neutralized, acid functional polymer which is the polymerization reaction product of (i) a polymerizable, ethylenically unsaturated monomer having acid functionality and (ii) at least one polymerizable, ethylenically unsaturated monomer different from (i); and (c) an amine containing an acyclic moiety of from 8 to 30 carbon atoms, the amine being different from the base used to neutralize the acid functional polymer (b). The temporary protective coating is compatible with a wide range of adhesives and sealants used in the assembly of automobiles.
摘要翻译： 公开了一种临时的保护性干润滑涂料组合物，其在金属基材上沉积和干燥时可通过与含水碱性清洁溶液接触来除去。 涂料组合物包含（a）以至多20重量％的量存在的蜡; （b）碱中和的酸官能聚合物，其是（i）具有酸官能团的可聚合的烯属不饱和单体和（ii）至少一种不同于（i）的可聚合的烯属不饱和单体的聚合反应产物; 和（c）含有8至30个碳原子的无环部分的胺，所述胺不同于用于中和酸官能聚合物（b）的碱。 临时保护涂层与汽车组装中使用的各种粘合剂和密封剂相兼容。
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