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1.
公开(公告)号:US11135575B2
公开(公告)日:2021-10-05
申请号:US15928690
申请日:2018-03-22
Applicant: Chevron U.S.A. Inc.
Inventor: Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Cho Timken , Steven Xugi Song , Michael Sean Driver
IPC: C07C2/58 , B01J31/40 , B01J31/02 , B01J38/10 , C07C2/62 , C10L1/06 , C10G29/20 , C10G45/60 , C10G47/02 , C10G50/00 , B01J35/12 , C07C2/56
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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公开(公告)号:US10173194B2
公开(公告)日:2019-01-08
申请号:US15456863
申请日:2017-03-13
Applicant: Chevron U.S.A. Inc.
Inventor: Huping Luo , Arthur William Etchells, III , Donald Henry Mohr , Hye Kyung Cho Timken , Moinudden Ahmed , Krishniah Parimi , Bong Kyu Chang , Michael John Girgis
IPC: B01J19/24 , B01J14/00 , C07C2/62 , B01F5/06 , B01F5/10 , B01F13/10 , C10G29/20 , B01D17/02 , B01J19/00 , B01J4/00 , B01F15/02
Abstract: We provide systems for ionic liquid catalyzed hydrocarbon conversion that comprise a modular reactor comprising a plurality of mixer modules. The mixer modules may be arranged in series. One or more feed modules are disposed between the mixer modules. Such systems may be used for ionic liquid catalyzed alkylation reactions. Processes for ionic liquid catalyzed hydrocarbon conversion are also disclosed.
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公开(公告)号:US20170197195A1
公开(公告)日:2017-07-13
申请号:US15456863
申请日:2017-03-13
Applicant: Chevron U.S.A. Inc.
Inventor: Huping Luo , Arthur William Etchells, III , Donald Henry Mohr , Hye Kyung Cho Timken , Moinudden Ahmed , Krishniah Parimi , Bong Kyu Chang , Michael John Girgis
CPC classification number: B01J19/24 , B01D17/0208 , B01F5/061 , B01F5/102 , B01F13/1016 , B01F2015/0221 , B01J4/004 , B01J14/00 , B01J19/006 , B01J19/245 , B01J2219/0002 , B01J2219/00777 , C07C2/62 , C10G29/205
Abstract: We provide systems for ionic liquid catalyzed hydrocarbon conversion that comprise a modular reactor comprising a plurality of mixer modules. The mixer modules may be arranged in series. One or more feed modules are disposed between the mixer modules. Such systems may be used for ionic liquid catalyzed alkylation reactions. Processes for ionic liquid catalyzed hydrocarbon conversion are also disclosed.
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4.
公开(公告)号:US20180207629A1
公开(公告)日:2018-07-26
申请号:US15928690
申请日:2018-03-22
Applicant: Chevron U.S.A. Inc.
Inventor: Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Timken , Steven Xugi Song , Michael Sean Driver
IPC: B01J31/40 , B01J35/12 , B01J38/10 , C10L1/06 , B01J31/02 , C07C2/62 , C10G29/20 , C10G50/00 , C10G47/02 , C10G45/60 , C07C11/16
CPC classification number: B01J31/40 , B01J31/0284 , B01J31/0298 , B01J35/12 , B01J38/10 , B01J2231/44 , C07C2/62 , C07C2531/02 , C10G29/205 , C10G45/60 , C10G47/02 , C10G50/00 , C10L1/06 , C10L2270/023 , C10L2290/12 , Y02P20/584 , C07C11/16
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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公开(公告)号:US09956552B2
公开(公告)日:2018-05-01
申请号:US15010168
申请日:2016-01-29
Applicant: Chevron U.S.A. Inc.
Inventor: Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Timken , Steven Xugi Song , Michael Sean Driver
IPC: C07C2/58 , B01J31/40 , B01J31/02 , B01J38/10 , C07C2/62 , C10L1/06 , C10G29/20 , C10G45/60 , C10G47/02 , C10G50/00 , B01J35/12
CPC classification number: B01J31/40 , B01J31/0284 , B01J35/12 , B01J38/10 , B01J2231/44 , C07C2/62 , C07C2531/02 , C10G29/205 , C10G45/60 , C10G47/02 , C10G50/00 , C10L1/06 , C10L2270/023 , C10L2290/12 , Y02P20/584 , C07C11/16
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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公开(公告)号:US20170216827A1
公开(公告)日:2017-08-03
申请号:US15010168
申请日:2016-01-29
Applicant: Chevron U.S.A. Inc.
Inventor: Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Timken , Steven Xugi Song , Michael Sean Driver
CPC classification number: B01J31/40 , B01J31/0284 , B01J35/12 , B01J38/10 , B01J2231/44 , C07C2/62 , C07C2531/02 , C10G29/205 , C10G45/60 , C10G47/02 , C10G50/00 , C10L1/06 , C10L2270/023 , C10L2290/12 , Y02P20/584 , C07C11/16
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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公开(公告)号:US12043589B2
公开(公告)日:2024-07-23
申请号:US18116747
申请日:2023-03-02
Applicant: Chevron U.S.A. Inc.
Inventor: Bong Kyu Chang , Hye-Kyung Cho Timken , Michelle K. Young
CPC classification number: C07C2/22 , C10G50/02 , C07C2527/06 , C07C2527/122 , C07C2527/125 , C07C2527/128
Abstract: A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.
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公开(公告)号:US11639320B1
公开(公告)日:2023-05-02
申请号:US17750663
申请日:2022-05-23
Applicant: CHEVRON U.S.A. INC.
Inventor: Bong Kyu Chang , Hye-Kyung Cho Timken , Michelle K. Young
Abstract: A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.
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