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公开(公告)号：US20190241484A1
公开(公告)日：2019-08-08
申请号：US16382708
申请日：2019-04-12
Applicant: Chevron U.S.A. Inc.
Inventor： Hye-Kyung Cho Timken , Kenneth John Peinado , Bong-Kyu Chang
CPC classification number: C07C2/58 , B01J31/0284 , C07C5/3335 , C07C5/3337 , C07C2521/04 , C07C2521/18 , C07C2523/26 , C07C2523/42 , C07C2531/02 , C10G5/00 , C10G9/00 , C10G29/205 , C10G57/005
Abstract: An integrated process unit for making one or more alkylate products is provided. The integrated process unit includes (a) a dehydrogenation reactor; (b) a single alkylation reactor; (c) a separator, following the alkylation reactor, that separates effluent from the alkylation reactor into a catalyst phase and a hydrocarbon phase; (d) a distillation unit, following the separator, that receives the hydrocarbon phase and separates it into alkylate products, an unreacted paraffin phase, and an isoparaffin phase; (e) a first recycle line that feeds unreacted paraffin phase to the dehydrogenation reactor; and (f) a second recycle line that feeds isoparaffin phase to the alkylation reactor.
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公开(公告)号：US10113963B1
公开(公告)日：2018-10-30
申请号：US16018143
申请日：2018-06-26
Applicant: Chevron U.S.A. Inc.
Inventor： Huping Luo , Hye-Kyung Cho Timken , Toni Zhang Miao , Howard Steven Lacheen , Bi-Zeng Zhan
IPC: G01J3/00 , G01N21/552 , G01N21/3577 , G01N1/34 , G01N21/15 , G01N21/35
Abstract: An integrated system for monitoring a chemical concentration in an ionic liquid, comprising: a. an online FTIR instrument with an ATR window; b. a sample conditioning station that removes light hydrocarbons and produces a degassed ionic liquid that is analyzed by FTIR; and c. a solvent flushing system that flows solvent across the ATR window. Also, a process for monitoring the chemical concentration, comprising: a. degassing the ionic liquid in the sample conditioning station; b. passing the degassed ionic liquid over an ATR window; c. periodically redirecting a flow of the degassed ionic liquid via a bypass line or an on-off valve that isolates the ATR window from the process unit that elutes the ionic liquid; and d. flowing a solvent and a purging gas over the ATR window during the periodically redirecting step c); and e. resuming the passing of the degassed ionic liquid over the ATR window.
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3.发明授权公开(公告)号：US09956504B2
公开(公告)日：2018-05-01
申请号：US15251640
申请日：2016-08-30
Applicant: Chevron U.S.A. Inc.
Inventor： Huping Luo , Hye-Kyung Cho Timken
CPC classification number: B01D17/045 , B01D17/0214 , B01D17/10 , C07C7/00 , C07C7/005 , C07C9/15 , C10G31/00 , C10G33/06 , C07C9/14
Abstract: An integrated coalescing system for separating ionic liquid from a liquid hydrocarbon is provided, comprising:a. a bulk settler,that separates an emulsion comprising the dispersed ionic liquid with a wide range of droplet sizes into a clean ionic liquid phase and a separated liquid hydrocarbon phase comprising retained droplets;b. a pre-coalescer that receives the separated liquid hydrocarbon phase, separates out solid particles from the separated liquid hydrocarbon phase, and begins to form coalesced droplets of the retained droplets; andc. a coalescer that receives an effluent from the pre-coalescer, wherein the at least one coalescer comprises multiple layers of media having a fine pore size, and produces a clean hydrocarbon stream that is free of the dispersed ionic liquid and additional amounts of the clean ionic liquid phase. Also, a process is provided for separating an ionic liquid from a liquid hydrocarbon, using the integrated coalescing system.
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公开(公告)号：US11884885B2
公开(公告)日：2024-01-30
申请号：US17868884
申请日：2022-07-20
Applicant: CHEVRON U.S.A. INC.
Inventor： Tengfei Liu , Joel Edward Schmidt , Richard Grove , Hye-Kyung Cho Timken
CPC classification number: C10G3/60 , C10G11/187 , C10L1/06 , C10G2300/1003 , C10G2300/1014 , C10G2300/1059 , C10G2300/305 , C10G2300/308 , C10G2300/4006 , C10G2300/4012 , C10G2400/02
Abstract: A process is provided for producing a liquid hydrocarbon material suitable for use as a fuel or as a blending component in a fuel. The process includes co-processing a pyrolysis oil derived from a waste plastic raw material and a biorenewable feedstock comprising triglycerides in a catalytic cracking process in a presence of a solid catalyst at catalytic cracking conditions to provide a cracking product. The cracking product may be fractionated to provide at least one of a gasoline fraction and a middle distillate fraction.
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公开(公告)号：US10227274B2
公开(公告)日：2019-03-12
申请号：US14597415
申请日：2015-01-15
Applicant: Chevron Phillips Chemical Company LP , Chevron U.S.A. Inc.
Inventor： Lei Ji , Ai-Fu Chang , Michael Sean Driver , Hye-Kyung Cho Timken
Abstract: Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.
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Patent Agency Ranking
公开(公告)号：US20190002368A1
公开(公告)日：2019-01-03
申请号：US15640655
申请日：2017-07-03
Applicant: Chevron U.S.A. Inc.
Inventor： Hye-Kyung Cho Timken , Kenneth John Peinado , Bong-Kyu Chang
Abstract: We provide a process, comprising:a. dehydrogenating natural gas liquid to produce a mixture comprising olefins and unconverted paraffins;b. without further purification or modification other than mixing with an isoparaffin, sending the mixture to a single alkylation reactor;c. alkylating the olefins with the isoparaffin, using an ionic liquid catalyst, to produce one or more alkylate products; andd. distilling the one or more alkylate products and collecting a bottoms distillation fraction that is a middle distillate blending component having a sulfur level of 50 wppm or less and a Bromine number less than 1.
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7.发明授权公开(公告)号：US10167432B2
公开(公告)日：2019-01-01
申请号：US15473738
申请日：2017-03-30
Applicant: Chevron U.S.A. Inc.
Inventor： Hye-Kyung Cho Timken , Bong-Kyu Chang
IPC: C07C2/58 , C10G50/00 , C10G29/20 , C10G11/18 , B01J31/02 , B01J35/12 , C10G57/00 , C10L1/02 , B01J27/125
Abstract: Processes are provided for making an alkylate gasoline blending component, comprising: a. feeding an olefin feed comprising greater than 80 wppm of a sulfur contaminant comprising mercaptans, alkyl sulfides, and alkyl disulfides to a chloroaluminate ionic liquid catalyst, wherein a level of the sulfur contaminant accumulates in the chloroaluminate ionic liquid catalyst to make a sulfur-contaminated ionic liquid catalyst comprising 300 to 20,000 wppm of a sulfur; and b. alkylating the olefin feed with an isoparaffin using the sulfur-contaminated ionic liquid catalyst to make the alkylate gasoline blending component having a final boiling point below 221° C. An alkylation process exclusively utilizing coker LPG olefins is also provided.
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8.发明授权公开(公告)号：US11135575B2
公开(公告)日：2021-10-05
申请号：US15928690
申请日：2018-03-22
Applicant: Chevron U.S.A. Inc.
Inventor： Michael John Girgis , Huping Luo , Bong Kyu Chang , Hye-Kyung Cho Timken , Steven Xugi Song , Michael Sean Driver
IPC: C07C2/58 , B01J31/40 , B01J31/02 , B01J38/10 , C07C2/62 , C10L1/06 , C10G29/20 , C10G45/60 , C10G47/02 , C10G50/00 , B01J35/12 , C07C2/56
Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.
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公开(公告)号：US10059639B2
公开(公告)日：2018-08-28
申请号：US15255271
申请日：2016-09-02
Applicant: Chevron U.S.A. Inc.
Inventor： Hye-Kyung Cho Timken , Bong-Kyu Chang , Sven Ivar Hommeltoft
CPC classification number: C07C2/58 , B01J31/0284 , B01J2231/32 , C07C2/60 , C07C2527/125 , C07C2531/02 , C10G17/02 , C10G29/205 , C10G2300/1088 , C10G2400/02 , C10L1/06 , C10L2270/023 , C07C11/02
Abstract: A process, comprising: providing an olefin feed comprising pentenes, butenes, and isopentane; and alkylating the olefin feed with isobutane using an acidic ionic liquid catalyst; wherein less than 5 mol % of C5 olefins in the olefin feed are converted to isopentane, and the alkylate gasoline has defined final boiling points and high RONs. A process comprising: alkylating an olefin feed comprising pentenes and isopentane, with isobutane using an acidic ionic liquid catalyst; wherein less than 5 mol % of C5 olefins in the olefin feed are converted to isopentane; and wherein an n-pentane product yield is low. An alkylate gasoline, comprising less than 0.1 wt % olefins and aromatics, less than 1.8 wt % C12+hydrocarbons, and greater than 60 wt % combined C8 and C9 hydrocarbons, wherein the trimethylpentane in the C8 hydrocarbons and the trimethylhexane in the C9 hydrocarbons are defined.
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10.发明申请APPARATUS FOR PERFORMING A HYDROCARBON CONVERSION USING AN ACIDIC IONIC LIQUID 审中-公开使用酸性离子液体进行氢转化的装置公开(公告)号：US20160332134A1
公开(公告)日：2016-11-17
申请号：US15223051
申请日：2016-07-29
Applicant: Chevron U.S.A. Inc.
CPC classification number: B01J19/02 , B01J2219/0286 , C07C2/62 , C07C2531/02 , C07C2531/26 , C10G9/203 , C10G75/00 , C22C14/00 , C22C19/03 , C22C19/055 , C22C19/056 , C22C38/001 , C22C38/04 , C22C38/42 , C22C38/44 , C22C38/50
Abstract: We provide an apparatus for performing a hydrocarbon conversion or for handling of an output of the hydrocarbon conversion, comprising: a bare metal alloy, wherein the bare metal alloy comprises: from 15.1 to 49 wt % nickel, from 2.3 to 10 wt % molybdenum, from 0.00 to 2.95 wt % copper, from 5 to 25 wt % chromium, and from 20 to 59 wt % iron; wherein the bare metal alloy exhibits a corrosion rate less than 0.07 mm/year when performing the hydrocarbon conversion or handling the output of the hydrocarbon conversion; and wherein the hydrocarbon conversion is performed using an acidic ionic liquid. We also provide a process for using the apparatus.
Abstract translation: 我们提供一种用于进行烃转化或处理烃转化率输出的装置，包括：裸金属合金，其中所述裸露金属合金包括：15.1至49重量％的镍，2.3至10重量％的钼， 从0.00至2.95重量％的铜，5至25重量％的铬和20至59重量％的铁; 其中所述裸金属合金在进行烃转化或处理烃转化的输出时显示出小于0.07mm /年的腐蚀速率; 并且其中烃转化使用酸性离子液体进行。 我们还提供使用该设备的过程。
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