SURFACE TREATMENT FOR SELECTIVE METAL CAP APPLICATIONS
    1.
    发明申请
    SURFACE TREATMENT FOR SELECTIVE METAL CAP APPLICATIONS 有权
    选择性金属盖应用的表面处理

    公开(公告)号:US20090250815A1

    公开(公告)日:2009-10-08

    申请号:US12062130

    申请日:2008-04-03

    IPC分类号: H01L23/532 H01L21/768

    摘要: Interconnect structures in which a noble metal-containing cap layer is present directly on a non-recessed surface of a conductive material which is embedded within a low k dielectric material are provided. It has been determined that by forming a hydrophobic surface on a low k dielectric material prior to metal cap formation provides a means for controlling the selective formation of the metal cap directly on the non-recessed surface of a conductive material. That is, the selective formation of the metal cap directly on the non-recessed surface of a conductive material is enhanced since the formation rate of the metal cap on the non-recessed surface of a conductive material is greater than on the hydrophobic surface of the low k dielectric material. It is observed that the hydrophobic surface may be a result of treating a damaged surface of the dielectric material with a silylating agent prior to the selective formation of the noble metal cap or, as a result of forming a hydrophobic polymeric layer on the surface of the dielectric material prior to the selective deposition of the noble metal cap. The hydrophobic polymeric layer typically includes atoms of Si, C and O.

    摘要翻译: 提供了其中含有贵金属的覆盖层直接存在于嵌入低k电介质材料的导电材料的非凹陷表面上的互连结构。 已经确定,在金属盖形成之前通过在低k电介质材料上形成疏水表面提供了一种用于直接控制在导电材料的非凹入表面上选择性形成金属帽的手段。 也就是说,直接在导电材料的非凹入表面上选择性地形成金属帽,因为金属帽在导电材料的非凹陷表面上的形成速率大于导电材料的疏水表面上的形成速率 低k电介质材料。 观察到,疏水性表面可以是在选择性形成贵金属盖之前用甲硅烷基化剂处理电介质材料的损坏表面的结果,或者由于在表面上形成疏水性聚合物层 在贵金属盖的选择​​性沉积之前的介电材料。 疏水性聚合物层通常包括Si,C和O的原子。

    STRUCTURE AND METALLIZATION PROCESS FOR ADVANCED TECHNOLOGY NODES
    2.
    发明申请
    STRUCTURE AND METALLIZATION PROCESS FOR ADVANCED TECHNOLOGY NODES 有权
    高级技术人员的结构和金属化过程

    公开(公告)号:US20120098133A1

    公开(公告)日:2012-04-26

    申请号:US12910075

    申请日:2010-10-22

    摘要: The problem of poor adherence of a dielectric coating on a patterned metal structure can be solved by forming an adhesion layer on exposed surfaces of such metal structure prior to deposition of such dielectric. According to an embodiment, the invention provides a method to form a self-aligned adhesion layer on the surface of metal interconnect structure within an integrated circuit by exposing the metal structure to a controlled atmosphere and a flow of nitrogen-containing gas.

    摘要翻译: 可以通过在沉积这种电介质之前在这种金属结构的暴露表面上形成粘合层来解决图案化金属结构上的电介质涂层粘附性差的问题。 根据一个实施例,本发明提供了一种通过将金属结构暴露于受控气氛和含氮气体的流动来在集成电路内的金属互连结构的表面上形成自对准粘附层的方法。