公开(公告)号：US3423369A

公开(公告)日：1969-01-21

申请号：US3423369D

申请日：1966-01-14

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  BERGER ALFRED ,  GUTH CHRISTIAN ,  MAEDER ARTHUR

IPC分类号： C08G12/40 ,  D06M13/288 ,  C08G41/00 ,  C09K3/28

CPC分类号： C08G12/40 ,  D06M13/288

公开(公告)号：US3658952A

公开(公告)日：1972-04-25

申请号：US3658952D

申请日：1969-07-01

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： C07F9/40 ,  C08K5/5353 ,  D06M13/288 ,  D06M1/00

CPC分类号： D06M13/288 ,  C07F9/4006 ,  C08K5/5353 ,  Y10S260/24

摘要： PHOSPHORUS-CONTAINING REACTION PRODUCTS OF A (METHYLENE)- OR (DIMETHYLENE ETHER)-BIS-(DIALKYL PHOSPHONOPROPIONIC ACID AMIDE) AND FORMALDEHYDE OR A FORMALDEHYDE RELEASING AGENT, FOR FLAME-PROOFING FIBER MATERIALS CONTAINING CELLULOSE ADVANTAGEOUSLY TOGETHER WITH A CURABLE AMINOPLAST PRECONDENSATE.

公开(公告)号：US3639539A

公开(公告)日：1972-02-01

申请号：US3639539D

申请日：1968-03-26

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： C07F9/40 ,  D06M13/288

CPC分类号： D06M13/288 ,  C07F9/4006 ,  Y10S8/04 ,  Y10S8/21 ,  Y10S260/24

摘要： THESE AMIDES ARE SUITABLE FOR RENDERING CELLULOSE-CONTAINING FIBROUS MATERIALS FLAMEPROFF. THE FLAMEPROFF FINISH IS RESISTANT TO WASHING AND DRY-CLEANING AND IMPROVES THE DRY CREASE ANGLE OF THE FINISHED MATERIAL.

-CH2-CO-N(-CH2-OH)2

WHEREIN R1 IS AN ALKYL OR HALOGEN ALKYL RESIDUE AND X1 IS HYDROGEN OR A GROUP OF THE FORMULA

(R1-O-)2-P(=O)-CH2-CH(-X1)-CH2-CO-N(-CH2-OH)2

PHOSPHORUS-CONTAINING N,N-DIMETHYLOLCARBOXYLIC ACID AMIDES OF THE FORMULA

公开(公告)号：US3669725A

公开(公告)日：1972-06-13

申请号：US3669725D

申请日：1970-03-26

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  KERN JOERG ,  MAEDER ARTHUR

IPC分类号： D06M13/44 ,  C07F9/40 ,  C08G12/40 ,  C09K21/14 ,  D06M13/288 ,  D06M13/292 ,  C09D5/18 ,  C09D3/28

CPC分类号： D06M13/292 ,  C07F9/4006 ,  C08G12/40 ,  D06M13/288 ,  Y10S428/921 ,  Y10T442/268 ,  Y10T442/2828

摘要： A PROCESS FOR THE FLAMEPROOFING OF MIXED FIBER MATERIALS OF POLYESTER AND CELLULOSE IS PROVIDED IN WHICH AN AQUEOUS PREPARATION IS APPLIED TO THESE MATERIALS, WHICH CONTAINS A REACTION PRODUCT OF A NITROGEN COMPOUND, A PHSOPHONOPROPIONIC ACID AMIDE, FORMALDEHYDE AND OPTIONALLY AN ALKANOL. AFTERWARDS THE MATERIALS ARE DRIED AND SUBJECTED TO A HEAT TREATMENT. THE FIBER MATERIALS THEN HAVE A VERY GOOD PERMANENT FLAME RESISTANCE. PREFERRED FIBER MATERIALS ARE POLYESTER-CONTTON MIXED FABRICS.

公开(公告)号：US3579532A

公开(公告)日：1971-05-18

申请号：US3579532D

申请日：1968-07-22

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  STARK BERNARD PETER ,  MAEDER ARTHUR

IPC分类号： D06M13/44 ,  C07F9/38 ,  C07F9/40 ,  C07F9/6506 ,  D06M13/02 ,  D06M13/288 ,  D06M13/322 ,  D06M13/402 ,  D06M13/432 ,  D06M13/447 ,  D06M15/432 ,  D06M15/433 ,  D21H21/34 ,  C07D49/34

CPC分类号： D06M15/432 ,  C07F9/4006 ,  C07F9/65067 ,  D06M13/288

摘要： THIS INVENTION PROVIDES PHOSPHORUS-CONTAINING PRODUCTS WHICH ARE OBTAINED BY REACTING A COMPOUND OF THE FORMULA

(R1-O-)2-P(=O)-CH2-CH(-R2)-CO-NH2

WHEREIN R1 REPRESENTS A SUBSTITUENT BOUND THROUGH A CARBON ATOM TO THE OXYGEN ATOM AND R2 E.G. A HYDROGEN ATOM OR A METHYL GROUP, WITH GLYOXAL, FORMALDEHYDE, UREA AND AN ETHERIFYING AGENT LIKE A SATURATED OR UNSATURATED ALIPHATIC ALCOHOL. THESE PHOSPHORUS-CONTAINING REACTION PRODUCTS ARE USEFUL AS AGENTS FOR FLAMEPROOFING.

公开(公告)号：US3634422A

公开(公告)日：1972-01-11

申请号：US3634422D

申请日：1969-07-01

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M13/44 ,  C07F9/40 ,  C07F9/6521 ,  D06M13/288 ,  D06M15/432 ,  C07D55/20 ,  C07D55/24

CPC分类号： D06M13/288 ,  C07F9/4006 ,  C07F9/65217 ,  Y10S428/921 ,  Y10T428/31953

摘要： PHOSPHORUS-CONTAINING REACTION PRODUCTS FROM A CONDENSATION PRODUCT FROM A 1,3,5-TRIAZINE CONTAINING AT LEAST 2 PRIMARY AMINO GROUP AND A PHOSPHONOPROPIONICACIDAMIDE, AT LEAST ONE OF THESE TWO COMPONENTS BEING METHYLOLATED AT THE H2N-GROUPS, AND FORMALDEHYDE OR A REAGENT RELEASING FORMALDEHYDE. THESE PRODUCTS ARE USEFUL FOR FLAME-PROOFING FIBRE MATERIALS CONTAINING CELLULOSE.

公开(公告)号：US3449302A

公开(公告)日：1969-06-10

申请号：US3449302D

申请日：1966-05-03

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  WERNER ROBERT ,  MAEDER ARTHUR

IPC分类号： C08F214/08 ,  C08F15/40

CPC分类号： C08F214/08 ,  Y10S526/915

公开(公告)号：US3671611A

公开(公告)日：1972-06-20

申请号：US3671611D

申请日：1969-12-23

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M15/432 ,  C07F9/40 ,  C09K21/14 ,  D06M13/288

CPC分类号： D06M13/288 ,  C07F9/4006 ,  Y10S260/24

摘要： Phosphorus compounds are provided which correspond to the formula IN WHICH EACH R is an alkyl, alkenyl or halogenalkyl radical, X and X'' each is a methyl group or a hydrogen atom, A is a -CO-, CS-, -SO2-, -CNH- or -CO-NE-CO- radical, wherein E is a hydrogen atom or a Y-CH2-O- radical and wherein Y is an alkyl radical or a hydrogen atom. The phosphorus compounds are manufactured from the corresponding phosphorus carboxylic acid amides, a diamide and formaldehyde. These compounds optionally together with a curable aminoplast precondensate are useful for flameproofing and creaseproofing of cellulose-containing fiber materials.

摘要翻译： 提供了对应于式I的磷化合物，其中每个R是烷基，烯基或卤素烷基，X和X'各自是甲基或氢原子，A是-CO - ， - CS-，-SO 2 - ，-CNH-或-CO-NE-CO-基，其中E为氢原子或Y-CH2-O-基，其中Y为烷基或氢原子。 磷化合物由相应的磷羧酸酰胺，二酰胺和甲醛制成。 这些化合物任选地与可固化的氨基塑料预缩合物一起可用于含纤维素纤维材料的防火和抗皱。

公开(公告)号：US3627784A

公开(公告)日：1971-12-14

申请号：US3627784D

申请日：1969-12-09

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  KERN JOERG ,  MAEDER ARTHUR

IPC分类号： D06M13/44 ,  B01J27/00 ,  C07F9/40 ,  C07F9/6527 ,  C09K21/12 ,  D06M13/02 ,  D06M13/288 ,  D06M13/322 ,  D06M13/447 ,  D06M15/432 ,  D06M15/673

CPC分类号： D06M13/288 ,  C07F9/4006 ,  C07F9/6527

摘要： Heterocyclic phosphorus compounds with a hetero-ring containing eight ring members, namely two carbon, two nitrogen and two oxygen atoms are provided. These compounds are manufactured by reacting 2 mols of at least one phosphonocarboxylic acid amide with at least 4 mols of anhydrous formaldehyde in the presence of an acid catalyst and in the absence of water. The phosphorous compounds are used for flameproofing and creaseproofing cellulose-containing textile material. They may be optionally used together with an aminoplast precondensate.

公开(公告)号：US3627767A

公开(公告)日：1971-12-14

申请号：US3627767D

申请日：1969-12-30

申请人： CIBA LTD

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M13/44 ,  C07F9/6506 ,  C07F9/6512 ,  C09K21/12 ,  D06M13/288 ,  C07D49/30 ,  C07D51/18

CPC分类号： D06M13/288 ,  C07F9/65061 ,  C07F9/65121

摘要： adical with two to three carbon atoms substituted by one to three methyl, methoxy or hydroxyl groups, Z is an oxygen or sulfur atom and Y is an alkyl radical with at most four carbon atoms or a hydrogen atom.