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1.发明授权Catalytic system for conjugated diene polymerisation, polymerisation method and functional polymer obtained 有权用于共轭二烯聚合的催化体系，聚合方法和获得的官能聚合物公开(公告)号：US09315590B2
公开(公告)日：2016-04-19
申请号：US13709446
申请日：2012-12-10
申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN , MICHELIN RECHERCHE ET TECHNIQUE S.A. , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , ECOLE POLYTECHNIQUE
IPC分类号： C08F4/50 , C08F4/52 , C08F4/46 , C08L15/00 , C08F236/08 , C08F236/06
CPC分类号： C08F4/50 , C08F4/463 , C08F4/52 , C08F136/06 , C08F236/06 , C08F236/08 , C08K3/04 , C08L15/00 , C08F4/545 , C08L19/006 , C08F36/04
摘要： The present invention relates to a novel catalytic system for polymerization, and more particularly for preparing conjugated diene polymers bearing a polar function at the chain end. This catalytic system is based on a metal salt of a rare-earth metal and, as alkylating agent, an organometallic compound based on a metal belonging to the 2nd column or the 13th column of the Periodic Table, capable of transferring a polar function to the diene elastomer during the conjugated diene polymerization step. The novel catalytic system makes it possible to reduce the steps for synthesizing a chain-end functionalized elastomer, while ensuring optimal functionalization, advantageously close or equal to 100%.
摘要翻译： 本发明涉及一种用于聚合的新型催化体系，更具体地说涉及在链末端制备具有极性官能团的共轭二烯聚合物。 该催化体系基于稀土金属的金属盐，并且作为烷基化剂，基于属于周期表第二列或第十三列的金属的有机金属化合物，其能够将极性官能团转移到 二烯烃弹性体。 新颖的催化体系使得有可能减少合成链端官能化弹性体的步骤，同时确保最佳官能化，有利地接近或等于100％。
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2.发明申请CATALYTIC SYSTEM FOR CONJUGATED DIENE POLYMERISATION, POLYMERISATION METHOD AND FUNCTIONAL POLYMER OBTAINED 审中-公开用于连接二烯聚合的催化体系，聚合方法和获得的官能聚合物公开(公告)号：US20130274407A1
公开(公告)日：2013-10-17
申请号：US13709446
申请日：2012-12-10
申请人： Francoise Hervagault , Elaine Le Floch , Clémence Le Floch , Paul Le Floch , COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN , ECOLE POLYTECHNIQUE , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , MICHELIN RECHERCHE ET TECHNIQUE S.A.
CPC分类号： C08F4/50 , C08F4/463 , C08F4/52 , C08F136/06 , C08F236/06 , C08F236/08 , C08K3/04 , C08L15/00 , C08F4/545 , C08L19/006 , C08F36/04
摘要： The present invention relates to a novel catalytic system for polymerization, and more particularly for preparing conjugated diene polymers bearing a polar function at the chain end. This catalytic system is based on a metal salt of a rare-earth metal and, as alkylating agent, an organometallic compound based on a metal belonging to the 2nd column or the 13th column of the Periodic Table, capable of transferring a polar function to the diene elastomer during the conjugated diene polymerization step. The novel catalytic system makes it possible to reduce the steps for synthesizing a chain-end functionalized elastomer, while ensuring optimal functionalization, advantageously close or equal to 100%.
摘要翻译： 本发明涉及一种用于聚合的新型催化体系，更具体地说涉及在链末端制备具有极性官能团的共轭二烯聚合物。 该催化体系基于稀土金属的金属盐，并且作为烷基化剂，基于属于周期表第二列或第十三列的金属的有机金属化合物，其能够将极性官能团转移到 二烯烃弹性体。 新颖的催化体系使得有可能减少合成链端官能化弹性体的步骤，同时确保最佳官能化，有利地接近或等于100％。
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公开(公告)号：US10266553B2
公开(公告)日：2019-04-23
申请号：US15528688
申请日：2015-12-11
申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN , MICHELIN RECHERCHE ET TECHNIQUE, S.A. , UNIVERSITE CLAUDE BERNARD LYON 1 , CENTRE NATIONAL DE LA RECHERCE SCIENTIFIQUE , CPE LYON FORMATION CONTINUE ET RECHERCHE
摘要： A compound and the use thereof to prepare a functional or telechelic polyolefin is provided. The compound has the following formula (II): Y((CH2)p—B′)m (II), wherein m=2 or 3; Y being an alkaline earth metal or zinc when m=2, Y being aluminum when m=3; B′ being selected from the group comprising N(SiMe3)2; N(SiMe2CH2CH2SiMe2); C6F5; C3F7; C6F13; para-C6H4—NMe2; para-C6H4—O-Me; para-C6H4—N(SiMe3)2; and CH(OCH2CH2O); and p being an integer from 0 to 50.
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公开(公告)号：US10189978B2
公开(公告)日：2019-01-29
申请号：US14762327
申请日：2014-01-21
IPC分类号： C08L23/00 , C08L23/08 , B60C1/00 , C08L9/06 , C08F236/10
摘要： The present invention relates to a rubber composition based on a reinforcing filler and on an elastomer matrix comprising a highly saturated diene elastomer comprising at least five distinct units of A, B, C, D and E distributed randomly within the elastomer at respective molar fractions of m %, n %, o %, p % and q %, where m+n+o+p+q=100; m≥50; n+o+p+q≥10; and 15≥p+q≥2.This rubber composition enables a satisfactory degree of stiffness to be reached while maintaining hysteresis properties acceptable for use in the manufacture of tires for running vehicles.
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公开(公告)号：US10364335B2
公开(公告)日：2019-07-30
申请号：US14648481
申请日：2013-11-21
IPC分类号： C08F236/06 , C08F236/10 , C08K3/04 , C08K3/36 , C08C19/02 , B60C1/00 , C08L15/00 , C08L7/00 , C08L9/00 , C08L61/04 , C08L91/00 , C08L93/00
摘要： A rubber composition based on a reinforcing filler and on an elastomeric matrix comprising a highly saturated diene elastomer, comprising units of the following categories A, B, C, D and E, or units of these same categories A, B, C, D and E comprising, for at least one of the categories B, C, D and E, a mixture of at least two different units of the same category which differ from one another through the nature of their side groups Ri: and where R1, R2, R3 and R4, which are identical or different, denote a hydrogen atom, a methyl radical or a phenyl radical which is substituted or unsubstituted in the ortho, meta or para position by a methyl radical; R5 denotes a hydrogen atom or a methyl radical; R6 denotes a methyl radical or a phenyl radical which is substituted or unsubstituted in the ortho, meta or para position by a methyl radical; m, n, o, p and q are numbers ranging from 0 to 100. This rubber composition enables a satisfactory degree of stiffness to be achieved while maintaining acceptable hysteresis properties, or even improving them, for use in the manufacture of tires for motor vehicles.
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公开(公告)号：US10435485B2
公开(公告)日：2019-10-08
申请号：US15327123
申请日：2015-07-09
摘要： A polymer comprises randomly distributed units UA, UB, UC and UD and at least one unit bearing a subunit F according to the respective molar percentages m, n, o, p and f F pendant along the chain of the polymer and bearing an associative group comprising at least one nitrogen atom, R1 and R2, which are identical or different, denoting a hydrogen atom, a methyl radical or a phenyl radical which is unsubstituted or substituted in the ortho, meta or para position by a methyl radical, m≥50, n≥0, o≥0, f>0, 0
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公开(公告)号：US10934377B2
公开(公告)日：2021-03-02
申请号：US16320014
申请日：2017-07-24
IPC分类号： C08F4/52 , C08F4/56 , C08F236/04 , C08F236/06 , C08F210/18 , C07F3/02 , C07F17/00 , C08F110/02 , C08F236/08 , C07F5/00
摘要： A catalytic system based at least on a preformation monomer which is ethylene or a mixture of ethylene and of a conjugated diene, on a metallocene of formula {P(Cp1)(Cp2)Y} or Cp3Cp4Y and on an organometallic compound as cocatalyst, Y denoting a group comprising a metal atom which is a rare earth metal, the Cp1, Cp2, Cp3 and Cp4 groups, which are identical or different, being selected from the group consisting of fluorenyl groups, cyclopentadienyl groups and indenyl groups, the groups being substituted or unsubstituted, and P being a group bridging the two Cp1 and Cp2 groups and comprising a silicon or carbon atom, is provided. Such a catalytic system exhibits an improved stability of the catalytic activity over time, in particular on storage.
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公开(公告)号：US10513150B2
公开(公告)日：2019-12-24
申请号：US15735531
申请日：2016-06-16
发明人： Séverin Dronet , Julien Thuilliez
IPC分类号： B60C1/00 , C08F236/06 , C08F236/08 , C08G8/02 , C08L9/00 , C08G81/02 , C08C19/25
摘要： The present invention relates to comb block copolymers, combining an elastomeric backbone and rigid pendent blocks and thus having thermoplastic elastomer properties. The invention targets in particular comb block copolymers which may be used as a material as is.According to the invention, the comb block copolymer is a diene/polypropylene thermoplastic elastomer copolymer, characterized in that it consists of a backbone, said backbone being derived from a diene elastomer, and in that it comprises from 5% to 50% by weight, relative to the total weight of the copolymer, of pendent semicrystalline polypropylene groups distributed along the backbone.Another subject of the invention is the process for preparing same, and the compositions comprising same.Finally, a subject of the invention is a tire, one of the constituent elements of which comprises such a composition.
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公开(公告)号：US11498985B2
公开(公告)日：2022-11-15
申请号：US16606371
申请日：2018-04-16
发明人： Julien Thuilliez , Nuno Pacheco
IPC分类号： C08F210/02 , C08F2/06
摘要： A process for the synthesis of an ethylene/butadiene copolymer is provided. The process is continuous and comprises the following steps: a. feeding at least one stirred polymerization reactor with a mixture of ethylene, butadiene, hydrocarbon-based solvent and catalytic system allowing the formation of cyclic trans-1,2-cyclohexane units in the polymer chain with a mole ratio of ethylene to the sum of the ethylene and butadiene monomers ranging from 0.5 to 0.99; the concentration of ethylene and butadiene monomers in the polymerization reaction medium being less than 15% by weight; the operating pressure of the reactor is greater than or equal to the saturated vapour pressure of the polymerization reaction medium; and the polymerization temperature is greater than 90° C.; b. recovering the ethylene/butadiene copolymer, this copolymer comprising, statistically distributed, ethylene units, butadiene units and trans-1,2-cyclohexane units, the molar fraction of ethylene units in the copolymer being greater than or equal to 50%.
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公开(公告)号：US10822475B2
公开(公告)日：2020-11-03
申请号：US16062343
申请日：2016-12-16
发明人： Julien Thuilliez , Nuno Pacheco
IPC分类号： C08L9/00 , C08F210/02 , C08F236/06 , C08F4/6192 , C08F210/16
摘要： An ethylene/butadiene copolymer comprising statistically distributed ethylene units butadiene units, and trans-1,2-cyclohexane units is provided. The molar fraction of ethylene units in the copolymer is greater than or equal to 50%, relative to the total number of moles of ethylene, butadiene and trans-1,2-cyclohexane units. The microstructure of the copolymer is homogeneous. A process for preparing such a copolymer and also to the uses of this copolymer, in particular in rubber compositions for tires, is also provided.
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