摘要:
Thermal management systems for battery cells and methods for their additive manufacture are provided. The thermal management systems include at least one heat pipe that physically contacts the battery cell and conforms to its geometry. Each battery cell is deposited within a separate heat pipe, and each heat pipe is disposed on a base plate, which itself connects to a heat sink. In many embodiments, the heat pipe is a two-phase heat exchanger having three major components: liquid channels, wick elements, and vapor channels. In such embodiments, the wick component comprises a porous body configured to be disposed between the liquid channels and vapor channels. The wick component may be made using a stochastic additive manufacturing process such that the wick component may take any configuration and/or such that the wick component may be directly integrated into the body of the heat pipe as a unitary piece thereof. In other embodiments, the heat pipe is a cavity with flow channels in which fluid can be pumped through. In some such embodiments, the fluid can occupy the heat pipe in a one-phase or two-phase state. This unitary heat pipe is part of a monolithic thermal management system.
摘要:
Systems and methods in accordance with embodiments of the invention implement high-temperature tolerant supercapacitors. In one embodiment, a high-temperature tolerant super capacitor includes a first electrode that is thermally stable between at least approximately 80° C. and approximately 300° C.; a second electrode that is thermally stable between at least approximately 80° C. and approximately 300° C.; an ionically conductive separator that is thermally stable between at least approximately 80° C. and 300° C.; an electrolyte that is thermally stable between approximately at least 80° C. and approximately 300° C.; where the first electrode and second electrode are separated by the separator such that the first electrode and second electrode are not in physical contact; and where each of the first electrode and second electrode is at least partially immersed in the electrolyte solution.
摘要:
Systems and methods in accordance with embodiments of the invention implement a lithium-based high energy density flow battery. In one embodiment, a lithium-based high energy density flow battery includes a first anodic conductive solution that includes a lithium polyaromatic hydrocarbon complex dissolved in a solvent, a second cathodic conductive solution that includes a cathodic complex dissolved in a solvent, a solid lithium ion conductor disposed so as to separate the first solution from the second solution, such that the first conductive solution, the second conductive solution, and the solid lithium ionic conductor define a circuit, where when the circuit is closed, lithium from the lithium polyaromatic hydrocarbon complex in the first conductive solution dissociates from the lithium polyaromatic hydrocarbon complex, migrates through the solid lithium ionic conductor, and associates with the cathodic complex of the second conductive solution, and a current is generated.
摘要:
A lithium ion battery cell includes a housing, a cathode disposed within the housing, wherein the cathode comprises a cathode active material, an anode disposed within the housing, wherein the anode comprises an anode active material, and an electrolyte disposed within the housing and in contact with the cathode and anode. The electrolyte includes a solvent mixture and a lithium salt serving as a primary lithium ion conductor in the electrolyte to allow for lithium ion intercalation and deintercalation processes at the cathode and the anode during charging and discharging of the lithium ion battery cell. The solvent mixture includes a cyclic carbonate and one or more non-cyclic carbonates. The lithium salt is lithium bis(fluorosulfonyl)imide (LiFSI). The solvent mixture and LiFSI are configured to enhance the low temperature performance of the lithium ion battery cell at operating temperatures below 0° C.
摘要:
A lithium ion battery cell includes a housing, a cathode disposed within the housing, wherein the cathode comprises a cathode active material, an anode disposed within the housing, wherein the anode comprises an anode active material, and an electrolyte disposed within the housing and in contact with the cathode and anode. The electrolyte consists essentially of a solvent mixture, a lithium salt in a concentration ranging from approximately 1.0 molar (M) to approximately 1.6 M, and an additive mixture. The solvent mixture includes a cyclic carbonate, an non-cyclic carbonate, and a linear ester. The additive mixture consists essentially of lithium difluoro(oxalato)borate (LiDFOB) in an amount ranging from approximately 0.5 wt % to approximately 2.0 wt % based on the weight of the electrolyte, and vinylene carbonate (VC) in an amount ranging from approximately 0.5 wt % to approximately 2.0 wt % based on the weight of the electrolyte.
摘要:
In some embodiments, a heat transfer device can include a case configured to receive at least one thermal element. The case can include an integrated oscillating heat pipe. The integrated oscillating heat pipe can be integrated into at least one wall of the case. The heat transfer device can further include a heatsink element. The heatsink element is in contact with at least one wall of the case. The integrated oscillating heat pipe can have two or more layers, and can extend in three dimensions.
摘要:
Thermal management systems for battery cells and methods for their additive manufacture are provided. The thermal management systems include at least one heat pipe that physically contacts the battery cell and conforms to its geometry. Each battery cell is deposited within a separate heat pipe, and each heat pipe is disposed on a base plate, which itself connects to a heat sink. In many embodiments, the heat pipe is a two-phase heat exchanger having three major components: liquid channels, wick elements, and vapor channels. In such embodiments, the wick component comprises a porous body configured to be disposed between the liquid channels and vapor channels. The wick component may be made using a stochastic additive manufacturing process such that the wick component may take any configuration and/or such that the wick component may be directly integrated into the body of the heat pipe as a unitary piece thereof. In other embodiments, the heat pipe is a cavity with flow channels in which fluid can be pumped through. In some such embodiments, the fluid can occupy the heat pipe in a one-phase or two-phase state. This unitary heat pipe is part of a monolithic thermal management system.
摘要:
Composite cathode materials are provided herein. Disclosed composite cathode materials include those comprising an aluminum borate coating. Systems making use of the cathode active materials are also described, such as electrochemical cells and electrodes for use in electrochemical cells. Methods for making and using the composite cathode materials are also disclosed.
摘要:
Provided herein are electrolytes for lithium-ion electrochemical cells, electrochemical cells employing the electrolytes, methods of making the electrochemical cells and methods of using the electrochemical cells over a wide temperature range. Included are electrolyte compositions comprising a lithium salt, a cyclic carbonate, a non-cyclic carbonate, and a linear ester and optionally comprising one or more additives.
摘要:
Composite cathode materials are provided herein. Disclosed composite cathode materials include those comprising an aluminum borate coating. Systems making use of the cathode active materials are also described, such as electrochemical cells and electrodes for use in electrochemical cells. Methods for making and using the composite cathode materials are also disclosed.