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公开(公告)号：US09463989B2
公开(公告)日：2016-10-11
申请号：US13527822
申请日：2012-06-20
IPC分类号： B01D53/48 , B01D53/52 , B01D53/76 , B01D53/77 , B01D53/78 , B01D19/00 , C02F1/68 , B01D53/79 , C02F101/10
CPC分类号： C02F1/683 , B01D19/0005 , B01D53/485 , B01D53/52 , B01D53/79 , B01D2251/21 , B01D2257/304 , B01D2257/306 , C02F2101/101
摘要： The use of a dialdehyde (e.g. glyoxal) and a nitrogen-containing scavenger (e.g. a triazine) when injected separately in media containing hydrogen sulfide (H2S) and/or mercaptans to scavenge H2S and/or mercaptans therefrom gives a synergistically better reaction rate and overall scavenging efficiency, i.e. capacity, over the use of the dialdehyde or the nitrogen-containing scavenger used alone, but in the same total amount of the dialdehyde and nitrogen-containing scavenger. The media may include an aqueous phase, a gas phase, a hydrocarbon phase and mixtures of a gas and/or hydrocarbon phase with an aqueous phase.
摘要翻译： 当分别注入含有硫化氢（H2S）和/或硫醇的介质中分别注入二氧化硫（如乙二醛）和含氮清除剂（如三嗪）以清除其中的硫化氢和/或硫醇时，会产生协同增效的反应速率和 总体清除效率，即容量，单独使用二醛或含氮清除剂的使用量，但二醛和含氮清除剂的总量相同。 介质可以包括水相，气相，烃相以及气相和/或烃相与水相的混合物。
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公开(公告)号：US20130004393A1
公开(公告)日：2013-01-03
申请号：US13527822
申请日：2012-06-20
CPC分类号： C02F1/683 , B01D19/0005 , B01D53/485 , B01D53/52 , B01D53/79 , B01D2251/21 , B01D2257/304 , B01D2257/306 , C02F2101/101
摘要： The use of a dialdehyde (e.g. glyoxal) and a nitrogen-containing scavenger (e.g. a triazine) when injected separately in media containing hydrogen sulfide (H2S) and/or mercaptans to scavenge H2S and/or mercaptans therefrom gives a synergistically better reaction rate and overall scavenging efficiency, i.e. capacity, over the use of the dialdehyde or the nitrogen-containing scavenger used alone, but in the same total amount of the dialdehyde and nitrogen-containing scavenger. The media may include an aqueous phase, a gas phase, a hydrocarbon phase and mixtures of a gas and/or hydrocarbon phase with an aqueous phase.
摘要翻译： 当分别注入含有硫化氢（H2S）和/或硫醇的介质中分别注入二氧化硫（如乙二醛）和含氮清除剂（如三嗪）以清除其中的硫化氢和/或硫醇时，会产生协同增效的反应速率和 总体清除效率，即容量，单独使用二醛或含氮清除剂的使用量，但二醛和含氮清除剂的总量相同。 介质可以包括水相，气相，烃相以及气相和/或烃相与水相的混合物。
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公开(公告)号：US20130320258A1
公开(公告)日：2013-12-05
申请号：US13900269
申请日：2013-05-22
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1468 , B01D53/1487 , B01D2252/10 , B01D2252/20426 , B01D2252/205 , B01D2252/504 , B01D2252/606 , B01D2257/304 , B01D2257/306 , C10G29/20 , C10G2300/1033 , C10G2300/202 , C10G2300/207 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08
摘要： The use of a composition that includes a metal salt and an oil soluble amine formaldehyde reaction product scavenges H2S that is present in aqueous fluids (e.g. produced water liquid streams), natural gas and in oil and mixtures thereof (e.g. mixed production streams that contain all three phases) better than either component when used alone. The resulting scavenger combination significantly increases the reaction rate and the overall scavenging efficiency, i.e. capacity over each component when used alone, in the same total amount. Non-limiting examples of the metal salt include zinc or iron carboxylates, and a non-limiting example of an oil soluble amine formaldehyde reaction product is the reaction product of dibutylamine with formaldehyde.
摘要翻译： 使用包含金属盐和油溶性胺甲醛反应产物的组合物清除存在于含水流体（例如产生的水液体流），天然气和油以及其混合物中的H 2 S（例如包含所有的混合生产流 三相）比单独使用时更好。 所得到的清除剂组合显着提高了反应速率和总体清除效率，即相同量的单独使用时每种组分的容量。 金属盐的非限制性实例包括锌或铁羧酸盐，并且油溶性胺甲醛反应产物的非限制性实例是二丁胺与甲醛的反应产物。
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公开(公告)号：US20130224092A1
公开(公告)日：2013-08-29
申请号：US13589794
申请日：2012-08-20
申请人： Stephen R. Keenan , Jonathan Collins , Sunder Ramachandran , Vladimir Jovancicevic , Rose Tompkins , Grahame N. Taylor , Richard L. Martin , Michael L. Walker
发明人： Stephen R. Keenan , Jonathan Collins , Sunder Ramachandran , Vladimir Jovancicevic , Rose Tompkins , Grahame N. Taylor , Richard L. Martin , Michael L. Walker
IPC分类号： C23F11/167 , C23F11/18
CPC分类号： C23F11/1673 , C09K8/532 , C09K8/54 , C10G29/00 , C10G29/24 , C10G75/02 , C23F11/162 , C23F11/184 , C23F11/188
摘要： Aldehydes useful as H2S sulfide scavengers may be corrosive to some metals such as steel, iron and aluminum, but the corrosive effect of the aldehydes may be mitigated by employing a corrosion inhibitor selected from the group consisting of a di-basic soluble phosphate salt, a tri-basic soluble phosphate salt, a phosphate ester, a thiophosphate ester, a thioamine, a Mannich Reaction Product, and combinations thereof.
摘要翻译： 可用作H 2 S硫化物清除剂的醛可能对一些金属如钢，铁和铝具有腐蚀性，但是可以通过使用选自以下的腐蚀抑制剂来缓解醛的腐蚀作用：二碱性可溶性磷酸盐， 三碱性可溶性磷酸盐，磷酸酯，硫代磷酸酯，硫胺，曼尼希反应产物及其组合。
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公开(公告)号：US09260669B2
公开(公告)日：2016-02-16
申请号：US13408657
申请日：2012-02-29
CPC分类号： C10G29/24 , C09K8/52 , C09K2208/20 , C10G19/02 , C10G29/04 , C10G29/06 , C10G29/20 , C10G29/22 , C10G2300/202 , C10G2300/207
摘要： The use of neutral aqueous solutions of glyoxal (pH approximately 6 to 8.5) scavenges H2S that is present in natural gas and in oil better than glyoxal alone or base alone. The resulting scavenger combination significantly increases the reaction rate and the overall scavenging efficiency, i.e. capacity over glyoxal used alone. A buffer may be optionally used. In another embodiment, the combination of non-nitrogen-containing surfactants and glyoxal results in a significant increase in the reaction rate and the overall scavenging efficiency, i.e. capacity as compared to glyoxal used alone.
摘要翻译： 使用乙二醛的中性水溶液（pH约6至8.5）清除天然气和油中存在的H2S比单独的乙二醛或单独的碱清除。 所得的清除剂组合显着增加了反应速率和总体清除效率，即单独使用的乙二醛的能力。 可以任选地使用缓冲器。 在另一个实施方案中，非含氮表面活性剂和乙二醛的组合导致反应速率和总体清除效率的显着增加，即与单独使用的乙二醛相比的容量。
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公开(公告)号：US20130089460A1
公开(公告)日：2013-04-11
申请号：US13253706
申请日：2011-10-05
IPC分类号： C23F11/08
CPC分类号： C09K8/54 , C09K2208/20 , C23F11/184
摘要： Aldehydes useful as H2S sulfide scavengers may be corrosive to some metals such as steel, iron and aluminum, but the corrosive effect of the aldehydes may be mitigated by employing a corrosion inhibitor selected from the group consisting of a di-basic soluble phosphate salt, a tri-basic soluble phosphate salt, and combinations thereof.
摘要翻译： 可用作H 2 S硫化物清除剂的醛可能对一些金属如钢，铁和铝具有腐蚀性，但是可以通过使用选自以下的腐蚀抑制剂来缓解醛的腐蚀作用：二碱性可溶性磷酸盐， 三碱性可溶性磷酸盐及其组合。
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7.发明授权公开(公告)号：US08109161B2
公开(公告)日：2012-02-07
申请号：US12393202
申请日：2009-02-26
IPC分类号： G01M19/00
CPC分类号： G01N25/68 , G01G3/16 , G01N5/04 , G01N17/008 , G01N29/022 , G01N2030/025 , G01N2291/02408 , G01N2291/0256
摘要： Solids deposition in a gas environment, such as a gas transmission line or pipeline are measured using metal-coated quartz crystal microbalance (QCM) in a QCM probe within a high pressure gas chamber in the gas environment. The metal coated on the QCM may be iron, iron alloys and/or iron oxide. The weight measurements are conducted at a constant (ΔT) or controlled (T=f(t)) temperature between the high pressure gas chamber and the QCM probe. The weight gain during a CE cycle is associated with the solids formation rate.
摘要翻译： 在气体环境中的高压气体室内的QCM探针中，使用金属涂覆的石英晶体微量天平（QCM）测量诸如气体输送管线或管道之类的气体环境中的固体沉积。 涂覆在QCM上的金属可以是铁，铁合金和/或氧化铁。 重量测量在高压气室和QCM探头之间的恒定（＆Dgr; T）或受控（T = f（t））温度下进行。 CE循环期间的体重增加与固体形成速率有关。
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8.发明申请Water-Based Formulation of H2S/Mercaptan Scavenger for Fluids in Oilfield and Refinery Applications 有权用于油田和炼油厂应用的流体H2S /硫醇清除剂的水基配方公开(公告)号：US20110315921A1
公开(公告)日：2011-12-29
申请号：US13172370
申请日：2011-06-29
申请人： Sunder Ramachandran , Vladimir Jovancicevic , Ying H. Tsang , Michael P. Squicciarini , Philippe Prince , Jianzhong Yang , Kyle C. Cattanach
发明人： Sunder Ramachandran , Vladimir Jovancicevic , Ying H. Tsang , Michael P. Squicciarini , Philippe Prince , Jianzhong Yang , Kyle C. Cattanach
CPC分类号： C10G29/26 , B01D53/1468 , B01D53/1487 , B01D53/1493 , B01D53/48 , B01D53/52 , B01D2251/304 , B01D2251/306 , B01D2252/103 , B01D2252/20 , B01D2252/60 , B01D2257/304 , B01D2257/306 , C02F1/683 , C02F2101/101 , C02F2101/40 , C02F2103/365 , C10G19/02 , C10G19/04 , C10G29/205 , C10G29/22 , C10G2300/202 , C10G2300/207 , C10G2300/44
摘要： Hydrogen sulfide (H2S) and/or mercaptan scavengers are chemicals that remove H2S and/or mercaptans from gas, oil and water. Water-based formulations may be made and used employing scavenging compounds having the formulae: wherein each R1, R2, R3, and R4 are the same or different and are selected from the group consisting of hydrogen, an alkyl, an alkenyl, an aryl, an acyl, a halogen, a hydroxyl, a nitro, an alkyl ester, an aryl ester, an alkyl ether, an aryl ether, a hydroxymethyl, an anhydride group, an amino, and a sulfide. In one non-limiting embodiment the compounds (A) and (B) do not contain nitrogen atoms. Water-based formulations, such as those using a protic solvent with the above compounds, work well as H2S scavengers.
摘要翻译： 硫化氢（H2S）和/或硫醇清除剂是从气体，油和水中除去H 2 S和/或硫醇的化学物质。 可以使用具有下式的清除化合物制备和使用水性制剂：其中每个R 1，R 2，R 3和R 4相同或不同，并且选自氢，烷基，烯基，芳基， 酰基，卤素，羟基，硝基，烷基酯，芳基酯，烷基醚，芳基醚，羟甲基，酸酐基，氨基和硫醚。 在一个非限制性实施方案中，化合物（A）和（B）不含有氮原子。 水性制剂，例如使用具有上述化合物的质子溶剂的那些制剂，作为H 2 S清除剂能很好地起作用。
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公开(公告)号：US09068269B2
公开(公告)日：2015-06-30
申请号：US13589794
申请日：2012-08-20
申请人： Stephen R. Keenan , Jonathan Collins , Sunder Ramachandran , Vladimir Jovancicevic , Rose Tompkins , Grahame N. Taylor , Richard L. Martin , Michael L. Walker
发明人： Stephen R. Keenan , Jonathan Collins , Sunder Ramachandran , Vladimir Jovancicevic , Rose Tompkins , Grahame N. Taylor , Richard L. Martin , Michael L. Walker
CPC分类号： C23F11/1673 , C09K8/532 , C09K8/54 , C10G29/00 , C10G29/24 , C10G75/02 , C23F11/162 , C23F11/184 , C23F11/188
摘要： Aldehydes useful as H2S sulfide scavengers may be corrosive to some metals such as steel, iron and aluminum, but the corrosive effect of the aldehydes may be mitigated by employing a corrosion inhibitor selected from the group consisting of a di-basic soluble phosphate salt, a tri-basic soluble phosphate salt, a phosphate ester, a thiophosphate ester, a thioamine, a Mannich Reaction Product, and combinations thereof.
摘要翻译： 可用作H 2 S硫化物清除剂的醛可能对一些金属如钢，铁和铝具有腐蚀性，但是可以通过使用选自以下的腐蚀抑制剂来缓解醛的腐蚀作用：二碱性可溶性磷酸盐， 三碱性可溶性磷酸盐，磷酸酯，硫代磷酸酯，硫胺，曼尼希反应产物及其组合。
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10.发明申请公开(公告)号：US20090211335A1
公开(公告)日：2009-08-27
申请号：US12393202
申请日：2009-02-26
CPC分类号： G01N25/68 , G01G3/16 , G01N5/04 , G01N17/008 , G01N29/022 , G01N2030/025 , G01N2291/02408 , G01N2291/0256
摘要： Solids deposition in a gas environment, such as a gas transmission line or pipeline are measured using metal-coated quartz crystal microbalance (QCM) in a QCM probe within a high pressure gas chamber in the gas environment. The metal coated on the QCM may be iron, iron alloys and/or iron oxide. The weight measurements are conducted at a constant (ΔT) or controlled (T=f(t)) temperature between the high pressure gas chamber and the QCM probe. The weight gain during a CE cycle is associated with the solids formation rate.
摘要翻译： 在气体环境中的高压气体室内的QCM探针中，使用金属涂覆的石英晶体微量天平（QCM）测量诸如气体输送管线或管道之类的气体环境中的固体沉积。 涂覆在QCM上的金属可以是铁，铁合金和/或氧化铁。 重量测量在高压气室和QCM探针之间的恒定（DeltaT）或受控（T = f（t））温度下进行。 CE循环期间的体重增加与固体形成速率有关。
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