Sensor for measuring syngas ratio in the high temperature and pressure condition
    1.
    发明授权
    Sensor for measuring syngas ratio in the high temperature and pressure condition 失效
    用于在高温和高压条件下测量合成气比的传感器

    公开(公告)号:US08435448B2

    公开(公告)日:2013-05-07

    申请号:US12756407

    申请日:2010-04-08

    IPC分类号: G01N31/10 G01N27/16 G01N33/00

    摘要: An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.

    摘要翻译: 气体分析装配和方法。 组件包括用于催化气体样品组分的催化剂室,产生一种或多种气体物质作为产物。 产品隔室接收气体种类,并且隔室内的感测元件感测一种或多种气体种类的量。 将该量与含有非催化气体样品的参考室中存在的相同气体物质的量进行比较,提供通过催化产生的气体种类的量。 使用该值,基于催化反应的化学计量来计算气体样品中气体组分的含量。 在优选实施例中,用于分析的气体是用于燃料生产的工艺气体,并且催化剂是催化一氧化碳和水与氢气和二氧化碳的反应的高温变换催化剂。

    Sensor for measuring syngas ratio in the high temperature and pressure condition
    2.
    发明申请
    Sensor for measuring syngas ratio in the high temperature and pressure condition 失效
    用于在高温和高压条件下测量合成气比的传感器

    公开(公告)号:US20100197035A1

    公开(公告)日:2010-08-05

    申请号:US12756407

    申请日:2010-04-08

    摘要: An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.

    摘要翻译: 气体分析装配和方法。 组件包括用于催化气体样品组分的催化剂室,产生一种或多种气体物质作为产物。 产品隔室接收气体种类,并且隔室内的感测元件感测一种或多种气体种类的量。 将该量与含有非催化气体样品的参考室中存在的相同气体物质的量进行比较,提供通过催化产生的气体种类的量。 使用该值,基于催化反应的化学计量来计算气体样品中气体组分的含量。 在优选实施例中,用于分析的气体是用于燃料生产的工艺气体,并且催化剂是催化一氧化碳和水与氢气和二氧化碳的反应的高温变换催化剂。

    Sensor for measuring syngas ratios under high temperature and pressure conditions
    3.
    发明授权
    Sensor for measuring syngas ratios under high temperature and pressure conditions 有权
    用于在高温和高压条件下测量合成气比的传感器

    公开(公告)号:US07754491B2

    公开(公告)日:2010-07-13

    申请号:US11299030

    申请日:2005-12-09

    摘要: An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.

    摘要翻译: 气体分析装配和方法。 组件包括用于催化气体样品组分的催化剂室,产生一种或多种气体物质作为产物。 产品隔室接收气体种类,并且隔室内的感测元件感测一种或多种气体种类的量。 将该量与含有非催化气体样品的参考室中存在的相同气体物质的量进行比较,提供通过催化产生的气体种类的量。 使用该值,基于催化反应的化学计量来计算气体样品中气体组分的含量。 在优选实施例中,用于分析的气体是用于燃料生产的工艺气体,并且催化剂是催化一氧化碳和水与氢气和二氧化碳的反应的高温变换催化剂。

    Method and apparatus for steam hydro-gasification with increased conversion times
    7.
    发明申请
    Method and apparatus for steam hydro-gasification with increased conversion times 有权
    蒸汽加氢气化方法和装置,转化时间越长

    公开(公告)号:US20080312348A1

    公开(公告)日:2008-12-18

    申请号:US12218653

    申请日:2008-07-16

    IPC分类号: C07C27/06 B01J8/24

    摘要: A method and apparatus for converting carbonaceous material to a stream of carbon rich gas, comprising heating a slurry feed containing the carbonaceous material in a hydrogasification process using hydrogen and steam, at a temperature and pressure sufficient to generate a methane and carbon monoxide rich stream in which the conversion time in the process is between 5 and 45 seconds. In particular embodiments, the slurry feed containing the carbonaceous material is fed, along with hydrogen, to a kiln type reactor before being fed to the fluidized bed reactor. Apparatus is provided comprising a kiln type reactor, a slurry pump connected to an input of the kiln type reactor, means for connecting a source of hydrogen to an input of the kiln type reactor; a fluidized bed reactor connected to receive output of the kiln type reactor for processing at a fluidizing zone, and a source of steam and a source of hydrogen connected to the fluidized bed reactor below the fluidizing zone. Optionally, a grinder can be provided in the kiln type reactor.

    摘要翻译: 一种用于将碳质材料转化为富含碳的气体流的方法和装置,包括在足以产生富含甲烷和一氧化碳的流的温度和压力下,使用氢气和蒸汽在加氢气化过程中加热含有碳质材料的浆料进料 该过程中的转换时间在5到45秒之间。 在具体实施方案中,含有碳质材料的浆料进料物料与氢气一起进料到窑式反应器中,然后送入流化床反应器。 提供了包括窑式反应器,连接到窑式反应器的输入端的浆料泵的装置,用于将氢源连接到窑式反应器的输入端的装置; 连接以接收在流化区处理的窑式反应器的输出的流化床反应器,以及连接到流化床下方的流化床反应器的蒸汽源和氢源。 任选地,可以在窑式反应器中提供研磨机。

    Method and apparatus for steam hydro-gasification with increased conversion times
    8.
    发明授权
    Method and apparatus for steam hydro-gasification with increased conversion times 有权
    蒸汽加氢气化方法和装置,转化时间越长

    公开(公告)号:US08143319B2

    公开(公告)日:2012-03-27

    申请号:US12218653

    申请日:2008-07-16

    IPC分类号: C07C27/00

    摘要: A method and apparatus for converting carbonaceous material to a stream of carbon rich gas, comprising heating a slurry feed containing the carbonaceous material in a hydrogasification process using hydrogen and steam, at a temperature and pressure sufficient to generate a methane and carbon monoxide rich stream in which the conversion time in the process is between 5 and 45 seconds. In particular embodiments, the slurry feed containing the carbonaceous material is fed, along with hydrogen, to a kiln type reactor before being fed to the fluidized bed reactor. Apparatus is provided comprising a kiln type reactor, a slurry pump connected to an input of the kiln type reactor, means for connecting a source of hydrogen to an input of the kiln type reactor; a fluidized bed reactor connected to receive output of the kiln type reactor for processing at a fluidizing zone, and a source of steam and a source of hydrogen connected to the fluidized bed reactor below the fluidizing zone. Optionally, a grinder can be provided in the kiln type reactor.

    摘要翻译: 一种用于将碳质材料转化为富含碳的气体流的方法和装置,包括在足以产生富含甲烷和一氧化碳的流的温度和压力下,使用氢气和蒸汽在加氢气化过程中加热含有碳质材料的浆料进料 该过程中的转换时间在5到45秒之间。 在具体实施方案中,含有碳质材料的浆料进料物料与氢气一起进料到窑式反应器中,然后送入流化床反应器。 提供了包括窑式反应器,连接到窑式反应器的输入端的浆料泵的装置,用于将氢源连接到窑式反应器的输入端的装置; 连接以接收在流化区处理的窑式反应器的输出的流化床反应器,以及连接到流化床下方的流化床反应器的蒸汽源和氢源。 任选地,可以在窑式反应器中提供研磨机。

    Commingled coal and biomass slurries
    10.
    发明申请
    Commingled coal and biomass slurries 有权
    混合煤和生物质泥浆

    公开(公告)号:US20090094892A1

    公开(公告)日:2009-04-16

    申请号:US12286165

    申请日:2008-09-29

    IPC分类号: C10J3/00

    摘要: An energy efficient process for converting biomass into a higher carbon content, high energy density slurry. Water and biomass are mixed at a temperature and under a pressure that are much lower than in prior processes, but under a non-oxidative gas, which enables a stable slurry to be obtained containing up to 60% solids by weight, 20-40% carbon by weight, in the slurry. The temperature is nominally about 200° C. under non-oxidative gas pressure of about 150 psi, conditions that are substantially less stringent than those required by the prior art. In another embodiment, the biomass water slurry can be mixed with a coal water slurry to further optimize the carbon content and pumpability of the biomass slurry.

    摘要翻译: 一种将生物质转化为较高碳含量,高能量密度浆料的节能工艺。 水和生物质在比现有方法低得多的温度和压力下进行混合,但是在非氧化性气体下进行混合,这使得能够获得含有高达60重量%固体,20-40重量% 在浆料中。 在约150psi的非氧化性气体压力下,温度基本上不如现有技术所要求的那样苛刻的条件下约为200℃。 在另一个实施方案中,生物质水浆料可以与煤水浆料混合以进一步优化生物质浆料的碳含量和可泵送性。