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15 条记录 (耗时 0.023 秒)

    Amide-modified urethane acrylate radiation curable compounds and coating compositions and methods of making same
    4.
    发明授权
    Amide-modified urethane acrylate radiation curable compounds and coating compositions and methods of making same 失效
    酰胺改性的氨基甲酸酯丙烯酸酯可辐射固化化合物和涂料组合物及其制备方法

    公开(公告)号：US4153776A

    公开(公告)日：1979-05-08

    申请号：US890895

    申请日：1978-03-28

    申请人： Charles B. Friedlander ,  Gerald W. Gruber ,  Rostyslaw Dowbenko

    发明人： Charles B. Friedlander ,  Gerald W. Gruber ,  Rostyslaw Dowbenko

    IPC分类号： C08F2/00 ,  C08F2/48 ,  C08F2/54 ,  C08F290/00 ,  C08F299/00 ,  C08F299/06 ,  C08G18/00 ,  C08G18/67 ,  C08G18/68 ,  C09D175/14 ,  G03F7/038 ,  C08G18/04

    CPC分类号： G03F7/038 ,  C08F299/06 ,  C08G18/672 ,  Y10S525/92

    摘要： Radiation curable compounds are disclosed comprising an amide moiety, a urethane moiety and an ethylenically unsaturated functional group, typically an acrylate functional group. The compounds comprise the reaction products of an amide-containing compound having at least one hydroxy functional group, a polyisocyanate and a polyfunctional compound having a hydroxy functional group reactive with an isocyanato group of the polyisocyanate, which polyfunctional compound provides an ethylenic functional group in the reaction product. Coating compositions containing these radiation curable reaction products cure at relatively high rates to form films having high abrasion resistance and improved tensile strength and elongation properties as compared to conventional urethane acrylate coating compositions.

    摘要翻译： 公开了可辐射固化的化合物，其包含酰胺部分，氨基甲酸酯部分和烯键式不饱和官能团，通常为丙烯酸酯官能团。 该化合物包括具有至少一个羟基官能团的含酰胺化合物，多异氰酸酯和具有与多异氰酸酯的异氰酸酯基反应的羟基官能团的多官能化合物的反应产物，该多官能化合物在其中提供烯属官能团 反应产物。 含有这些可辐射固化反应产物的涂料组合物相对于常规氨基甲酸酯丙烯酸酯涂料组合物相对较高的速率固化，以形成具有高耐磨性和改进的拉伸强度和伸长性能的薄膜。

    Photocatalyst system and ultraviolet light curable coating compositions containing the same
    5.
    发明授权
    Photocatalyst system and ultraviolet light curable coating compositions containing the same 失效
    光催化剂体系和含有该组合物的紫外光固化性涂料组合物

    公开(公告)号：US4017652A

    公开(公告)日：1977-04-12

    申请号：US517572

    申请日：1974-10-23

    申请人： Gerald W. Gruber

    发明人： Gerald W. Gruber

    IPC分类号： C08F2/00 ,  C08F2/50 ,  C09D4/00 ,  C09D163/10 ,  B05D3/06

    CPC分类号： C08F2/50 ,  C08K5/07 ,  C09D163/10

    摘要： The oxygen inhibition of the photopolymerization of acrylic resins is reduced by employing a photocatalyst system containing an aromatic ketone and/or aromatic aldehyde photosensitizer having a triplet energy in the range of from about 54 kilocalories per mole to about 72 kilocalories per mole and which promotes polymerization through bimolecular photochemical reactions of the energy donor type and an aromatic ketone photoinitiator which generates a radical pair by way of unimolecular homolysis resulting from photoexcitation. An exemplary photocatalyst system is benzophenone and isobutyl benzoin ether.

    摘要翻译： 通过使用含有芳族酮和/或芳香族醛光敏剂的光催化剂体系来降低丙烯酸树脂的光聚合的氧气抑制，其具有在约54千卡每摩尔至约72千卡每摩尔的三重态能量范围内，并促进聚合 通过能量给体类型的双分子光化学反应和通过由光激发产生的单分子均聚产生自由基对的芳族酮光引发剂。 示例性的光催化剂体系是二苯甲酮和异丁基苯偶姻醚。

    Positive photoresist compositions having enhanced processing time
    6.
    发明授权
    Positive photoresist compositions having enhanced processing time 失效
    正光致抗蚀剂组合物具有增强的处理时间

    公开(公告)号：US07090958B2

    公开(公告)日：2006-08-15

    申请号：US10411899

    申请日：2003-04-11

    申请人： James E. Jones ,  Randal L. Campbell ,  David A. Diehl ,  Ljiljana Maksimovic ,  Ronald R. Ambrose ,  Gerald W. Gruber

    发明人： James E. Jones ,  Randal L. Campbell ,  David A. Diehl ,  Ljiljana Maksimovic ,  Ronald R. Ambrose ,  Gerald W. Gruber

    IPC分类号： G03F7/023 ,  G03F7/30

    CPC分类号： G03F7/039 ,  G03F7/0233 ,  Y10S430/106 ,  Y10S430/107

    摘要： Novel compositions comprising photoactive polymers comprising a dinitrobenzyl group in conjunction with a photoacid generator are disclosed. In one embodiment, the photoacid generator is a diazide and/or a sulfonyl aceto carbonyl compound. The photoacid generators are typically used in amounts of 10 weight percent or less. The compositions find particular application in storage stable, pH stable, and water stable positive photoresist compositions. Such compositions demonstrate reduced process time as compared with similar compositions lacking the photoacid generator. Methods for using these compositions are also disclosed.

    摘要翻译： 公开了包含与光酸产生剂结合的包含二硝基苄基的光活性聚合物的新型组合物。 在一个实施方案中，光酸产生剂是重氮化物和/或磺酰基乙酰羰基化合物。 光酸产生剂的用量通常为10重量％以下。 该组合物特别适用于储存稳定，pH稳定和水稳定的正性光致抗蚀剂组合物。 与不含光致酸发生剂的类似组合物相比，这种组合物显示出缩短的处理时间。 还公开了使用这些组合物的方法。

    Photodegradation-resistant electrodepositable primer compositions containing hindering aminoether light stabilizers
    7.
    发明授权
    Photodegradation-resistant electrodepositable primer compositions containing hindering aminoether light stabilizers 失效
    含有阻碍氨基醚光稳定剂的耐光降解电沉积底漆组合物

    公开(公告)号：US5385962A

    公开(公告)日：1995-01-31

    申请号：US93572

    申请日：1993-07-19

    申请人： Victor G. Corrigan ,  Gerald W. Gruber ,  Michael A. Polack ,  Robert R. Zwack

    发明人： Victor G. Corrigan ,  Gerald W. Gruber ,  Michael A. Polack ,  Robert R. Zwack

    IPC分类号： B05D7/00 ,  C09D5/44 ,  C08L63/00

    CPC分类号： C09D5/4457 ,  B05D7/53 ,  Y10T428/31522

    摘要： An electrodepositable primer composition having improved delamination resistance with regard to automotive topcoats is disclosed. The composition is particularly useful in conjunction with topcoats which transmit ultraviolet radiation. The composition includes an ionic resin and a hindered amine light stabilizer (HALS) which is preferably a hindered aminoether light stabilizer. A preferred hindered aminoether light stabilizer is bis-(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl)sebacate. The invention also includes a process for coating a substrate by applying the above-described primer composition and subsequently applying a topcoat. The process can alternatively include applying a standard primer composition to a substrate and subsequently applying a HALS compound to the electrodeposited substrate.

    摘要翻译： 公开了一种对汽车面漆具有改善的耐层合性的电沉积底漆组合物。 该组合物特别适用于透射紫外线辐射的面漆。 该组合物包括优选受阻氨基醚光稳定剂的离子树脂和受阻胺光稳定剂（HALS）。 优选的受阻氨基醚光稳定剂是双（1-辛氧基-2,2,6,6-四甲基-4-哌啶基）癸二酸酯。 本发明还包括通过应用上述底漆组合物并随后涂覆顶涂层来涂覆基材的方法。 该方法可以替代地包括将标准底漆组合物施加到基底上，随后将HALS化合物施​​加到电沉积的基底上。

    Photocatalyst system and pigmented actinic light polymerizable coating compositions containing the same
    8.
    发明授权
    Photocatalyst system and pigmented actinic light polymerizable coating compositions containing the same 失效
    光催化剂体系和含有该光催化剂体系的着色光化聚合性涂料组合物

    公开(公告)号：US4024296A

    公开(公告)日：1977-05-17

    申请号：US654499

    申请日：1976-02-02

    申请人： Gerald W. Gruber

    发明人： Gerald W. Gruber

    IPC分类号： B05D3/06 ,  C08F2/50 ,  C08F299/04 ,  G03F7/031

    CPC分类号： G03F7/031 ,  B05D3/067 ,  C08F2/50 ,  C08F299/0435 ,  Y10S430/124

    摘要： A photocatalyst system comprising an aromatic ketone photopolymerization activator having a triplet energy in the range of from about 54 kilocalories per mole to about 72 kilocalories per mole and phenanthrenequinone is present in an actinic light polymerizable coating composition containing organic polymerizable material containing a plurality of sites of ethylenic unsaturation and ultraviolet light absorbing hiding pigment. Coatings of the coating composition are polymerized by exposing them to actinic light of a wavelength where absorption by the pigment is substantial and to actinic light of a wavelength where absorption by the pigment is insubstantial.

    摘要翻译： 包含芳族酮光聚合活化剂的光催化剂体系存在于含有有机可聚合材料的光化聚合性涂料组合物中，该组合物含有约54千卡每摩尔至约72千卡每摩尔和菲醌的三重态能量，该组合物含有多个位点 烯属不饱和度和紫外线吸收隐藏颜料。 通过将涂料组合物的涂料暴露于颜料吸收很大的波长的光化光和通过颜料的吸收无色的波长的光化光下进行聚合。