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公开(公告)号：US4370224A
公开(公告)日：1983-01-25
申请号：US317116
申请日：1981-11-02
IPC分类号： B01J23/89 , B01J27/057 , C10G35/09 , C10G35/085
CPC分类号： B01J23/8926 , B01J27/0573 , C10G35/09
摘要： A catalyst comprised of platinum, iridium, copper, selenium and halogen, composited with an inorganic oxide support or carrier, preferably alumina. The catalyst is one which possesses an intrinsically high activity, is stable, and can operate at reforming conditions at high severities.
摘要翻译： 由铂，铱，铜，硒和卤素组成的催化剂，与无机氧化物载体或载体，优选氧化铝复合。 催化剂是具有本质上高的活性，稳定的催化剂，并且可以在高浓度的重整条件下操作。
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公开(公告)号：US4302359A
公开(公告)日：1981-11-24
申请号：US152669
申请日：1980-05-23
CPC分类号： B01J23/8986 , B01J23/6567 , C10G35/09
摘要： A process for the synthesis of catalysts by pre-forming a porous refractory inorganic oxide support, or carrier from a coarse particulate solid, preferably an alumina extrudate, contacting said preformed support with an acid solution, and then treating, contacting and neutralizing said preformed acid treated support with a base prior to the impregnation of said neutralized support with a metal, or metals, hydrogenation-dehyrdogenation component. The preformed solid support ranges at least about 1/32 inch diameter, and preferably at least about 1/16 inch diameter, and larger.
摘要翻译： 一种通过从粗颗粒固体，优选氧化铝挤出物预先形成多孔耐火无机氧化物载体或载体来合成催化剂的方法，使所述预制载体与酸溶液接触，然后处理，接触和中和所述预成型的酸 在用金属或金属氢化脱硫成分浸渍所述中和的载体之前，用碱处理的载体。 预制的固体支持体的直径至少约为1/32英寸，优选至少约1/16英寸直径，并且更大。
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公开(公告)号：US4251391A
公开(公告)日：1981-02-17
申请号：US29675
申请日：1979-04-13
IPC分类号： C10G35/085 , B01J23/89 , B01J27/02 , B01J27/045 , B01J27/08 , B01J27/10 , C10G35/09 , B01J27/04 , B01J23/64
CPC分类号： B01J23/8986 , C10G35/09
摘要： A catalyst constituted of a composite which includes hydrogenation-dehydrogenation components comprised of platinum and rhenium to which a small amount of copper is added to suppress hydrogenolysis, which is particularly acute in reforming during the early period of operation when the catalyst is placed on stream, i.e., at the startup of a reactor; and process of employing such catalyst in reforming.
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公开(公告)号：US4303500A
公开(公告)日：1981-12-01
申请号：US206091
申请日：1980-11-12
IPC分类号： B01J23/89 , B01J27/057 , C10G35/09 , C10G35/085
CPC分类号： B01J23/8926 , B01J27/0573 , C10G35/09
摘要： A catalyst comprised of platinum, copper, selenium and halogen, composited with an inorganic oxide support or carrier, preferably alumina. The catalyst is one which possesses an intrinsically high activity, is stable and can operate at reforming conditions at high severities.
摘要翻译： 由铂，铜，硒和卤素组成的催化剂，与无机氧化物载体或载体，优选氧化铝复合。 该催化剂是具有本质上高活性的，稳定的并且能够在高浓度的重整条件下操作的催化剂。
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公开(公告)号：US4295957A
公开(公告)日：1981-10-20
申请号：US168491
申请日：1980-07-14
IPC分类号： B01J23/44 , B01J23/656 , B01J23/89 , C10G35/09
CPC分类号： B01J23/44 , B01J23/6567 , B01J23/8986 , C10G35/09
摘要： A catalyst constituted of a composite which includes hydrogenation-dehydrogenation components comprised of palladium and platinum in total concentration ranging from about 0.2 to about 0.6 percent, in molar concentration of palladium:platinum ranging from about 1:1 to about 10:1 composited with an inorganic oxide support. In its preferred aspects the catalyst composite also contains rhenium, and more preferably a small amount of copper is added to suppress hydrogenolysis, which is particularly acute in reforming during the early period of operation when the catalyst is placed on stream, i.e., at the startup of a reactor; and process of employing such catalysts in reforming.
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公开(公告)号：US4292204A
公开(公告)日：1981-09-29
申请号：US53376
申请日：1979-06-29
CPC分类号： C10G35/09 , B01J23/6567
摘要： A catalyst constituted of a composite which includes hydrogenation-dehydrogenation components comprised of palladium and rhenium to which a small amount of iridium is added to increase the aromatic content of the reformate, particularly the high octane C.sub.9.sup.+ aromatics, and reduce the coking tendency of the catalyst. It also encompasses the process of employing such catalyst in reforming, particularly high severity low pressure, semi-regenerative reforming.
摘要翻译： 由复合物组成的催化剂，其包含由钯和铼组成的氢化脱氢组分，其中加入少量铱以增加重整产物的芳族含量，特别是高辛烷值C9 +芳族化合物，并降低催化剂的焦化倾向 。 它还包括在重整，特别是高度苛刻的低压，半再生重整中使用这种催化剂的方法。
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公开(公告)号：US4265786A
公开(公告)日：1981-05-05
申请号：US53375
申请日：1979-06-29
IPC分类号： B01J23/89 , B01J27/057 , C10G35/09 , B01J27/02
CPC分类号： B01J23/8926 , B01J27/0573 , C10G35/09
摘要： A catalyst comprised of platinum, copper, selenium and halogen, composited with an inorganic oxide support or carrier, preferably alumina. The catalyst is one which possesses an intrinsically high activity, is stable and can operate at reforming conditions at high severities.
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公开(公告)号：US4251392A
公开(公告)日：1981-02-17
申请号：US34596
申请日：1979-04-30
IPC分类号： C10G35/085 , B01J23/44 , B01J23/60 , B01J23/656 , B01J23/89 , B01J27/04 , B01J27/045 , B01J27/08 , B01J27/13 , C10G35/09 , B01J27/10
CPC分类号： B01J23/6567 , B01J23/44 , B01J23/8926 , C10G35/09
摘要： A catalyst constituted of a composite which includes hydrogenation-dehydrogenation components comprised of palladium and platinum in total concentration ranging from about 0.2 to about 0.6 percent, in molar concentration of palladium:platinum ranging from about 1:1 to about 10:1 composited with an inorganic oxide support. In its preferred aspects the catalyst composite also contains rhenium, and more preferably a small amount of copper is added to suppress hydrogenolysis, which is particularly acute in reforming during the early period of operation when the catalyst is placed on stream, i.e., at the startup of a reactor; and process of employing such catalysts in reforming.
摘要翻译： 一种由复合材料构成的催化剂，其包括总计为约0.2至约0.6％的钯和铂组成的氢化 - 脱氢组分，钯：铂的摩尔浓度为约1:1至约10:1，其与 无机氧化物载体。 在其优选的方面，催化剂复合材料还含有铼，并且更优选加入少量的铜以抑制氢解，这在催化剂在流动时，即启动时在操作的早期阶段在重整过程中特别急剧 的反应堆; 以及在重整中使用这种催化剂的方法。
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公开(公告)号：US4541915A
公开(公告)日：1985-09-17
申请号：US656714
申请日：1984-10-01
CPC分类号： C10G35/22 , Y10S585/951
摘要： A start-up procedure wherein a halogenated rhenium-containing catalyst, to improve its performance in reforming naphtha feeds, is contacted with water, added with the hydrogen and said feed. During the start-up period, preferably on initiation of the start-up period after aromatics production has begun, a naphtha feed, hydrogen and water are passed cocurrently through the several reactors of a reforming unit and reacted over the halogenated rhenium-containing catalyst. Water is generally added with the naphtha and hydrogen, preferably to the initial reactor of the series of reactors of the reforming unit, in concentration ranging from about 100 vppm of hydrogen to about 10,000 vppm of hydrogen, preferably from about 100 vppm to about 5000 vppm of hydrogen.
摘要翻译： 一种启动方法，其中将卤代铼催化剂改进石脑油进料重整的性能与加入氢气和所述进料的水接触。 在启动期间，优选在芳族化合物生产开始后的启动时段开始时，石脑油进料，氢气和水同时通过重整单元的几个反应器并在卤代含铼催化剂上反应。 水通常与石脑油和氢气一起加入，优选加入到重整单元的一系列反应器的初始反应器中，浓度范围为约100vppm氢气至约10,000vppm氢气，优选约100vppm至约5000vppm 的氢。
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公开(公告)号：US4369129A
公开(公告)日：1983-01-18
申请号：US253080
申请日：1981-04-10
CPC分类号： B01J37/20 , B01J23/36 , B01J23/6567 , B01J23/8986 , B01J37/18 , C10G35/09
摘要： A rhenium-containing catalyst, particularly one comprising platinum and rhenium, composited with a porous inorganic support material, especially alumina, is found to be more selective in hydrocarbon conversion reactions, particularly reforming (hydroforming) when pretreated in a sequence which includes the steps of oxidation, dry hydrogen reduction, and sulfiding. In all embodiments, the hydrogen reduction step is conducted at conditions sufficient to remove product water from the catalyst as it is produced until the catalyst becomes dry, or desiccated, and to continue such treatment until the amount of water contained in the exit gas is less than about 1000 ppm, preferably less than about 500 ppm. In a preferred embodiment, the catalyst is desiccated by an initial high temperature oxidation treat to activate the porous inorganic oxide base, or alumina, and then the hydrogen reduction step is performed at a lower temperature than that employed to effect the oxidation.
摘要翻译： 发现与含多孔无机载体材料，特别是氧化铝复合的含铼催化剂，特别是含有铂和铼的催化剂在烃转化反应中更具选择性，特别是当按顺序进行预处理时重整（液压成型） 氧化，干氢还原和硫化。 在所有实施方案中，氢还原步骤在足以在产生催化剂直到催化剂干燥或干燥之前从催化剂中除去产物水的条件下进行，并继续进行这种处理，直到出口气体中所含的水量少 比约1000ppm，优选小于约500ppm。 在优选的实施方案中，通过初始高温氧化处理来干燥催化剂以活化多孔无机氧化物碱或氧化铝，然后在比用于氧化的温度低的温度下进行氢还原步骤。
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