公开(公告)号：US20140336286A1

公开(公告)日：2014-11-13

申请号：US14339866

申请日：2014-07-24

申请人： Charles Leonard Kibby ,  Robert James Saxton, JR. ,  Kandaswamy Jothimurugesan ,  Tapan Kumar Das ,  Howard Steven Lacheen ,  Michael Bartz ,  Alfred Hass

发明人： Charles Leonard Kibby ,  Robert James Saxton, JR. ,  Kandaswamy Jothimurugesan ,  Tapan Kumar Das ,  Howard Steven Lacheen ,  Michael Bartz ,  Alfred Hass

IPC分类号： B01J29/76 ,  B01J23/89 ,  C07C1/04

CPC分类号： B01J29/7669 ,  B01J23/8986 ,  B01J29/061 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/7469 ,  B01J29/7869 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0203 ,  B01J37/0225 ,  B01J37/0228 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  B01J2229/186 ,  B01J2229/42 ,  B01J2229/60 ,  C07C1/0435 ,  C07C2529/072 ,  C10G2/33 ,  Y10T428/31678

摘要： Disclosed are hybrid synthesis gas conversion catalysts containing at least one Fischer-Tropsch component and at least one acidic component deposited on a monolith catalyst support for use in synthesis gas conversion processes and methods for preparing the catalysts. Also disclosed are synthesis gas conversion processes in which the hybrid synthesis gas conversion catalysts are contacted with synthesis gas to produce a hydrocarbon product containing at least 50 wt % C5+ hydrocarbons. Also disclosed are synthesis gas conversion processes in which at least one layer of Fischer-Tropsch component deposited onto a monolith support is alternated with at least one layer of acidic component in a fixed bed reactor.

摘要翻译： 公开了含有至少一种费 - 托组分和沉积在整体催化剂载体上的至少一种酸性组分的混合合成气转化催化剂，用于合成气转化方法和制备催化剂的方法。 还公开了合成气转化方法，其中混合合成气转化催化剂与合成气体接触以产生含有至少50重量％的C 5+烃的烃产物。 还公开了合成气转化方法，其中沉积在整料载体上的至少一层费 ​​- 托成分与固定床反应器中的至少一层酸性组分交替。

公开(公告)号：US20130210942A1

公开(公告)日：2013-08-15

申请号：US13396466

申请日：2012-02-14

申请人： Charles Leonard Kibby ,  Robert James Saxton, JR. ,  Kandaswamy Jothimurugesan ,  Tapan Kumar Das ,  Howard Steven Lacheen ,  Michael Bartz ,  Alfred Has

发明人： Charles Leonard Kibby ,  Robert James Saxton, JR. ,  Kandaswamy Jothimurugesan ,  Tapan Kumar Das ,  Howard Steven Lacheen ,  Michael Bartz ,  Alfred Has

IPC分类号： B01J35/02 ,  B01J23/75 ,  C07C1/04 ,  B01J37/02

CPC分类号： B01J29/7669 ,  B01J23/8986 ,  B01J29/061 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/7469 ,  B01J29/7869 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0203 ,  B01J37/0225 ,  B01J37/0228 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  B01J2229/186 ,  B01J2229/42 ,  B01J2229/60 ,  C07C1/0435 ,  C07C2529/072 ,  C10G2/33 ,  Y10T428/31678

摘要： Disclosed are hybrid synthesis gas conversion catalysts containing at least one Fischer-Tropsch component and at least one acidic component deposited on a monolith catalyst support for use in synthesis gas conversion processes and methods for preparing the catalysts. Also disclosed are synthesis gas conversion processes in which the hybrid synthesis gas conversion catalysts are contacted with synthesis gas to produce a hydrocarbon product containing at least 50 wt % C5+ hydrocarbons. Also disclosed are synthesis gas conversion processes in which at least one layer of Fischer-Tropsch component deposited onto a monolith support is alternated with at least one layer of acidic component in a fixed bed reactor.

摘要翻译： 公开了含有至少一种费 - 托组分和沉积在整体催化剂载体上的至少一种酸性组分的混合合成气转化催化剂，用于合成气转化方法和制备催化剂的方法。 还公开了合成气转化方法，其中混合合成气转化催化剂与合成气体接触以产生含有至少50重量％的C 5+烃的烃产物。 还公开了合成气转化方法，其中沉积在整料载体上的至少一层费 ​​- 托成分与固定床反应器中的至少一层酸性组分交替。

公开(公告)号：US20140031194A1

公开(公告)日：2014-01-30

申请号：US14041074

申请日：2013-09-30

申请人： Kandaswamy Jothimurugesan ,  Robert James Saxton ,  Howard Steven Lacheen ,  Tapan Kumar Das

发明人： Kandaswamy Jothimurugesan ,  Robert James Saxton ,  Howard Steven Lacheen ,  Tapan Kumar Das

IPC分类号： B01J29/76

CPC分类号： B01J29/7669 ,  B01J23/8913 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/7469 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/035 ,  B01J2229/186 ,  B01J2229/42 ,  C10G2/334 ,  C10G2/341 ,  Y02E60/324

摘要： Methods for preparing integral synthesis gas conversion catalyst extrudates including an oxide of a Fischer-Tropsch (FT) metal component and a zeolite component are disclosed. The oxide of the FT metal component is precipitated from a solution into crystallites having a particle size between about 2 nm and about 30 nm. The oxide of the FT metal component is combined with a zeolite powder and a binder material, and the combination is extruded to form integral catalyst extrudates. The oxide of the FT metal component in the resulting catalyst is in the form of reduced crystallites located outside the zeolite channels. No appreciable ion exchange of FT metal occurs within the zeolite channels. The acid site density of the integral catalyst extrudate is at least about 80% of the zeolite acid site density.

摘要翻译： 公开了制备包含费 - 托（FT）金属组分和沸石组分的氧化物的整体合成气转化催化剂挤出物的方法。 FT金属成分的氧化物从溶液中沉淀成粒径在约2nm至约30nm之间的微晶。 将FT金属成分的氧化物与沸石粉末和粘合剂材料组合，将其组合挤出成一体的催化剂挤出物。 所得催化剂中FT金属组分的氧化物为位于沸石通道外部的微晶形式。 在沸石通道内不发生明显的FT金属离子交换。 整体催化剂挤出物的酸性位点密度为沸石酸性位点密度的至少约80％。

公开(公告)号：US20140241952A1

公开(公告)日：2014-08-28

申请号：US14267211

申请日：2014-05-01

申请人： Charles Leonard Kibby ,  Dennis John O'Rear ,  Robert James Saxton ,  Tapan Kumar Das ,  Kandaswany Jothimurugesan

发明人： Charles Leonard Kibby ,  Dennis John O'Rear ,  Robert James Saxton ,  Tapan Kumar Das ,  Kandaswany Jothimurugesan

IPC分类号： C10G2/00

CPC分类号： C10G2/34 ,  C10G2/32 ,  C10G2/332 ,  C10G2/333 ,  C10G2/341 ,  C10G2/344 ,  C10G5/06 ,  C10G45/02 ,  C10G45/58 ,  C10G47/00 ,  C10G49/00 ,  C10G2300/1022 ,  C10G2300/1033 ,  C10G2300/302 ,  C10G2300/4062

摘要： A process and system are described for the processing of gas associated with crude oil production, i.e. associated gas. A separation complex is used to separate produced fluids produced from a hydrocarbon reservoir into crude oil, liquefied petroleum gas, water, and natural gas. At least a portion of the natural gas is converted into synthesis gas in a synthesis gas generator. A combination of a synthesis gas conversion catalysts and hydroconversion catalysts are used in a synthesis gas reactor to convert the synthesis gas into a liquid effluent stream containing liquefied petroleum gas and a synthetic crude oil. The liquefied petroleum gas and synthetic crude oil from the synthesis gas reactor is sent to the separation complex. Liquefied petroleum gas is separated both from the synthetic crude oil and a natural crude oil obtained from the produced fluids. The system and process permits synthetic crude oil to be blended with the natural crude oil producing a blended stabilized crude oil having 2 wt % or more of the synthetic crude oil and with a pour point of 60° C. or less. Use of a common facility for separation operations on the natural crude oil and synthetic crude oil thus reduces capital costs and allows converted associated gases to be shipped with the natural crude oil on a conventional crude oil tanker.

摘要翻译： 描述了用于处理与原油生产相关的气体，即相关气体的方法和系统。 分离复合物用于将由烃储层产生的产物分离成原油，液化石油气，水和天然气。 至少一部分天然气在合成气发生器中被转化为合成气。 在合成气反应器中使用合成气转化催化剂和加氢转化催化剂的组合，以将合成气转化为含有液化石油气和合成原油的液体流出物流。 将来自合成气反应器的液化石油气和合成原油送至分离复合物。 液化石油气与合成原油和从生产的流体获得的天然原油分离。 该系统和方法允许合成原油与天然原油混合，产生具有2重量％或更多的合成原油并且倾点为60℃或更低的混合稳定的原油。 在天然原油和合成原油上使用通用设施进行分离操作，从而降低资本成本，并允许转换的相关气体与常规原油油轮上的天然原油一起运输。

公开(公告)号：US20140142204A1

公开(公告)日：2014-05-22

申请号：US14163226

申请日：2014-01-24

申请人： Charles Leonard Kibby ,  Dennis John O'Rear ,  Robert James Saxton ,  Tapan Kumar Das ,  Kandaswany Jothimurugesan ,  Allison Amy Evans ,  Michelle Hart

发明人： Charles Leonard Kibby ,  Dennis John O'Rear ,  Robert James Saxton ,  Tapan Kumar Das ,  Kandaswany Jothimurugesan ,  Allison Amy Evans ,  Michelle Hart

IPC分类号： C10G2/00

CPC分类号： C10G2/32 ,  C10G2/332 ,  C10G2/333 ,  C10G2/341 ,  C10G2/344 ,  C10G5/06 ,  C10G45/02 ,  C10G45/58 ,  C10G47/00 ,  C10G49/00 ,  C10G2300/1022 ,  C10G2300/1033 ,  C10G2300/302 ,  C10G2300/4062

摘要： A process and system are described for producing a synthetic crude oil by contacting a synthesis gas with a combination of a synthesis gas conversion catalyst and a hydroconversion catalyst in a synthesis gas reactor. The synthesis gas can be obtained from gas associated with crude oil production, i.e., associated gas, in a synthesis gas generator. The synthetic crude oil can be blended with a natural crude oil to produce a blended stabilized crude oil having 2 wt % or more of the synthetic crude oil. The resulting blended stabilized crude oil has improved flow characteristics including a pour point of 30° C. or less.

摘要翻译： 描述了通过在合成气反应器中使合成气与合成气转化催化剂和加氢转化催化剂的组合接触来制备合成原油的方法和系统。 合成气可以由合成气体发生器中与原油产生相关的气体即相关气体获得。 合成原油可与天然原油混合，生产合成原油的混合稳定原油为2重量％以上。 所得混合稳定的原油具有改善的流动特性，包括30℃或更低的倾点。