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公开(公告)号：US4119616A
公开(公告)日：1978-10-10
申请号：US510392
申请日：1974-09-30
CPC分类号： C08C19/20 , C08F8/44 , C08F2800/20 , Y10S260/31
摘要： A process for sulfonating unsaturated elastomers which comprises sulfonating an olefinically unsaturated elastomer using as the sulfonating agent an acyl sulfate. The products produced thereby have improved properties over those sulfonated elastomers prepared by prior art methods. The preferred acyl sulfate is acetyl sulfate. The sulfonated elastomers of this invention are useful as films, adhesives and for other general purpose rubber uses. Especially advantageous properties are obtained when the sulfonic acid polymer is neutralized with ethylamine.
摘要翻译： 用于磺化不饱和弹性体的方法，其包括使用酰基硫酸盐作为磺化剂磺化烯属不饱和弹性体。 由此生产的产品比通过现有技术方法制备的那些磺化弹性体具有改进的性能。 优选的酰基硫酸盐是乙酰基硫酸盐。 本发明的磺化弹性体可用作膜，粘合剂和其它通用橡胶用途。 当用乙胺中和磺酸聚合物时，可获得特别有利的特性。
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2.发明授权
公开(公告)号：US4117186A
公开(公告)日：1978-09-26
申请号：US766704
申请日：1977-02-08
IPC分类号： D06M15/693 , B32B25/08 , B32B25/10 , B32B25/18 , B32B27/32
CPC分类号： D06M15/693 , Y10T442/291
摘要： Improved butyl rubber-hydrocarbon resin latex compositions are prepared by emulsifying a solution of butyl rubber and a hydrocarbon resin in a one-step process wherein the emulsifying agent is the sodium salt of the sulfate ester of nonylphenoxypoly(ethyleneoxy) ethanol. The films formed therefrom exhibit improved properties over compositions prepared from blends of latices of butyl rubber and hydrocarbon resins.
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公开(公告)号：US4303766A
公开(公告)日：1981-12-01
申请号：US859288
申请日：1977-12-12
摘要： A process for sulfonating polymers which are prepared by solution polymerization using a Friedel-Crafts or Ziegler-type catalyst is disclosed. The reactor effluent containing polymer, unreacted light monomers, diluent-solvent and active catalyst is first treated to remove substantially all unreacted light monomer, e.g. by flashing. The effluent is then treated with a sulfonating agent (e.g. acetyl sulfate and acetic acid) which simultaneously deactivates catalyst. Thereafter, the sulfonated polymer is neutralized, e.g. by exposure to metal salts, organic amines, etc., and subjected to normal finishing operations, e.g. deashing, steam stripping, stabilizing and drying.
摘要翻译： 公开了通过使用Friedel-Crafts或Ziegler型催化剂的溶液聚合制备的磺化聚合物的方法。 首先处理含有反应器流出物的聚合物，未反应的轻单体，稀释剂 - 溶剂和活性催化剂，以除去基本上所有未反应的轻单体，例如， 通过闪烁。 然后用同时使催化剂失活的磺化剂（例如乙酰硫酸盐和乙酸）处理流出物。 此后，中和磺化聚合物，例如 通过暴露于金属盐，有机胺等，并进行正常的精加工操作，例如， 脱水，汽提，稳定和干燥。
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公开(公告)号：US4131586A
公开(公告)日：1978-12-26
申请号：US855763
申请日：1977-11-29
CPC分类号： C08C19/30 , C08F8/14 , C08F8/44 , C08F2810/30
摘要： Polymers having one or more sulfonic acid groups covalently bonded to one or more carbon atoms including the polymer are stabilized against thermal and hydrolytic degradation by reaction with an oxirane. The solid, gel-free hydroxyalkyl sulfonates thus formed are readily converted to thermoplastic ionomers by reaction with a metallic base or salt of a weak acid. The polymeric hydroxy alkylsulfonates possess a low melt viscosity and thus are readily mixed with neutralizing agents, plasticizers or other polymers and thereafter converted to ionomers by reaction with the neutralizing agent which is a metallic base or salt of a weak acid. The formulated solid gel-free ionomers are thermoelastic in nature and can be extruded, injected molded, and compression molded to useful products.
摘要翻译： 具有一个或多个与一个或多个包含聚合物的碳原子共价结合的磺酸基团的聚合物通过与环氧乙烷的反应而稳定化，防止热和水解降解。 由此形成的固体，不含凝胶的羟烷基磺酸盐通过与金属碱或弱酸的盐反应而容易地转化为热塑性离聚物。 聚合羟基烷基磺酸盐具有低熔体粘度，因此易于与中和剂，增塑剂或其它聚合物混合，然后通过与作为金属碱或弱酸的盐的中和剂反应而转变为离聚物。 配制的固体无凝胶离聚物本质上是热弹性的，可以挤出，注射成型和压缩成型为有用的产品。
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公开(公告)号：US4105647A
公开(公告)日：1978-08-08
申请号：US764515
申请日：1977-01-31
摘要： A process for sulfonating polymers which are prepared by solution polymerization using a Friedel-Crafts or Ziegler-type catalyst is disclosed. The reactor effluent containing polymer, unreacted light monomers, diluent-solvent and active catalyst is first treated to remove substantially all unreacted light monomer, e.g. by flashing. The effluent is then treated with a sulfonating agent (e.g. acetyl sulfate and acetic acid) which simultaneously deactivates catalyst. Thereafter, the sulfonated polymer is neutralized, e.g. by exposure to metal salts, organic amines, etc., and subjected to normal finishing operations, e.g. deashing, steam stripping, stabilizing and drying.
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6.发明授权Process for preparing a sulfonated and passivated low unsaturation elastomer cement 失效制备磺化和钝化的低不饱和弹性体水泥的方法
公开(公告)号：US4077933A
公开(公告)日：1978-03-07
申请号：US729415
申请日：1976-10-04
CPC分类号： C08F8/44 , C08F2800/10
摘要： Sulfonated ionomers of low unsaturation polymers in latex form are prepared in an improved process comprising sulfonating a butyl rubber or EPDM elastomer cement with an acyl sulfate, passivating the sulfonated cement with an organic epoxide, such as propylene oxide, and emulsifying the product in water with an anionic emulsifying agent.
摘要翻译： 以胶乳形式的低不饱和聚合物的磺化离聚物以改进的方法制备，包括用酰基硫酸酯磺化丁基橡胶或EPDM弹性体胶泥，用有机环氧化物如环氧丙烷钝化磺化胶泥，并用水 阴离子乳化剂。
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公开(公告)号：US4447338A
公开(公告)日：1984-05-08
申请号：US292235
申请日：1981-08-12
CPC分类号： C09K8/36
摘要： A new family of viscosification agents based on sulfonated ionomers is described for oil-based drilling muds. The resultant muds display good viscosity characteristics and good stability when formulated from ionomers having an appropriate sulfonate level, cation type, and cosolvent content.
摘要翻译： 描述了一种基于磺化离聚物的新型稠化剂系列，用于油基钻井泥浆。 当由具有适当的磺酸盐水平，阳离子类型和共溶剂含量的离聚物配制时，所得泥浆表现出良好的粘度特性和良好的稳定性。
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公开(公告)号：US4134870A
公开(公告)日：1979-01-16
申请号：US855770
申请日：1977-11-29
摘要： This invention relates to elastomeric blend compositions of a neutralized sulfonated elastomeric polymer. The solid, gel-free compositions include a neutralized sulfonated elastomeric polymer, a hydroxyalkyl carboxylate ester, a non-polar wax, wherein the resultant compositions have both improved physical and rheological properties.
摘要翻译： 本发明涉及中和磺化弹性体聚合物的弹性共混组合物。 固体，不含凝胶的组合物包括中和的磺化弹性体聚合物，羧酸羟烷基酯，非极性蜡，其中所得组合物具有改善的物理和流变性质。
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公开(公告)号：US4118353A
公开(公告)日：1978-10-03
申请号：US855545
申请日：1977-11-29
摘要： This invention relates to moldable or extrudable type elastomeric compositions having a viscosity at 200.degree. C at 0.73 sec.sup.-1 of about less than about 10.sup.5 poise. The compositions used for elastomeric articles include 100 parts of a neutralized sulfonated EPDM terpolymer; about 25 to about 150 parts per hundred of a non-polar process oil; about 25 to about 200 parts per hundred of a filler; and about 2 to about 50 parts of a hydroxyalkyl carboxylate ester.These blend compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment into elastomeric articles having excellent physical properties and desirable rubbery characteristics.
摘要翻译： 本发明涉及可模制或可挤压型弹性体组合物，其在200℃，0.73秒-1下的粘度约为约105泊。 用于弹性制品的组合物包括100份中和的磺化EPDM三元共聚物; 每百份非极性加工油约25至约150份; 每百份填料约25至约200份; 和约2-约50份羟烷基羧酸酯。
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10.发明授权
公开(公告)号：US4072648A
公开(公告)日：1978-02-07
申请号：US505341
申请日：1974-09-12
IPC分类号： C09J123/32 , C08K5/01 , C08K5/05 , C08K5/15 , C08L9/00
CPC分类号： C09J123/32 , Y10T428/3188 , Y10T442/3415
摘要： Adhesive contact cements of sulfonated olefinically unsaturated elastomers (sulfobutyl rubber) containing from about 0.1 to about 5.0 mol % SO.sub.3 H neutralized, partially neutralized, or unneutralized, are admixed with tackifiers, i.e. phenolformaldehyde resins, polyisobutylene, alkylphenol formaldehyde resins, petroleum resins, etc. in an amount of between about 5 and about 90 phr in between about 10 and about 50 wt. % solids concentration in organic solvents. These cements are used for adhering porous or non-porous materials such as textiles, wood, cloth, sheets or strip of metals, plastics, etc. to each other. High green strength, high tensile strength, high resistance to peel, even at elevated temperatures, water impermeability, etc. characterize such adhesive layers in laminates. A preferred solvent, 90% toluene, 10% isopropyl alcohol is used in compounding the cement and preferably an organic amine, e.g. ethylamine, is used to partially or completely neutralize the sulfonated elastomer although inorganic bases may also be used for neutralization.
摘要翻译： 将含有约0.1至约5.0mol％SO 3 H中和，部分中和或未中和的磺化烯属不饱和弹性体（磺丁基橡胶）的粘合剂接合剂与增粘剂即酚醛树脂，聚异丁烯，烷基酚甲醛树脂，石油树脂等混合。 其量为约5至约90phr，约10至约50wt。 有机溶剂中固体浓度％。 这些粘固剂用于将诸如纺织品，木材，布，金属，塑料等的多孔或无孔材料粘合到彼此上。 高的生坯强度，高拉伸强度，高耐剥离性，即使在升高的温度下，不透水性等也表征了层压板中的这种粘合剂层。 将优选的溶剂，90％甲苯，10％异丙醇用于配混水泥和优选有机胺，例如， 乙胺用于部分或完全中和磺化弹性体，尽管无机碱也可用于中和。
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