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公开(公告)号：US20050131164A1
公开(公告)日：2005-06-16
申请号：US11002747
申请日：2004-12-02
IPC分类号： C07D491/04 , C07D498/04 , C08G18/00 , C08G18/38 , C08G18/62 , C08G18/79 , C09D175/04
CPC分类号： C08G18/792 , C07D498/04 , C08G18/3827 , C08G18/6229 , C09D175/04
摘要： A process for preparing amide acetals represented in Formula I comprising dehydrating a reactant mixture comprising reactants selected from a group consisting of N-acyl dialkanol amines, O-acyl dialkanol amines and mixtures thereof wherein n and m are independently 2 or 3; p is 1, 2 or 3; R1 and R2 can be the same or different and are each independently hydrogen, a linear or branched alkyl, cycloalkyl or aryl group with 1-20 C atoms; R represents hydrogen, a branched or linear alkyl, cycloalkyl, aryl or an alkenyl group with 1-20 C-atoms, each may have one or more substituents.
摘要翻译： 一种制备式I表示的酰胺缩醛的方法，包括使包含选自N-酰基二链烷醇胺，O-酰基二链烷醇胺及其混合物的反应物的反应物混合物脱水，其中n和m独立地为2或3; p为1,2或3; R 1和R 2可以相同或不同，各自独立地为氢，具有1-20个C原子的直链或支链烷基，环烷基或芳基; R表示氢，具有1-20个C原子的支链或直链烷基，环烷基，芳基或烯基，各自可具有一个或多个取代基。
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公开(公告)号：US20060216525A1
公开(公告)日：2006-09-28
申请号：US11089120
申请日：2005-03-24
申请人： Josef Huybrechts , Koen Linsen , Ann Vaes
发明人： Josef Huybrechts , Koen Linsen , Ann Vaes
CPC分类号： C09D175/12 , C08G18/3857 , C08G18/3889 , C08G18/6254 , C08G18/792 , Y10T428/31551
摘要： The invention is directed to an aqueous coating composition, comprising A) at least one water-dilutable binder with functional groups containing active hydrogen, B) at least one polyisocyanate cross-linking agent with free isocyanate groups, C) at least one amino functional, having at least one group selected from a group consisting of primary amino group, secondary amino group and mixtures thereof, and having at least one group selected from a group consisting of sulfonic acid group, phosphonic acid group and mixtures thereof, and D) water and optionally, E) usual coating additives, pigments and organic solvents.
摘要翻译： 本发明涉及一种水性涂料组合物，其包含A）至少一种具有含活性氢官能团的水可稀释粘合剂，B）至少一种具有游离异氰酸酯基团的多异氰酸酯交联剂，C）至少一个氨基官能团， 具有至少一个选自伯氨基，仲氨基及其混合物的基团，并且具有至少一个选自磺酸基团，膦酸基团及其混合物的基团，D）水和 任选地，E）通常的涂料添加剂，颜料和有机溶剂。
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公开(公告)号：US20060047065A1
公开(公告)日：2006-03-02
申请号：US11194920
申请日：2005-08-02
申请人： Wiebke Becker , Volker Duecoffre , George Hendrickx , Josef Huybrechts , Birgit Kleuser , Johan Rommens , Ann Vaes
发明人： Wiebke Becker , Volker Duecoffre , George Hendrickx , Josef Huybrechts , Birgit Kleuser , Johan Rommens , Ann Vaes
IPC分类号： C08G18/08
CPC分类号： C09D175/04 , C08F212/08 , C08F257/02 , C08G18/6254 , C08G18/722 , C08G18/73 , C08G18/755 , C08G18/7837 , C08G18/792 , C08K5/29 , C08L75/00 , C08L2312/00 , C09D4/06 , C09D133/02 , C09D133/068 , C08F2/06 , C08F220/18 , C08L33/06 , C08F265/06 , C08L2666/20
摘要： The invention is directed to aqueous coating composition comprising A) at least one water-dilutable (meth)acrylate copolymer and B) at least one polyisocyanate cross-linking agent with free isocyanate groups, wherein the (meth)acrylate copolymer comprise a) 10-80% by weight of at least one reaction product of a monoepoxyester and an unsaturated acid functional monomer b) 0-40% by weight of at least one hydroxy functional unsaturated monomer which is different from component a), c) 1-8% by weight of at least one unsaturated acid functional monomer and d) 0-70% by weight of at least one other polymerisable unsaturated monomer, wherein the % by weight of components A) and B) and of components a) to d) is adding up to 100% by weight and wherein the (meth)acrylate copolymer is prepared by a skew feed polymerization process with at least two feed streams and wherein one feed stream comprises the main quantity, namely 60-100% by weight of component a), based on the total amount of component a) and the lower amount, namely 0-30% by weight of the unsaturated acid functional monomer c) based on the total amount of monomer c).
摘要翻译： 本发明涉及包含A）至少一种水可稀释（甲基）丙烯酸酯共聚物和B）至少一种具有游离异氰酸酯基团的多异氰酸酯交联剂的水性涂料组合物，其中（甲基）丙烯酸酯共聚物包含a）10- 80重量％的单环氧酯和不饱和酸官能单体的至少一种反应产物b）0-40重量％的至少一种不同于组分a）的羟基官能不饱和单体，c）1-8％由 至少一种不饱和酸官能单体的重量和d）0-70％重量的至少一种其它可聚合不饱和单体，其中组分A）和B）和组分a）至d）的重量百分比是相加的 至100重量％，并且其中（甲基）丙烯酸酯共聚物通过具有至少两个进料流的偏斜进料聚合方法制备，并且其中一个进料流包含主要量，即组分a）的基于60-100重量％ 对组分a的总量 ），较低的量，即0-30重量％的不饱和酸官能单体c），基于单体c）的总量。
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公开(公告)号：US07439354B2
公开(公告)日：2008-10-21
申请号：US11002747
申请日：2004-12-02
IPC分类号： C07D491/04
CPC分类号： C08G18/792 , C07D498/04 , C08G18/3827 , C08G18/6229 , C09D175/04
摘要： A process for preparing amide acetals represented in Formula I comprising dehydrating a reactant mixture comprising reactants selected from a group consisting of N-acyl dialkanol amines, O-acyl dialkanol amines and mixtures thereof wherein n and m are independently 2 or 3; p is 1, 2 or 3; R1 and R2 can be the same or different and are each independently hydrogen, a linear or branched alkyl, cycloalkyl or aryl group with 1-20 C atoms; R represents hydrogen, a branched or linear alkyl, cycloalkyl, aryl or an alkenyl group with 1-20 C-atoms, each may have one or more substituents.
摘要翻译： 一种制备式I表示的酰胺缩醛的方法，包括使包含选自N-酰基二链烷醇胺，O-酰基二链烷醇胺及其混合物的反应物的反应物混合物脱水，其中n和m独立地为2或3; p为1,2或3; R 1和R 2可以相同或不同，各自独立地为氢，具有1-20个C原子的直链或支链烷基，环烷基或芳基; R表示氢，具有1-20个C原子的支链或直链烷基，环烷基，芳基或烯基，各自可具有一个或多个取代基。
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公开(公告)号：US20060128876A1
公开(公告)日：2006-06-15
申请号：US11009433
申请日：2004-12-10
申请人： Josef Huybrechts , Koen Linsen , Ann Vaes
发明人： Josef Huybrechts , Koen Linsen , Ann Vaes
IPC分类号： C08L31/00
CPC分类号： C08G18/706 , C08G18/0823 , C08G18/6258 , C08G18/792 , C09D175/04
摘要： The invention is directed to an aqueous coating composition, comprising A) at least one water-dilutable binder with functional groups containing active hydrogen, B) at least one polyisocyanate cross-linking agent with free isocyanate groups, C) at least one amino functional and acid functional compound having at least one carboxyl group and at least one group selected from a group consisting of primary amino group, secondary amino group and mixtures thereof, and having preferably a molecular weight of 75 to 1000 g/mole, D) water and optionally, E) usual coating additives, pigments and organic solvents.
摘要翻译： 本发明涉及一种水性涂料组合物，其包含A）至少一种具有含活性氢官能团的水可稀释粘合剂，B）至少一种具有游离异氰酸酯基团的多异氰酸酯交联剂，C）至少一个氨基官能团和 具有至少一个羧基的酸官能化合物和选自伯氨基，仲氨基及其混合物中的至少一种，优选分子量为75至1000g / mol，D）水和任选地 ，E）通常的涂料添加剂，颜料和有机溶剂。
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公开(公告)号：US06646153B1
公开(公告)日：2003-11-11
申请号：US09619320
申请日：2000-07-19
申请人： Josef Huybrechts
发明人： Josef Huybrechts
IPC分类号： C07C27100
CPC分类号： C09D175/04 , C07C271/16 , C08G18/10 , C08G18/3831 , C08G18/44 , C08G18/4854 , C08G18/792
摘要： Hydroxy functional urethane compounds comprising the reaction product of a hydroxy functional urethane intermediate with a compound having at least 2 isocyanate groups, wherein the intermediate is represented by the formula: wherein R1 and R2=hydrogen, alkyl, cycloalkyl or a residue R6—O— or R6—CO—O— with R6; R6=an alkyl, cycloalkyl or benzylic group having up to 18 carbon atoms; R4 and R5=hydrogen or alkyl group containing eventually a hydroxyl group; and R3=alkyl, cycloalkyl or benzylic group eventually containing an ether linkage and/or a hydroxyl group, or HO—CH(R1)—CH(R2)—; and is prepared by reaction of a cyclic 5-ring carbonate with a beta-hydroxy functional, secondary amine. The hydroxy functional urethanes are useful in paints and coatings, particularly for automotive applications.
摘要翻译： 羟基官能氨基甲酸酯化合物，其包含羟基官能氨基甲酸酯中间体与具有至少2个异氰酸酯基团的化合物的反应产物，其中所述中间体由下式表示：其中R 1和R 2 =氢，烷基，环烷基或残基R 6 -O- R6-CO-O-与R6; R6 =具有至多18个碳原子的烷基，环烷基或苄基; R4和R5 =氢或最终含有羟基的烷基; 和R 3 =最终含有醚键和/或羟基的烷基，环烷基或苄基，或HO-CH（R 1）-CH（R 2） - ;并且通过环状5-环碳酸酯与β- 羟基官能团，仲胺。 羟基官能聚氨酯可用于油漆和涂料，特别适用于汽车应用。
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7.发明授权公开(公告)号：US06239214B1
公开(公告)日：2001-05-29
申请号：US09462964
申请日：2000-01-14
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08F290/04 , C08F290/044 , C08F290/046 , C08G18/625 , C08G18/633 , C09D151/00 , C08L2666/14 , C08L2666/02
摘要： The invention concerns a graft copolymer emulsion which is anionically stabilized and which contains an amino-functional monomer. The graft copolymer, useful in a coating composition, has a weight average molecular weight of at least about 3,000 and comprises 20 to 95 weight percent of a polymer backbone and 5 to 80 weight percent of a macromonomer. The polymer backbone further comprises 0.5 to 30 weight percent of an amino-functional monomer and the macromonomer comprises at least about 5 weight percent of an unsaturated acid-functional monomer.
摘要翻译： 本发明涉及阴离子稳定并含有氨基官能单体的接枝共聚物乳液。 可用于涂料组合物中的接枝共聚物的重均分子量为至少约3,000，并且包含20至95重量％的聚合物主链和5至80重量％的大分子单体。 聚合物主链还包含0.5至30重量％的氨基官能单体，大分子单体包含至少约5重量％的不饱和酸官能单体。
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公开(公告)号：US06624227B1
公开(公告)日：2003-09-23
申请号：US09462966
申请日：2000-07-12
IPC分类号： C08K308
CPC分类号： C09C1/644 , C01P2004/20 , C08F8/40 , C09C1/622 , C09D5/38
摘要： The invention provides an aqueous coating composition comprising nonionically and/or anionically stabilized film-forming polymers and metallic pigments and a compound which is the reaction product of a phosphonic acid derivative, a hydroxy-functional addition polymers and, optionally a compound having a hydroxy group, in which the phosphonic acid derivative is selected from one or both of wherein R and R′ are selected from the group consisting of an aliphatic and an aromatic substituent having 1 to 25 carbon atoms optionally including heteroatoms of at least one of oxygen, phosphorus and silicon.
摘要翻译： 本发明提供一种水性涂料组合物，其包含非离子和/或阴离子稳定的成膜聚合物和金属颜料，以及作为膦酸衍生物，羟基官能加成聚合物和任选具有羟基的化合物的反应产物的化合物 其中膦酸衍生物选自其中一个或两个，其中R和R'选自具有1至25个碳原子的脂族和芳族取代基，任选地包括氧，磷和硅中的至少一个的杂原子 。
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公开(公告)号：US06558796B2
公开(公告)日：2003-05-06
申请号：US09731305
申请日：2000-12-06
IPC分类号： B23B2738
CPC分类号： C09D5/38 , C08G59/4071 , C09D163/00 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , C08L2666/54
摘要： The invention is directed to gassing stabilized aqueous coating compositions comprising A) a metallic pigment and at least one reaction product of: (a) 5 to 95 weight percent of a at least one phosphonic acid derivative selected form compound I and II wherein R1 is H or O═P(OH)2; R2 and R3 are independently H, OH or an aliphatic, cycloaliphatic and aromatic substituent having 1 to 25 carbon atoms and optionally up to 10 heteroatoms of at least one of oxygen and phosphorus; and R′ is an aliphatic, cycloaliphatic and aromatic substituent having 1 to 25 carbon atoms and optionally up to 10 heteroatoms of at least one of oxygen and phosphorus; (b) 5 to 95 weight percent of a at least one compound having at least two epoxy groups and a number average molecular weight Mn of 300 to 5000 g/mol; and (c) 0 to 90 weight percent of a compound having one epoxy-functional group, wherein the proportions by weight of components (a), (b) and (c) total 100 weight percent. B) at least one metallic pigment.
摘要翻译： 本发明涉及放气稳定的水性涂料组合物，其包含A）金属颜料和至少一种反应产物：（a）5-95重量％的选自化合物I和II的至少一种膦酸衍生物，其中R 1是H或O = P（OH）2; R2和R3独立地是H，OH或具有1至25个碳原子和任选至多10个氧和磷中的至少一个的杂原子的脂族，脂环族和芳族取代基; 并且R'是具有1至25个碳原子和任选至多10个至少10个氧和磷的杂原子的脂族，脂环族和芳族取代基;（b）5至95重量％的至少一种具有至少两个 环氧基，数均分子量Mn为300〜5000g / mol; 和（c）0至90重量％的具有一个环氧官能团的化合物，其中组分（a），（b）和（c）的重量百分比总计为100重量％。B）至少一种金属颜料。
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公开(公告)号：US06503975B1
公开(公告)日：2003-01-07
申请号：US09538104
申请日：2000-03-29
申请人： Josef Huybrechts
发明人： Josef Huybrechts
IPC分类号： C08K320
CPC分类号： C09D151/003 , C08F290/06 , C08F290/061 , C08F291/08 , C08F293/005 , C09D153/00 , C08L2666/02
摘要： Emulsions are disclosed which contain (a) an aqueous carrier and (b) a polymer mixture of (1) 40-99.5% by weight of a copolymer with a weight average molecular weight of at least 3000; and (2) 0.5-60% by weight of a stabilizing copolymer dispersed in water, wherein the stabilizing copolymer comprises a structured polymer having a hydrophobic portion and a hydrophilic portion, wherein said structured polymer is selected from the group consisting of (i) polymers comprising 5-95% by weight of a hydrophilic macromonomer having at least 10% of an acid functional monomer and 5-95% by weight of at least one hydrophobic monomer polymerized in the presence of the macromonomer; and (ii) polymers comprising 5-95% by weight of a hydrophobic macromonomer and 5-95% by weight of hydrophilic copolymer comprising at least 10% of an acid functional monomer polymerized in the presence of the macromonomer.
摘要翻译： 公开了含有（a）水性载体和（b）（1）40-99.5重量％的重均分子量为至少3000的共聚物的聚合物混合物的乳液; 和（2）分散在水中的0.5-60重量％的稳定共聚物，其中所述稳定共聚物包含具有疏水部分和亲水部分的结构化聚合物，其中所述结构化聚合物选自（i）聚合物 包含5-95重量％的具有至少10％酸官能单体和5-95重量％至少一种在大分子单体存在下聚合的疏水单体的亲水性大分子单体; 和（ii）包含5-95重量％的疏水性大分子单体和5-95重量％的包含至少10％的在大分子单体存在下聚合的酸官能单体的亲水性共聚物的聚合物。
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