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1.发明授权公开(公告)号：US07737313B2
公开(公告)日：2010-06-15
申请号：US11643550
申请日：2006-12-21
申请人： Christine N. Elia , Frederick Y. Lo , Michael C. Clark , C. Morris Smith , Michael Hryniszak , Mohan Kalyanaraman
发明人： Christine N. Elia , Frederick Y. Lo , Michael C. Clark , C. Morris Smith , Michael Hryniszak , Mohan Kalyanaraman
IPC分类号： C07C2/66
CPC分类号： B01J29/7038 , B01J29/7007 , B01J29/80 , B01J37/0009 , B01J37/0036 , B01J2229/42 , C07C2/66 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C15/073
摘要： A catalyst composition comprises (a) a MCM-22 family molecular sieve; and (b) a binder, wherein the MCM-22 family molecular sieve is characterized by an average crystal agglomerate size of less than or equal to 16 microns. The catalyst composition may further have a second molecular sieve having a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent.
摘要翻译： 催化剂组合物包含（a）MCM-22族分子筛; 和（b）粘合剂，其中MCM-22族分子筛的特征在于平均晶体聚集体尺寸小于或等于16微米。 催化剂组合物还可以具有约束指数小于12，例如小于2的第二分子筛。可用于本发明的分子筛的实例是MCM-22族分子筛，Y沸石和β沸石。 催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。
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2.发明申请公开(公告)号：US20080154081A1
公开(公告)日：2008-06-26
申请号：US11643550
申请日：2006-12-21
申请人： Christine N. Elia , Frederick Y. Lo , Michael C. Clark , Morris C. Smith , Michael Hryniszak , Mohan Kalyanaraman
发明人： Christine N. Elia , Frederick Y. Lo , Michael C. Clark , Morris C. Smith , Michael Hryniszak , Mohan Kalyanaraman
CPC分类号： B01J29/7038 , B01J29/7007 , B01J29/80 , B01J37/0009 , B01J37/0036 , B01J2229/42 , C07C2/66 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C15/073
摘要： A catalyst composition comprises (a) a MCM-22 family molecular sieve; and (b) a binder, wherein the MCM-22 family molecular sieve is characterized by an average crystal agglomerate size of less than or equal to 16 microns. The catalyst composition may further have a second molecular sieve having a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent.
摘要翻译： 催化剂组合物包含（a）MCM-22族分子筛; 和（b）粘合剂，其中MCM-22族分子筛的特征在于平均晶体聚集体尺寸小于或等于16微米。 催化剂组合物还可以具有约束指数小于12，例如小于2的第二分子筛。可用于本发明的分子筛的实例是MCM-22族分子筛，Y沸石和β沸石。 催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。
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公开(公告)号：US07038100B2
公开(公告)日：2006-05-02
申请号：US09845856
申请日：2001-04-30
申请人： Ajit B. Dandekar , John P. McWilliams , Thomas Francis Degnan , Michael Hryniszak , Donald J. Klocke , Wieslaw Jerzy Roth
发明人： Ajit B. Dandekar , John P. McWilliams , Thomas Francis Degnan , Michael Hryniszak , Donald J. Klocke , Wieslaw Jerzy Roth
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/085
摘要： The present invention provides a process for producing an alkylaromatic compound comprising the step of contacting an alkylatable aromatic compound with an alkylating agent under alkylation conditions in the presence of a alkylation catalyst comprising phosphorus and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including the d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom.
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公开(公告)号：US20100056835A1
公开(公告)日：2010-03-04
申请号：US12615817
申请日：2009-11-10
CPC分类号： C07C15/085 , C07C2/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/70 , Y02P20/52
摘要： A process for producing cumene is provided which comprises the step of contacting benzene and propylene under at least partial liquid phase alkylating conditions with a particulate molecular sieve alkylation catalyst, wherein the particles of said alkylation catalyst have a surface to volume ratio of about 80 to less than 200 inch−1.
摘要翻译： 提供了生产枯烯的方法，其包括在至少部分液相烷基化条件下使苯和丙烯与颗粒分子筛烷基化催化剂接触的步骤，其中所述烷基化催化剂的颗粒的表面与体积比为约80至少 超过200英寸-1。
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公开(公告)号：US20050209493A1
公开(公告)日：2005-09-22
申请号：US11128721
申请日：2005-05-13
申请人： Ajit Dandekar , John McWilliams , Thomas Degnan , Michael Hryniszak , Donald Klocke , Wieslaw Roth
发明人： Ajit Dandekar , John McWilliams , Thomas Degnan , Michael Hryniszak , Donald Klocke , Wieslaw Roth
IPC分类号： B01J29/70 , C07B61/00 , C07C2/12 , C07C2/66 , C07C15/073 , C07C15/085 , C07C2/68
CPC分类号： C07C2/66 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/085
摘要： The present invention provides a process for producing an alkylaromatic compound comprising the step of contacting an alkylatable aromatic compound with an alkylating agent under alkylation conditions in the presence of a alkylation catalyst comprising phosphorus and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including the d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom.
摘要翻译： 本发明提供一种生产烷基芳族化合物的方法，包括使烷基化芳族化合物与烷基化剂在烷基化条件下在包含磷的烷基化催化剂和具有X射线衍射图的多孔结晶无机氧化物材料存在下接触的步骤 包括12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值。
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公开(公告)号：US07868215B2
公开(公告)日：2011-01-11
申请号：US12615817
申请日：2009-11-10
CPC分类号： C07C15/085 , C07C2/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/70 , Y02P20/52
摘要： A process for producing cumene is provided which comprises the step of contacting benzene and propylene under at least partial liquid phase alkylating conditions with a particulate molecular sieve alkylation catalyst, wherein the particles of said alkylation catalyst have a surface to volume ratio of about 80 to less than 200 inch−1.
摘要翻译： 提供了生产枯烯的方法，其包括在至少部分液相烷基化条件下使苯和丙烯与颗粒分子筛烷基化催化剂接触的步骤，其中所述烷基化催化剂的颗粒的表面与体积比为约80至少 超过200英寸-1。
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公开(公告)号：US20080154082A1
公开(公告)日：2008-06-26
申请号：US11660223
申请日：2005-08-05
IPC分类号： C07C2/66
CPC分类号： C07C409/08 , C07C2/66 , C07C15/02 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , Y02P20/127 , C07C49/10 , C07C39/04
摘要： A process for producing sec-butylbenzene comprises contacting a feed comprising benzene and ethylene under alkylation conditions with catalyst comprising (i) a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom and (ii) at least one metal selected from Group 10 of the Periodic Table of Elements to produce an alkylation effluent comprising sec-butylbenzene.
摘要翻译： 一种生产仲丁基苯的方法包括在烷基化条件下将包含苯和乙烯的进料与催化剂接触，所述催化剂包括（i）具有包含d-间距最大值的X射线衍射图的分子筛在12.4±0.25,6.9±0.15,3.57± 0.07和3.42±0.07埃和（ii）选自元素周期表第10族的至少一种金属，以产生包含仲丁基苯的烷基化流出物。
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公开(公告)号：US06888037B2
公开(公告)日：2005-05-03
申请号：US10319161
申请日：2002-12-13
IPC分类号： C07B61/00 , C07C2/66 , C07C6/12 , C07C15/085
CPC分类号： C07C15/085 , C07C2/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/70 , Y02P20/52
摘要： A process for producing cumene is provided which comprises the step of contacting benzene and propylene under at least partial liquid phase alkylating conditions with a particulate molecular sieve alkylation catalyst, wherein the particles of said alkylation catalyst have a surface to volume ratio of about 80 to less than 200 inch−1.
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公开(公告)号：US07569739B2
公开(公告)日：2009-08-04
申请号：US11873865
申请日：2007-10-17
申请人： Ajit B. Dandekar , John P. McWilliams , Thomas Francis Degnan , Michael Hryniszak , Donald J. Klocke , Wieslaw Jerzy Roth
发明人： Ajit B. Dandekar , John P. McWilliams , Thomas Francis Degnan , Michael Hryniszak , Donald J. Klocke , Wieslaw Jerzy Roth
IPC分类号： C07C2/68
CPC分类号： C07C2/66 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/085
摘要： The present invention provides a process for producing an alkylaromatic compound comprising the step of contacting an alkylatable aromatic compound with an alkylating agent under alkylation conditions in the presence of a alkylation catalyst comprising phosphorus and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including the d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom.
摘要翻译： 本发明提供一种生产烷基芳族化合物的方法，包括使烷基化芳族化合物与烷基化剂在烷基化条件下在包含磷的烷基化催化剂和具有X射线衍射图的多孔结晶无机氧化物材料存在下接触的步骤 包括12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值。
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公开(公告)号：US20080045765A1
公开(公告)日：2008-02-21
申请号：US11876233
申请日：2007-10-22
申请人： Ajit Dandekar , Michael Hryniszak , David Stern
发明人： Ajit Dandekar , Michael Hryniszak , David Stern
IPC分类号： C07C2/00
CPC分类号： C07C15/085 , C07C2/66 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/70 , Y02P20/52
摘要： A process for producing cumene is provided which comprises the step of contacting benzene and propylene under at least partial liquid phase alkylating conditions with a particulate molecular sieve alkylation catalyst, wherein the particles of said alkylation catalyst have a surface to volume ratio of about 80 to less than 200 inch−1.
摘要翻译： 提供了生产枯烯的方法，其包括在至少部分液相烷基化条件下使苯和丙烯与颗粒分子筛烷基化催化剂接触的步骤，其中所述烷基化催化剂的颗粒的表面与体积比为约80至少 超过200英寸 -1。
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