公开(公告)号：US06911568B1

公开(公告)日：2005-06-28

申请号：US10239372

申请日：2000-04-28

Applicant: Ajit B. Dandekar ,  John P. McWilliams ,  C. Morris Smith ,  Michael A. Better ,  Wei-Ping Tai

Inventor： Ajit B. Dandekar ,  John P. McWilliams ,  C. Morris Smith ,  Michael A. Better ,  Wei-Ping Tai

IPC: C07C2/66

CPC classification number: C07C2/66 ,  Y02P20/584 ,  C07C15/085 ,  C07C15/073

Abstract: A process for alkylating an alkylatable aromatic compound is disclosed, in which the process includes: (a) contacting the alkylatable aromatic compound and an alkylating agent with an alkylation catalyst under alkylation conditions; and (b) when said alkylation catalyst has become at least partially deactivated, contacting said alkylation catalyst with a C1-C8 hydrocarbon under alkylation catalyst reactivation conditions. The process provides comparable rejuvenation of catalyst activity as air rengenaration with minimal or no increase in amounts of undesirable byproducts such as polypropylbenzenes in the case of benzene alkylation with propylene.

Abstract translation: 公开了一种烷基化可烷基化芳族化合物的方法，其中该方法包括：（a）在烷基化条件下使烷基化芳族化合物与烷基化剂与烷基化催化剂接触; 和（b）当所述烷基化催化剂至少部分失活时，在烷基化催化剂再活化条件下使所述烷基化催化剂与C 1 -C 8 -C 8烃接触。 在苯与丙烯烷基化的情况下，该方法提供了与空气再生相当的催化剂活性的可比的复原，其中不希望的副产物（例如聚丙苯）的量最小或没有增加。

公开(公告)号：US07737313B2

公开(公告)日：2010-06-15

申请号：US11643550

申请日：2006-12-21

Applicant: Christine N. Elia ,  Frederick Y. Lo ,  Michael C. Clark ,  C. Morris Smith ,  Michael Hryniszak ,  Mohan Kalyanaraman

Inventor： Christine N. Elia ,  Frederick Y. Lo ,  Michael C. Clark ,  C. Morris Smith ,  Michael Hryniszak ,  Mohan Kalyanaraman

IPC: C07C2/66

CPC classification number: B01J29/7038 ,  B01J29/7007 ,  B01J29/80 ,  B01J37/0009 ,  B01J37/0036 ,  B01J2229/42 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/085 ,  C07C15/073

Abstract: A catalyst composition comprises (a) a MCM-22 family molecular sieve; and (b) a binder, wherein the MCM-22 family molecular sieve is characterized by an average crystal agglomerate size of less than or equal to 16 microns. The catalyst composition may further have a second molecular sieve having a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent.

Abstract translation: 催化剂组合物包含（a）MCM-22族分子筛; 和（b）粘合剂，其中MCM-22族分子筛的特征在于平均晶体聚集体尺寸小于或等于16微米。 催化剂组合物还可以具有约束指数小于12，例如小于2的第二分子筛。可用于本发明的分子筛的实例是MCM-22族分子筛，Y沸石和β沸石。 催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。

公开(公告)号：US5557024A

公开(公告)日：1996-09-17

申请号：US452919

申请日：1995-05-30

Applicant: Jane C. Cheng ,  Anthony D. Fung ,  Donald J. Klocke ,  Stephen L. Lawton ,  Daria N. Lissy ,  Wieslaw J. Roth ,  C. Morris Smith ,  Dennis E. Walsh

Inventor： Jane C. Cheng ,  Anthony D. Fung ,  Donald J. Klocke ,  Stephen L. Lawton ,  Daria N. Lissy ,  Wieslaw J. Roth ,  C. Morris Smith ,  Dennis E. Walsh

IPC: B01J20/18 ,  B01J29/03 ,  B01J29/06 ,  B01J29/40 ,  B01J29/70 ,  C01B33/38 ,  C01B35/00 ,  C01B39/00 ,  C01B39/02 ,  C01B39/48 ,  C07C2/66 ,  C07C15/02 ,  C10G35/06 ,  C10G35/095

CPC classification number: B01J29/70 ,  B01J37/0009 ,  C01B33/38 ,  B01J2229/42

Abstract: Relatively short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively short chain alkylating agent under sufficient reaction conditions in the presence of a catalyst comprising zeolite MCM-56. The liquid phase syntheses of ethylbenzene and cumene are particular examples of such MCM-56 catalyzed reactions.

公开(公告)号：US5371310A

公开(公告)日：1994-12-06

申请号：US78369

申请日：1993-06-16

Applicant: J. Michael Bennett ,  Clarence D. Chang ,  Jane C. Cheng ,  Stephen L. Lawton ,  Michael E. Leonowicz ,  Daria N. Lissy ,  Mae K. Rubin ,  C. Morris Smith ,  Dennis E. Walsh

Inventor： J. Michael Bennett ,  Clarence D. Chang ,  Jane C. Cheng ,  Stephen L. Lawton ,  Michael E. Leonowicz ,  Daria N. Lissy ,  Mae K. Rubin ,  C. Morris Smith ,  Dennis E. Walsh

IPC: B01J29/06 ,  B01J29/70 ,  C01B39/04 ,  C01B39/06 ,  C01B39/48 ,  C07B61/00 ,  C07C2/02 ,  C07C2/66 ,  C07C15/02 ,  C07C37/14 ,  C07C37/16 ,  C07C39/06 ,  C10G11/05 ,  C10G35/095

CPC classification number: B01J29/7038 ,  B01J29/70 ,  B01J29/7049 ,  B01J29/87 ,  C01B39/065 ,  C01B39/48 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42

Abstract: Relatively short chain alkyl aromatic compounds are prepared by alkylating or transalkylating an alkylatable aromatic compound with a relatively short chain alkylating or transalkylating agent under sufficient reaction conditions in the presence of catalyst comprising zeolite MCM-49.

Abstract translation: 通过在足够的反应条件下，在含有沸石MCM-49的催化剂的存在下，用相对短链的烷基化或烷基转移剂烷基化或烷基化烷基化芳族化合物来制备相对短链的烷基芳族化合物。

公开(公告)号：US20100304959A1

公开(公告)日：2010-12-02

申请号：US12767559

申请日：2010-04-26

Applicant: Christine N. Elia ,  Frederick Y. Lo ,  Michael C. Clark ,  C. Morris Smith ,  Mohan Kalyanaraman

Inventor： Christine N. Elia ,  Frederick Y. Lo ,  Michael C. Clark ,  C. Morris Smith ,  Mohan Kalyanaraman

IPC: B01J29/06

CPC classification number: B01J29/7038 ,  B01J29/7007 ,  B01J29/80 ,  B01J37/0009 ,  B01J37/0036 ,  B01J2229/42 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/085 ,  C07C15/073

Abstract: A catalyst composition comprises (a) a MCM-22 family molecular sieve; and (b) a binder, wherein the MCM-22 family molecular sieve is characterized by an average crystal agglomerate size of less than or equal to 16 microns. The catalyst composition may further have a second molecular sieve having a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent.

Abstract translation: 催化剂组合物包含（a）MCM-22族分子筛; 和（b）粘合剂，其中MCM-22族分子筛的特征在于平均晶体聚集体尺寸小于或等于16微米。 催化剂组合物还可以具有约束指数小于12，例如小于2的第二分子筛。可用于本发明的分子筛的实例是MCM-22族分子筛，Y沸石和β沸石。 催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。

公开(公告)号：US06984761B2

公开(公告)日：2006-01-10

申请号：US10320237

申请日：2002-12-16

Applicant: Doron Levin ,  C. Morris Smith ,  Jose Guadalupe Santiesteban ,  James C. Vartuli

Inventor： Doron Levin ,  C. Morris Smith ,  Jose Guadalupe Santiesteban ,  James C. Vartuli

IPC: C07C45/33 ,  C07C37/68 ,  C07C37/08 ,  C07C4/02

CPC classification number: C07C409/10 ,  B01J23/75 ,  B01J27/1853 ,  B01J37/03 ,  C07C1/20 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C2521/06 ,  C07C2523/28 ,  C07C2527/054 ,  Y02P20/52 ,  C07C15/44 ,  C07C49/08 ,  C07C39/04

Abstract: A process is disclosed for producing α-methylstyrene, acetone, and phenol wherein the amount of α-methylstyrene produced may be controlled by selectively converting a portion of the cumene hydroperoxide to dimethyl phenyl carbinol, the hydrated form of α-methylstyrene. The dimethyl phenyl carbinol thus produced will lead to increased production of α-methylstyrene upon dehydration in the acid cleavage unit of the phenol plant. By controlling the fraction of the cumene hydroperoxide reduced to dimethyl phenyl carbinol, the amount of α-methylstyrene produced in the plant can be continuously set to meet the demand of the market for α-methylstyrene. Also disclosed is a non-acidic catalyst for reduction of cumene hydroperoxide.

Abstract translation: 公开了用于生产α-甲基苯乙烯，丙酮和苯酚的方法，其中可以通过选择性地将一部分氢过氧化枯烯选择性转化为甲基苯乙烯的水合形式的二甲基苯基甲醇来控制所产生的α-甲基苯乙烯的量。 这样生产的二甲基苯甲醇将导致苯酚装置的酸裂解装置脱水时α-甲基苯乙烯的生产增加。 通过控制还原成二甲苯基甲醇的氢过氧化枯烯的分数，可以连续设定工厂生产的α-甲基苯乙烯的量以满足α-甲基苯乙烯市场的需求。 还公开了用于还原枯烯氢过氧化物的非酸性催化剂。

公开(公告)号：US07960304B2

公开(公告)日：2011-06-14

申请号：US12767559

申请日：2010-04-26

Applicant: Christine N. Elia ,  Frederick Y. Lo ,  Michael C. Clark ,  C. Morris Smith ,  Mohan Kalyanaraman

Inventor： Christine N. Elia ,  Frederick Y. Lo ,  Michael C. Clark ,  C. Morris Smith ,  Mohan Kalyanaraman

IPC: B01J29/06

CPC classification number: B01J29/7038 ,  B01J29/7007 ,  B01J29/80 ,  B01J37/0009 ,  B01J37/0036 ,  B01J2229/42 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/085 ,  C07C15/073

Abstract: A catalyst composition comprises (a) a MCM-22 family molecular sieve; and (b) a binder, wherein the MCM-22 family molecular sieve is characterized by an average crystal agglomerate size of less than or equal to 16 microns. The catalyst composition may further have a second molecular sieve having a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent.

Abstract translation: 催化剂组合物包含（a）MCM-22族分子筛; 和（b）粘合剂，其中MCM-22族分子筛的特征在于平均晶体聚集体尺寸小于或等于16微米。 催化剂组合物还可以具有约束指数小于12，例如小于2的第二分子筛。可用于本发明的分子筛的实例是MCM-22族分子筛，Y沸石和β沸石。 催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。

公开(公告)号：US5600048A

公开(公告)日：1997-02-04

申请号：US364145

申请日：1994-12-27

Applicant: Jane C. Cheng ,  C. Morris Smith ,  Chaya R. Venkat ,  Dennis E. Walsh

Inventor： Jane C. Cheng ,  C. Morris Smith ,  Chaya R. Venkat ,  Dennis E. Walsh

IPC: B01J29/70 ,  C07C2/66 ,  C07C6/12 ,  C07C15/073

CPC classification number: C07C15/073 ,  C07C6/126 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/582

Abstract: There is provided a process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation. The liquid phase alkylation reaction may be catalyzed by an acidic solid oxide, such as MCM-22, MCM-49 and MCM-56. The vapor phase transalkylation may be catalyzed by a medium-pore size zeolite such as ZSM-5. The process may be run continuously with the continuous introduction of fresh benzene feed containing at least 500 ppm of nonbenzene hydrocarbon impurities. The combined ethylbenzene product of these alkylation and transalkylation reactions has very low levels of impurities including xylene, hydrocarbons having 7 or less carbon atoms and hydrocarbons having 9 or more carbon atoms.

Abstract translation: 提供了使用液相烷基化和气相烷基转移制备乙苯的方法。 液相烷基化反应可以由酸性固体氧化物如MCM-22，MCM-49和MCM-56催化。 气相烷基转移可以通过中等孔径的沸石催化，例如ZSM-5。 该方法可以连续引入含有至少500ppm非苯烃杂质的新鲜苯进料而连续进行。 这些烷基化和烷基转移反应的组合乙苯产物具有非常低的杂质含量，包括二甲苯，具有7个或更少碳原子的烃和具有9个或更多个碳原子的烃。

公开(公告)号：US5493065A

公开(公告)日：1996-02-20

申请号：US319318

申请日：1994-10-06

Applicant: Jane C. Cheng ,  C. Morris Smith ,  Dennis E. Walsh

Inventor： Jane C. Cheng ,  C. Morris Smith ,  Dennis E. Walsh

IPC: B01J29/06 ,  C07B61/00 ,  C07C2/66 ,  C07C15/073

CPC classification number: C07C2/66 ,  C07C2529/70

Abstract: There is provided a process for the liquid phase synthesis of ethylbenzene with a zeolite designated MCM-49. The process involves the alkylation of benzene with ethylene under liquid phase conditions.

Abstract translation: 提供了一种用称为MCM-49的沸石液相合成乙苯的方法。 该方法涉及在液相条件下苯与乙烯的烷基化。

公开(公告)号：US5453554A

公开(公告)日：1995-09-26

申请号：US249609

申请日：1994-05-26

Applicant: Jane C. Cheng ,  Anthony S. Fung ,  Donald J. Klocke ,  Stephen L. Lawton ,  Daria N. Lissy ,  Wieslaw J. Roth ,  C. Morris Smith ,  Dennis E. Walsh

Inventor： Jane C. Cheng ,  Anthony S. Fung ,  Donald J. Klocke ,  Stephen L. Lawton ,  Daria N. Lissy ,  Wieslaw J. Roth ,  C. Morris Smith ,  Dennis E. Walsh

IPC: B01J20/18 ,  B01J29/03 ,  B01J29/06 ,  B01J29/40 ,  B01J29/70 ,  C01B33/38 ,  C01B35/00 ,  C01B39/00 ,  C01B39/02 ,  C01B39/48 ,  C07C2/66 ,  C07C15/02 ,  C10G35/06 ,  C10G35/095

CPC classification number: B01J29/70 ,  B01J37/0009 ,  C01B33/38 ,  B01J2229/42

Abstract: Relatively short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively short chain alkylating agent under sufficient reaction conditions in the presence of a catalyst comprising zeolite MCM-56. The liquid phase syntheses of ethylbenzene and cumene are particular examples of such MCM-56 catalyzed reactions.

Abstract translation: 通过在含有沸石MCM-56的催化剂的存在下，在足够的反应条件下，用相对短链的烷基化剂烷基化可烷基化芳族化合物来制备相对短链烷基芳族化合物。 乙苯和枯烯的液相合成是这种MCM-56催化反应的具体实例。