公开(公告)号：US08324322B2

公开(公告)日：2012-12-04

申请号：US10572944

申请日：2004-09-22

申请人： Christophe Fringant ,  Vincent Bodart ,  Berengere Rixens ,  Romain Severac ,  Yves Hervaud ,  Patrick Lacroix-Desmazes ,  Bernard Boutevin

发明人： Christophe Fringant ,  Vincent Bodart ,  Berengere Rixens ,  Romain Severac ,  Yves Hervaud ,  Patrick Lacroix-Desmazes ,  Bernard Boutevin

IPC分类号： C08L27/08 ,  C08L33/08 ,  C08L27/12 ,  B05D7/02 ,  B05D7/16 ,  B05D7/10 ,  C08F230/02 ,  C08F214/08

CPC分类号： C09D127/08 ,  C08L27/08 ,  C08L43/02 ,  C08L51/003 ,  C08L2666/04 ,  C08L2666/24

摘要： Polymer composition comprising: 1) a polymer (P1) comprising at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1), and 2) at least one co-oligomer (O1) comprising at least: a) a component (A) comprising at least one monomeric unit identical to that derived from the monomer (M1) on which the polymer (P1) is based, and b) a component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one group chosen from the following groups: —CaH2a+1 with a between 6 and 30; —(CH2)b—CcF2c+1 with b between 1 and 11 and c greater than or equal to 5; —(CH2)d—(Si(CH3)2—O)e—Si(CH3)3 with d between 1 and 11 and e between 1 and 1000; —COOH; —SO3H, and the phosphonate groups —PO(OH)(OR1) with R1 being a hydrogen atom or an alkyl radical containing from 1 to 11 carbon atoms.

摘要翻译： 聚合物组合物，包括：1）包含至少50重量％衍生自烯键式不饱和单体（M1）的单体单元的聚合物（P1），和2）至少包含至少一个共低聚物（O1）：a） 组分（A），其包含至少一种与聚合物（P1）所基于的单体（M1）相同的单体单元，和b）包含至少一种单体单元（m2）的组分（A），衍生自 带有至少一个选自以下基团的烯属不饱和单体：-CaH2a + 1，其中6至30; - （CH2）b-CcF2c + 1，其中b在1和11之间，c大于或等于5; - （CH 2）d - （Si（CH 3）2 -O）e-Si（CH 3）3，d为1至11，e为1至1000; -COOH; -SO 3 H和膦酸酯基-PO（OH）（OR 1），其中R 1为氢原子或含有1至11个碳原子的烷基。

公开(公告)号：US20070218207A1

公开(公告)日：2007-09-20

申请号：US10572944

申请日：2004-09-22

申请人： Christophe Fringant ,  Vincent Bodart ,  Berengere Rixens ,  Romain Severac ,  Yves Hervaud ,  Patrick Lacroix-Desmazes ,  Bernard Boutevin

发明人： Christophe Fringant ,  Vincent Bodart ,  Berengere Rixens ,  Romain Severac ,  Yves Hervaud ,  Patrick Lacroix-Desmazes ,  Bernard Boutevin

IPC分类号： C08L27/08 ,  C09D127/08

CPC分类号： C09D127/08 ,  C08L27/08 ,  C08L43/02 ,  C08L51/003 ,  C08L2666/04 ,  C08L2666/24

摘要： Polymer composition comprising: 1) a polymer (P1) comprising at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1), and 2) at least one co-oligomer (01) comprising at least: a) a component (A) comprising at least one monomeric unit identical to that derived from the monomer (Ml) on which the polymer (P1) is based, and b) a component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one group chosen from the following groups: —CaH2a+1 with a between 6 and 30; —(CH2)b—CeF26+1 with b between 1 and 11 and c greater than or equal to 5; —(CH2)d—(Si(CH3)2—O)e—Si(CH3)3 with d between 1 and 11 and e between 1 and 1000; —COOH; —SO3H, and the phosphonate groups —PO(OH)(OR1) with RI being a hydrogen atom or an alkyl radical containing from 1 to 11 carbon atoms.

摘要翻译： 聚合物组合物包括：1）包含至少50重量％的衍生自烯属不饱和单体（M1）的单体单元的聚合物（P1），和2）至少包含至少一个共低聚物（01）：a） 组分（A）包含至少一种与聚合物（P1）所基于的单体（M1）相同的单体单元，和b）包含至少一种单体单元（m2）的组分（B），衍生自 带有至少一个选自以下基团的烯键式不饱和单体：具有介于6和30之间的-C≡AH 2a + - （CH 2 - ） - - - - - - - - - - - - - （2）其中b在1和11之间，c更大 超过或等于5; - （CH 2）2 - （Si（CH 3）2-O） - （CH 2）2 - 其中d在1和11之间，e在1和1000之间; -COOH; -SO 3 H，以及R 1为氢原子或含有1至11个碳原子的烷基的膦酸酯基-PO（OH）（OR 1）。

公开(公告)号：US07208558B2

公开(公告)日：2007-04-24

申请号：US11431836

申请日：2006-05-11

申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

IPC分类号： C08F14/08 ,  C08F293/00

CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyl diphenylalkanes Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn of less than 1.60.

公开(公告)号：US20070066781A1

公开(公告)日：2007-03-22

申请号：US10553993

申请日：2004-04-22

申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

IPC分类号： C07C69/52 ,  C08F20/00

CPC分类号： C07C41/06 ,  C07C68/06 ,  C08F2/38 ,  C08F4/00 ,  C08F218/08 ,  C08F220/18 ,  C07C69/96 ,  C07C43/174

摘要： Process for preparing one or more iodinated organic substances having a molecular mass of less than 2000 (substances (S)) using (A) at least one free-radical-generating substance chosen from peroxides, diazo compounds, dialkyldiphenylalkanes, substances derived from tetraphenylethane, boranes and iniferter substances comprising at least one thiuram disulphide group, (B) an ethylenically unsaturated substance capable of adding a free radical to its ethylenic double bond, (C) molecular iodine, which comprises the steps according to which at least a fraction of (A), at least a fraction of (B) and at least a fraction of (C) are introduced into a reactor, and then the contents of the reactor are caused to react, while introducing therein the possible remainder of (A), the possible remainder of (B) and the possible remainder of (C), until a moment is reached when the content of the reactor is a mixture comprising one or more substances (S). Iodinated organic substances for whose preparation the abovementioned process is particularly well suited.

摘要翻译： 使用（A）至少一种选自过氧化物，重氮化合物，二烷基二苯基烷烃的衍生自四苯基乙烷的物质的至少一种自由基产生物质制备一种或多种分子量小于2000的碘化有机物质（物质（S））的方法， 包含至少一种秋兰姆二硫基的硼烷和引发剂物质，（B）能够向其烯属双键加入自由基的烯属不饱和物质，（C）分子碘，其包括以下步骤：至少一部分（ A）中，将至少一部分（B）和至少一部分（C）引入反应器中，然后使反应器的内容物反应，同时在其中引入可能的剩余部分（A）， 当反应器的含量是包含一种或多种物质（S）的混合物时，直到达到一定时间为止（B）的剩余部分和（C）的可能剩余部分）。 上述方法制备的碘化有机物质特别适合。

公开(公告)号：US08263811B2

公开(公告)日：2012-09-11

申请号：US12774844

申请日：2010-05-06

申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

IPC分类号： C07C41/06 ,  C07C43/12 ,  C07C69/96 ,  C07C305/00 ,  C07C309/65

CPC分类号： C07C41/06 ,  C07C68/06 ,  C08F2/38 ,  C08F4/00 ,  C08F218/08 ,  C08F220/18 ,  C07C69/96 ,  C07C43/174

摘要： Process for preparing one or more iodinated organic substances having a molecular mass of less than 2000 (substances (S)) using (A) at least one free-radical-generating substance chosen from peroxides, diazo compounds, dialkyldiphenylalkanes, substances derived from tetraphenylethane, boranes and iniferter substances comprising at least one thiuram disulphide group, (B) an ethylenically unsaturated substance capable of adding a free radical to its ethylenic double bond, (C) molecular iodine, which comprises the steps according to which at least a fraction of (A), at least a fraction of (B) and at least a fraction of (C) are introduced into a reactor, and then the contents of the reactor are caused to react, while introducing therein the possible remainder of (A), the possible remainder of (B) and the possible remainder of (C), until a moment is reached when the content of the reactor is a mixture comprising one or more substances (S). Iodinated organic substances for whose preparation the abovementioned process is particularly well suited.

摘要翻译： 使用（A）至少一种选自过氧化物，重氮化合物，二烷基二苯基烷烃的衍生自四苯基乙烷的物质的至少一种自由基产生物质制备一种或多种分子量小于2000的碘化有机物质（物质（S））的方法， 包含至少一种秋兰姆二硫基的硼烷和引发剂物质，（B）能够向其烯属双键加入自由基的烯属不饱和物质，（C）分子碘，其包括以下步骤：至少一部分（ A）中，将至少一部分（B）和至少一部分（C）引入反应器中，然后使反应器的内容物反应，同时在其中引入可能的剩余部分（A）， 当反应器的含量是包含一种或多种物质（S）的混合物时，直到达到一定时间为止（B）的剩余部分和（C）的可能剩余部分）。 上述方法制备的碘化有机物质特别适合。

公开(公告)号：US07741524B2

公开(公告)日：2010-06-22

申请号：US10553993

申请日：2004-04-22

申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

IPC分类号： C07C41/06 ,  C07C43/12 ,  C07C69/96 ,  C07C305/00 ,  C07C309/65

CPC分类号： C07C41/06 ,  C07C68/06 ,  C08F2/38 ,  C08F4/00 ,  C08F218/08 ,  C08F220/18 ,  C07C69/96 ,  C07C43/174

摘要： Process for preparing one or more iodinated organic substances having a molecular mass of less than 2000 (substances (S)) using (A) at least one free-radical-generating substance chosen from peroxides, diazo compounds, dialkyldiphenylalkanes, substances derived from tetraphenylethane, boranes and iniferter substances comprising at least one thiuram disulphide group, (B) an ethylenically unsaturated substance capable of adding a free radical to its ethylenic double bond, (C) molecular iodine, which comprises the steps according to which at least a fraction of (A), at least a fraction of (B) and at least a fraction of (C) are introduced into a reactor, and then the contents of the reactor are caused to react, while introducing therein the possible remainder of (A), the possible remainder of (B) and the possible remainder of (C), until a moment is reached when the content of the reactor is a mixture comprising one or more substances (S). Iodinated organic substances for whose preparation the abovementioned process is particularly well suited.

摘要翻译： 使用（A）至少一种选自过氧化物，重氮化合物，二烷基二苯基烷烃的衍生自四苯基乙烷的物质的至少一种自由基产生物质制备一种或多种分子量小于2000的碘化有机物质（物质（S））的方法， 包含至少一种秋兰姆二硫基的硼烷和引发剂物质，（B）能够向其烯属双键加入自由基的烯属不饱和物质，（C）分子碘，其包括以下步骤：至少一部分（ A）中，将至少一部分（B）和至少一部分（C）引入反应器中，然后使反应器的内容物反应，同时在其中引入可能的剩余部分（A）， 当反应器的含量是包含一种或多种物质（S）的混合物时，直到达到一定时间为止（B）的剩余部分和（C）的可能剩余部分）。 上述方法制备的碘化有机物质特别适合。

公开(公告)号：US07285597B2

公开(公告)日：2007-10-23

申请号：US11687461

申请日：2007-03-16

申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

IPC分类号： C08F293/00 ,  C08F4/04 ,  C08F4/28

CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyl diphenylalkanes Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn of less than 1.60.

摘要翻译： 用于制备卤化聚合物的自由基聚合方法，其使用一种或多种烯键式不饱和单体，其中至少一种选自卤代单体，分子碘和一种或多种选自重氮化合物，过氧化物和二烷基二烷基烷烃的自由基产生剂。自由基聚合方法 用于制备，从由上述方法制备的卤化聚合物开始的嵌段共聚物，其至少一个嵌段是卤代聚合物嵌段。 具有大于1.0×10 4的数均分子量Mn和小于1.65的Mz / Mw比的卤化聚合物。 嵌段共聚物，其至少一个嵌段是与上述卤化聚合物相同的卤代聚合物嵌段。 包含数均分子量Mn大于1.5×10 4的至少一种卤代聚合物嵌段和小于1.60的多分散指数Mw / Mn的嵌段共聚物。

公开(公告)号：US20060205906A1

公开(公告)日：2006-09-14

申请号：US11431836

申请日：2006-05-11

申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

IPC分类号： C08F214/08

CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyl diphenylalkanes Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn of less than 1.60.

摘要翻译： 用于制备卤化聚合物的自由基聚合方法，其使用一种或多种烯键式不饱和单体，其中至少一种选自卤代单体，分子碘和一种或多种选自重氮化合物，过氧化物和二烷基二烷基烷烃的自由基产生剂。自由基聚合方法 用于制备，从由上述方法制备的卤化聚合物开始的嵌段共聚物，其至少一个嵌段是卤代聚合物嵌段。 具有大于1.0×104的数均分子量M N n N以及小于1.65的M z z / M x W比的卤化聚合物 。 嵌段共聚物，其至少一个嵌段是与上述卤化聚合物相同的卤代聚合物嵌段。 包含数均分子量大于1.5×10 4的至少一种卤代聚合物嵌段的嵌段共聚物和多分散性指数M SUB> / M 小于1.60。

公开(公告)号：US07078473B2

公开(公告)日：2006-07-18

申请号：US10512870

申请日：2003-05-16

申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

IPC分类号： C08F14/02 ,  C08F293/00

CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

摘要： Radical polymerization process for the preparation of halogenated polymers and block copolymers. Halogenated polymers and block copolymers.

摘要翻译： 用于制备卤化聚合物和嵌段共聚物的自由基聚合方法。 卤化聚合物和嵌段共聚物。

公开(公告)号：US20050171312A1

公开(公告)日：2005-08-04

申请号：US10512870

申请日：2003-05-16

申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

IPC分类号： C08F2/00 ,  C08F2/38 ,  C08F4/40 ,  C08F8/22 ,  C08F14/00 ,  C08F14/08 ,  C08F14/16 ,  C08F14/22 ,  C08F293/00

CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyldiphenylalkanes. Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw, ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn, of less than 1.60.

摘要翻译： 使用一种或多种烯属不饱和单体制备卤化聚合物的自由基聚合方法，其中至少一种选自卤化单体，分子碘和一种或多种选自重氮化合物，过氧化物和二烷基二苯基烷烃的自由基产生剂。 用于制备的自由基聚合方法，从由上述方法制备的卤化聚合物开始的嵌段共聚物，其至少一个嵌段是卤化聚合物嵌段。 具有大于1.0×10 4的数均分子量M n N以及M z z / M z的卤化聚合物， / SUB>，比值小于1.65。 嵌段共聚物，其至少一个嵌段是与上述卤化聚合物相同的卤代聚合物嵌段。 包含数均分子量大于1.5×10 4的至少一种卤代聚合物嵌段的嵌段共聚物和多分散性指数M 小于或等于1.60。