摘要:
A fuel cell power plant (36) has vertical fuel cells (102) each sharing a half of a hybrid separator plate (100) which includes a solid fuel flow plate (105) having horizontal fuel flow channels (106) on one surface and coolant channels (108) on an upper portion of the opposite surface, bonded to a plain rear side of a porous, hydrophilic oxidant flow field plate (115) having vertical oxidant flow channels (118). Coolant permeates through the upper portion of the porous, hydrophilic oxidant flow field plates and enters the oxidant flow channels, where it evaporates as the water trickles downward through the oxidant flow field channels, thereby cooling the fuel cell.
摘要:
A fuel cell power plant (36) has vertical fuel cells (102) each sharing a half of a hybrid separator plate (100) which includes a solid fuel flow plate (105) having horizontal fuel flow channels (106) on one surface and coolant channels (108) on an upper portion of the opposite surface, bonded to a plain rear side of a porous, hydrophilic oxidant flow field plate (115) having vertical oxidant flow channels (118). Coolant permeates through the upper portion of the porous, hydrophilic oxidant flow field plates and enters the oxidant flow channels, where it evaporates as the water trickles downward through the oxidant flow field channels, thereby cooling the fuel cell.
摘要:
Fuel cell systems (100, 400) and related methods involving accumulators (106, 200, 300, 406) with multiple regions (R1, R2; R1′, R2′) of differing water fill rates are provided. At least one accumulator region with a relatively more-rapid fill rate (R2; R2′) than another accumulator region (R1; R1′) is drained of water at shutdown under freezing conditions to allow at least that region to be free of water and ice. That region is then available to receive water from and supply water to, a fuel cell (102; 402) nominally upon start-up. The region having the relatively more-rapid fill rate (R2; R2′) may typically be of relatively lesser volume, and may be positioned either relatively below or relatively above the other region(s).
摘要:
A method of operating a fuel cell power plant (10) including a stack (11) of fuel cells having an anode catalyst layer and a cathode electrode (15) including a catalyst layer disposed on catalyst support material is characterized by, during normal operation of said power plant, adjusting the voltage of the stack to be substantially equal to or less than a predetermined maximum voltage for the temperature of the stack. Further, said step of adjusting comprises adjusting the stack voltage to the lesser of: a) a predetermined voltage above which corrosion of catalyst support material is significant and below which corrosion of catalyst support material is insignificant at the temperature of the stack; and b) a predetermined voltage above which dissolution of catalyst is significant and below which dissolution of the catalyst is insignificant at the temperature of the stack.
摘要:
A method of operating a fuel cell power plant (10) including a stack (11) of fuel cells having an anode catalyst layer and a cathode electrode (15) including a catalyst layer disposed on catalyst support material is characterized by, during normal operation of said power plant, adjusting the voltage of the stack to be substantially equal to or less than a predetermined maximum voltage for the temperature of the stack. Further, said step of adjusting comprises adjusting the stack voltage to the lesser of: a) a predetermined voltage above which corrosion of catalyst support material is significant and below which corrosion of catalyst support material is insignificant at the temperature of the stack; and b) a predetermined voltage above which dissolution of catalyst is significant and below which dissolution of the catalyst is insignificant at the temperature of the stack.
摘要:
A fuel cell for a fuel cell power plant having gas diffusion layers which do not have microporous layers, includes a PEM (9), a cathode comprising at least a cathode catalyst (10) and a gas diffusion layer (17) on one side of the PEM, and an anode comprising at least an anode catalyst (11) and a gas diffusion layer (14) on the opposite side of the PEM, and a porous water transport plate having reactant gas flow field channels (31, 32) (21, 28) adjacent to each of said support substrates as well as water flow channels (22) in at least one of said water transport plates. The thermal conductivity of the cathode and/or the anode gas dif- fusion layers is less than about one-quarter of the thermal conductivity of conventional gas diffusion layers, less than about 0.25 W/m/K, to promote flow of water from the cathodes to the anodes and to the adjacent water transport plates, during start-up at normal ambient temperatures (lower than normal PEM fuel cell operating temperatures).
摘要翻译:一种具有不具有微孔层的气体扩散层的燃料电池发电厂的燃料电池,包括PEM(9),至少包含阴极催化剂(10)的阴极和在一侧的气体扩散层(17) 所述PEM和在所述PEM相反侧的至少包含阳极催化剂(11)和气体扩散层(14)的阳极和具有反应气体流场通道(31,32)(21,32)的多孔水输送板 ,28),以及至少一个所述水输送板中的水流通道(22)。 阴极和/或阳极气体扩散层的热导率小于常规气体扩散层的热传导率的约四分之一,小于约0.25W / m / K,以促进水从 在正常环境温度(低于正常的PEM燃料电池工作温度)的启动期间,阳极和相邻的水输送板的阴极。
摘要:
The fuel flow channels (20a) of the end fuel cell (9a) at the anode end (34) of a fuel cell stack are significantly deeper than the fuel flow field channels (20) of the remaining fuel cells (9) in the stack, whereby fuel starvation caused by ice in the fuel flow channels is avoided during cold startup. The fuel flow field channels of the end cell (9) at the anode end of the stack is between about 0.15 mm and about 1.5 mm deeper than the fuel flow field channels in the remaining fuel cells of the stack, or between about 35% and about 65% deeper than the fuel flow field channels in the remaining fuel cells of the stack.
摘要:
The fuel flow channels (20a) of the end fuel cell (9a) at the anode end (34) of a fuel cell stack are significantly deeper than the fuel flow field channels (20) of the remaining fuel cells (9) in the stack, whereby fuel starvation caused by ice in the fuel flow channels is avoided during cold startup. The fuel flow field channels of the end cell (9) at the anode end of the stack is between about 0.15 mm and about 1.5 mm deeper than the fuel flow field channels in the remaining fuel cells of the stack, or between about 35% and about 65% deeper than the fuel flow field channels in the remaining fuel cells of the stack.
摘要:
A fuel cell stack (31) includes a plurality of fuel cells (9) each having an electrolyte such as a PEM (10), anode and cathode catalyst layers (13, 14), anode and cathode gas diffusion layers (16, 17), and water transport plates (21, 28) adjacent the gas diffusion layers. The cathode diffusion layer of cells near the cathode end (36) of the stack have a high water permeability, such as greater than 3×10−4 g/(Pa s m) at about 80° C. and about 1 atmosphere, whereas the cathode gas diffusion layer in cells near the anode end (35) have water vapor permeance greater than 3×10−4 g/(Pa s m) at about 80° C. and about 1 atmosphere. In one embodiment, the anode gas diffusion layer of cells near the anode end (35) of the stack have a higher liquid water permeability than the anode gas diffusion layer in cells near the cathode end; a second embodiment reverses that relationship.
摘要:
Coolant velocity greater than zero everywhere within the coolant channels (78, 85) of fuel cells (38) in a fuel cell stack (37) is assured by providing a flow of gas in the coolant channels, the flow being created by gas pressure from a source (92) of pressurized gas, an oxidant reactant air pump (52), a source (75) of hydrogen-containing fuel, or the fuel outlet (47), or the outflow of a condenser (59). Positive pressure may be applied to the coolant inlet (66) or negative pressure from an eductor (97) may be applied to a gas outlet (90) of the coolant channels, or both. Using gas to induce flow within the coolant channels eliminates the need for a bubble-clearing liquid pump and reduces liquid inventory and other plumbing; this makes the fuel cell power plant more freeze tolerant. Biphase flow from the condenser, which may be a vehicle radiator (120), renders the coolant return flow more freeze tolerant. Separate cooler plates (122) may be used with a coolant management system (125).