公开(公告)号：US4105578A

公开(公告)日：1978-08-08

申请号：US771099

申请日：1977-02-23

申请人： Claude M. Finlayson ,  John W. Jordan

发明人： Claude M. Finlayson ,  John W. Jordan

IPC分类号： C09K3/00 ,  B01J13/00 ,  B22C1/16 ,  C01B33/20 ,  C01B33/40 ,  C01B33/44 ,  C09D7/00 ,  C09D7/12 ,  C09K8/32 ,  C10M113/16 ,  C10M121/04 ,  C10N50/10

CPC分类号： C10M113/16 ,  C01B33/44 ,  C09K8/32 ,  Y10S507/901

摘要： An organophilic clay gellant having enhanced dispersibility in organic systems is prepared from the reaction product of a smectite-type clay having a cation exchange capacity of at least 0.75 milliequivalents per gram and from 1.00 to less than 1.20 milliequivalents per gram of clay of a methyl benzyl dialkyl ammonium compound, wherein the compound contains 20 to 35% alkyl groups having 16 carbon atoms and 60 to 75% alkyl groups having 18 carbon atoms.

公开(公告)号：US4287086A

公开(公告)日：1981-09-01

申请号：US749323

申请日：1976-12-10

申请人： Claude M. Finlayson ,  John W. Jordan

发明人： Claude M. Finlayson ,  John W. Jordan

IPC分类号： C01B33/44 ,  C09K8/32 ,  C10M113/16 ,  B01J13/00 ,  C10M1/10 ,  C10M5/04

CPC分类号： C09K8/32 ,  C01B33/44 ,  C10M113/16 ,  Y10S507/901 ,  Y10S507/926

摘要： The viscosity of liquid organic systems is increased by adding thereto an organophilic clay gellant which is the reaction product of a smectite clay having a cation exchange capacity of at least 0.75 milliequivalents per gram and from 1.00 to less than 1.20 milliequivalents per gram of clay of a methyl benzyl dialkyl ammonium salt, wherein the two alkyl groups independently contain from 16 to 18 carbon atoms, and from 0% to 1% water in the absence of a polar organic dispersant for the gellant.

摘要翻译： 液体有机体系的粘度通过加入有机粘土胶凝胶而增加，该有机粘土胶凝胶是阳离子交换容量至少为0.75毫当量/克的蒙脱石粘土和1.00至小于1.20毫当量的每克粘土的反应产物 甲基苄基二烷基铵盐，其中两个烷基独立地含有16至18个碳原子，和0％至1％的水，不存在用于胶凝剂的极性有机分散剂。

公开(公告)号：US4434075A

公开(公告)日：1984-02-28

申请号：US313033

申请日：1981-10-19

申请人： Wilbur S. Mardis ,  Claude M. Finlayson

发明人： Wilbur S. Mardis ,  Claude M. Finlayson

IPC分类号： C09K3/00 ,  B01J13/00 ,  B41M5/155 ,  C01B33/20 ,  C01B33/40 ,  C01B33/44 ,  C01B39/06 ,  C07F9/54 ,  C09D7/00 ,  C10M113/16

CPC分类号： C09D7/1225 ,  B41M5/1555 ,  C07F9/54 ,  C09D7/002 ,  C10M113/16 ,  C08K3/346 ,  C08K5/19 ,  C10M2201/14 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2203/104 ,  C10M2203/106 ,  C10M2203/108 ,  C10M2215/02 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/26 ,  C10M2219/044 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/06 ,  C10M2223/061 ,  C10M2223/063 ,  C10M2223/065 ,  Y10S507/901 ,  Y10S507/926

摘要： An organophilic clay gellant is disclosed which comprises the reaction product of an organic cation compound, an organic anion, and a smectite-type clay having a cation exchange capacity of at least 75 milliequivalents per 100 grams of said clay. The organic cation compound has the formula: ##STR1## wherein R.sub.1 is selected from the group consisting of a .beta., .gamma.-unsaturated alkyl group and a hydroxyalkyl group having 2 to 6 carbon atoms and mixtures thereof; R.sub.2 is a long chain alkyl group having 12 to 60 carbon atoms; R.sub.3 and R.sub.4 are individually selected from the group consisting of a .beta., .gamma.-unsaturated alkyl group, a hydroxyalkyl group having 2 to 6 carbon atoms, an aralkyl group, an alkyl group having from 1 to 22 carbon atoms and mixtures thereof; X is selected from a group consisting of phosphorous and nitrogen. The reaction is carried out in a manner such that an organic cation-organic anion complex is intercalated with the smectite-type clay and the cation exchange sites of the smectite-type clay are substituted with the organic cation.

摘要翻译： 公开了一种亲有机粘土胶凝胶，其包含有机阳离子化合物，有机阴离子和具有至少75毫当量/ 100克所述粘土的阳离子交换容量的蒙脱石型粘土的反应产物。 有机阳离子化合物具有下式：其中R 1选自β，γ-不饱和烷基和具有2-6个碳原子的羟烷基及其混合物; R2是碳原子数12〜60的长链烷基; R 3和R 4分别选自β，γ-不饱和烷基，具有2-6个碳原子的羟烷基，芳烷基，具有1至22个碳原子的烷基及其混合物; X选自磷和氮组成的组。 该反应以有机阳离子 - 有机阴离子络合物嵌入蒙脱石型粘土并且蒙脱石型粘土的阳离子交换位置被有机阳离子取代的方式进行。

公开(公告)号：US4450095A

公开(公告)日：1984-05-22

申请号：US207544

申请日：1980-11-17

申请人： Claude M. Finlayson

发明人： Claude M. Finlayson

IPC分类号： C01B33/44 ,  C09D7/00 ,  C09K8/14 ,  C10M113/16 ,  B01J13/00

CPC分类号： C09D7/1225 ,  C01B33/44 ,  C09D7/002 ,  C09K8/145 ,  C10M113/16 ,  C08K3/346 ,  C08K5/16 ,  C10M2201/1036 ,  C10M2201/14 ,  C10M2201/145 ,  C10M2215/04 ,  C10M2215/26 ,  Y10S507/901 ,  Y10S507/926

摘要： The viscosity of liquid organic systems is increased by adding thereto an organophilic clay gellant which is the reaction product of a smectite-type clay having a cation exchange capacity of at least 75 milliequivalents per 100 grams of said clay and from 100 to 120 milliequivalents per 100 grams of clay of methyl or benzyl trialkyl ammonium salt, wherein the alkyl groups independently contain from 14 to 20 carbon atoms.

摘要翻译： 通过加入有机粘土胶凝胶来增加液体有机体系的粘度，该有机粘土胶凝胶是阳离子交换容量为每100克所述粘土至少75毫当量的蒙脱石型粘土和100至120毫当量/ 100的反应产物 克的甲基或苄基三烷基铵盐的粘土，其中烷基独立地含有14至20个碳原子。

公开(公告)号：US4742098A

公开(公告)日：1988-05-03

申请号：US60082

申请日：1987-06-09

申请人： Claude M. Finlayson ,  Charles A. Cody ,  Steven J. Kemnetz ,  William W. Reichert ,  Edward D. Magauran ,  Johnny R. Johnson

发明人： Claude M. Finlayson ,  Charles A. Cody ,  Steven J. Kemnetz ,  William W. Reichert ,  Edward D. Magauran ,  Johnny R. Johnson

IPC分类号： B01F17/54 ,  C01B33/44 ,  C08K3/34 ,  C08K9/04 ,  C09D7/00 ,  C09D11/02 ,  C09K3/00 ,  C09K8/14 ,  C10M113/16 ,  C08L67/00

CPC分类号： C09D7/1225 ,  C01B33/44 ,  C08K3/346 ,  C08K9/04 ,  C09D11/03 ,  C09D7/002 ,  C09K3/00 ,  C09K8/145 ,  C10M113/16 ,  C10M2201/14 ,  C10M2215/02 ,  C10M2215/04 ,  C10M2215/26

摘要： Improved organophilic clay gellants can be prepared by a process wherein the smectite-type clay is subjected to shearing in order to break apart the agglomerates and/or the smectite-type clay can be reacted with organic cation and, possibly organic anion, under dilute reaction conditions. The reaction product is recovered using gentle drying conditions. Depending in large part on its composition, the organophilic clay gellant may be used to thicken a variety of organic compositions. In a preferred aspect, the organophilic clay gellant can be directly added to polyester compositions in order to efficiently and effectively increase the viscosity thereof or can be first formed into a pregel under low shear conditions to yield even higher efficiencies.

摘要翻译： 改进的亲有机粘土胶凝剂可以通过一种方法制备，其中蒙脱石型粘土经受剪切以分离附聚物和/或蒙皂石型粘土可以在有机阳离子和可能的有机阴离子的条件下与稀释反应 条件。 使用温和的干燥条件回收反应产物。 在很大程度上取决于其组成，亲有机粘土胶凝剂可用于增稠各种有机组合物。 在优选的方面，亲有机粘土胶凝剂可以直接加入到聚酯组合物中，以便有效和有效地增加其粘度，或者可以在低剪切条件下首先形成预凝胶以产生更高的效率。

公开(公告)号：US4391637A

公开(公告)日：1983-07-05

申请号：US313031

申请日：1981-10-19

申请人： Wilbur S. Mardis ,  Claude M. Finlayson

发明人： Wilbur S. Mardis ,  Claude M. Finlayson

IPC分类号： C10M159/12 ,  B01J19/06 ,  B22C1/20 ,  C01B33/44 ,  C09D7/00 ,  C09K3/00 ,  C09K3/10 ,  C10M113/16 ,  C10N50/10 ,  C09D11/00 ,  C08L91/06 ,  C07F5/06

CPC分类号： C09D7/1225 ,  B01J19/06 ,  C01B33/44 ,  C09D7/002 ,  C10M113/16 ,  C08K3/346 ,  C10M2201/02 ,  C10M2201/14 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2203/104 ,  C10M2203/106 ,  C10M2203/108 ,  C10M2215/02 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/26 ,  C10M2219/044 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/06 ,  C10M2223/061 ,  C10M2223/063 ,  C10M2223/065 ,  C10N2250/10

摘要： A self-activating organophilic clay gellant having enhanced dispersibility in non-aqueous fluid systems comprising the reaction product of a smectite-type clay and an organic cationic compound having at least one long chain alkyl group and at least one long chain alkyl group and at least one group selected from a .beta., .gamma.-unsaturated alkyl group or a hydroxyalkyl group having 2 to 6 carbon atoms.

摘要翻译： 一种具有增强的非水性流体体系分散性的自活化亲有机粘土胶凝胶，其包含蒙脱石型粘土和具有至少一个长链烷基和至少一个长链烷基的有机阳离子化合物的反应产物，并且至少 一个选自β，γ-不饱和烷基或具有2至6个碳原子的羟烷基的基团。

公开(公告)号：US4695402A

公开(公告)日：1987-09-22

申请号：US767599

申请日：1985-08-20

申请人： Claude M. Finlayson ,  Charles A. Cody ,  Steven J. Kemnetz ,  William W. Reichert ,  Edward D. Magauran ,  Johnny R. Johnson

发明人： Claude M. Finlayson ,  Charles A. Cody ,  Steven J. Kemnetz ,  William W. Reichert ,  Edward D. Magauran ,  Johnny R. Johnson

IPC分类号： C01B33/44 ,  C08K3/34 ,  C08K9/04 ,  C09D7/00 ,  C09D11/02 ,  C09K3/00 ,  C09K8/14 ,  C10M113/16 ,  B01J13/00

CPC分类号： C09D7/1225 ,  C01B33/44 ,  C08K3/346 ,  C08K9/04 ,  C09D11/03 ,  C09D7/002 ,  C09K3/00 ,  C09K8/145 ,  C10M113/16 ,  C10M2201/14 ,  C10M2215/02 ,  C10M2215/04 ,  C10M2215/26

摘要： Improved organophilic clay gellants can be prepared by a process wherein the smectite-type clay is subjected to shearing in order to break apart the agglomerates and/or the smectite-type clay can be reacted with organic cation and, possibly organic anion, under dilute reaction conditions. The reaction product is recovered using gentle drying conditions. Depending in large part on its composition, the organophilic clay gellant may be used to thicken a variety of organic compositions. In a preferred aspect, the organophilic clay gellant can be directly added to polyester compositions in order to efficiently and effectively increase the viscosity thereof or can be first formed into a pregel under low shear conditions to yield even higher efficiencies.

公开(公告)号：US4410364A

公开(公告)日：1983-10-18

申请号：US313032

申请日：1981-10-19

申请人： Claude M. Finlayson ,  Wilbur S. Mardis

发明人： Claude M. Finlayson ,  Wilbur S. Mardis

IPC分类号： C01B33/44 ,  C09D11/02

CPC分类号： C09D11/03 ,  C01B33/44 ,  C10M2201/14 ,  C10M2215/02 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/26 ,  C10M2219/044 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/06 ,  C10M2223/061 ,  C10M2223/063 ,  C10M2223/065

摘要： Printing inks are provided comprising an organic ink vehicle having dispersed therein an ink coloring material and an organophilic clay gellant. The organophilic clay gellant comprises the reaction product of an organic cation, an organic anion and a smectite-type clay having a cation exchange capacity of at least 75 milliequivalents per 100 grams of said clay such that an organic cation - organic anion complex is intercalated with the smectite-type clay and the cation exchange sites of the smectite-type clay are substituted with the organic cation.

摘要翻译： 提供的印刷油墨包括分散有油墨着色材料和亲有机粘土胶凝胶的有机油墨载体。 亲有机粘土胶凝剂包括阳离子交换能力为每100克所述粘土至少75毫当量的有机阳离子，有机阴离子和蒙脱石型粘土的反应产物，使得有机阳离子 - 有机阴离子络合物被插入 绿土型粘土和蒙脱石型粘土的阳离子交换位置被有机阳离子取代。

公开(公告)号：US4208218A

公开(公告)日：1980-06-17

申请号：US890809

申请日：1978-03-27

申请人： Claude M. Finlayson

发明人： Claude M. Finlayson

IPC分类号： C09K3/00 ,  A61K8/25 ,  A61K8/26 ,  A61K8/41 ,  A61Q5/00 ,  A61Q15/00 ,  A61Q19/00 ,  B01J13/00 ,  C01B33/44 ,  C03C8/16 ,  C09D7/00 ,  C09D7/12

CPC分类号： A61K8/416 ,  A61K8/26 ,  A61Q19/00 ,  C01B33/44 ,  C03C8/16 ,  C09D7/002 ,  C09D7/1225 ,  A61Q15/00 ,  A61Q5/00 ,  C03C2205/00 ,  C08K3/346

摘要： An organoclay rheological additive for non-aqueous fluid systems comprising an organophilic clay gellant comprising the reaction product of a smectite-type clay having a cation exchange capacity of at least 75 milliequivalents per 100 grams of clay and a methyl benzyl dialkyl ammonium compound or a dibenzyl dialkyl ammonium compound wherein the alkyl groups contain specific amounts of 8 to 22 carbon atoms and the amount of said ammonium compound reacted with said clay being from 100 to 130 milliequivalents per 100 grams of clay based upon 100% active clay.

摘要翻译： 一种用于非水系流变体系的有机粘土流变助剂，其包含有机粘土胶凝胶，其包含阳离子交换容量至少为75毫当量/ 100克粘土和甲基苄基二烷基铵化合物或二苄基 二烷基铵化合物，其中烷基含有特定量的8至22个碳原子，并且所述铵化合物与所述粘土反应的量为100至130毫当量/ 100克粘土，基于100％活性粘土。

公开(公告)号：US4517112A

公开(公告)日：1985-05-14

申请号：US348641

申请日：1982-02-18

申请人： Wilbur S. Mardis ,  Claude M. Finlayson

发明人： Wilbur S. Mardis ,  Claude M. Finlayson

IPC分类号： C09K3/00 ,  B01F17/54 ,  B01J13/00 ,  C01B33/44 ,  C09D7/00 ,  C09D7/12 ,  C09K8/32 ,  C10M113/16

CPC分类号： C09D7/1225 ,  C01B33/44 ,  C09D7/002 ,  C09K8/32 ,  C10M113/16 ,  C08K3/346 ,  C10M2201/14 ,  C10M2215/02 ,  C10M2219/04 ,  C10M2219/042 ,  C10M2219/044 ,  C10M2223/06 ,  C10M2223/061 ,  Y10S507/901 ,  Y10S507/926

摘要： An organophilic clay gellant useful for gelling organic liquids is disclosed which comprises the reaction product of (a) a smectite-type clay having a cation exchange capacity of at least 75 milliequivalents per 100 grams of said clay; (b) a primary anion selected from the group consisting of anions derived from organic sulfonic acids, alkylsulfates and mixtures thereof containing at least one lineal or branched alkyl group having greater than 9 carbon atoms, aromatic sulfonic acids and mixtures thereof; (c) a secondary anion different from said primary anion and selected from the group consisting of anions derived from organic acids having a pKa of less than about 11.0 and mixtures thereof; and (d) an organic cation is an amount sufficient to satisfy the cation in exchange capacity of said clay and the cationic activity of the primary and secondary anions wherein the resulting organic cation-organic anion complexes are intercalated with the smectite-type clay and wherein the combination of said primary and secondary anion synergistically increases the ease of dispersion of said organophilic clay gellant in an organic liquid.

摘要翻译： 公开了可用于胶凝有机液体的有机粘土胶凝胶，其包含（a）阳离子交换容量为每100克所述粘土至少75毫当量的蒙脱石型粘土的反应产物; （b）选自由有机磺酸衍生的阴离子的主阴离子，烷基硫酸盐及其含有至少一个具有大于9个碳原子的直链或支链烷基的混合物，芳族磺酸及其混合物; （c）不同于所述初级阴离子并选自由pKa小于约11.0的有机酸衍生的阴离子的二次阴离子及其混合物; 和（d）有机阳离子的量足以满足所述粘土的交换能力的阳离子和初级和次级阴离子的阳离子活性，其中所得有机阳离子 - 有机阴离子络合物插入蒙脱石型粘土，其中 所述初级和次级阴离子的组合协同增加了所述有机粘土胶凝剂在有机液体中的分散容易性。