公开(公告)号：US20130078458A1

公开(公告)日：2013-03-28

申请号：US13702043

申请日：2011-05-26

申请人： Claudine Biver ,  Sandrine Duluard ,  Joëlle Corde ,  Jean-Pierre Boilot ,  Thierry Gacoin ,  Sandrine Perruchas

发明人： Claudine Biver ,  Sandrine Duluard ,  Joëlle Corde ,  Jean-Pierre Boilot ,  Thierry Gacoin ,  Sandrine Perruchas

IPC分类号： B05D3/06

CPC分类号： B05D3/065 ,  C23C18/1225 ,  C23C18/1254 ,  C23C18/1295 ,  C23C18/14 ,  C23C18/1603 ,  C23C18/165 ,  C23C18/1667 ,  C23C18/42 ,  Y10T428/265

摘要： The present invention relates to a method for manufacturing mesostructural coatings comprising electrically conductive structures formed of metal nanoparticles. Said method includes the steps that involve: a) depositing on a substrate, a first layer consisting of a silica material, mesostructured by a structuring agent, and a photocatalytic material: b) depositing on the first layer, a second layer of a mesostructural silica material, said second layer being free of photocatalytic material: c) consolidating the first and second layers at at temperature between 50° C. and 250° C.; and d) placing the consolidating coating in contact with a solution that contains and irradiatting coating with a radiation that enables the photocatalytic material to be activated. Said method is characterized in that it includes no heat treatment at a temperature greater than 250° C.

摘要翻译： 本发明涉及包含由金属纳米颗粒形成的导电结构的介观涂层的制造方法。 所述方法包括以下步骤：a）沉积在基材上，由由结构化剂介孔结构的二氧化硅材料和光催化材料组成的第一层，和b）在第一层上沉积第二层中等结构二氧化硅 所述第二层不含光催化材料：c）在50℃和250℃之间的温度下固化第一层和第二层; 以及d）将固结涂层与含有能够使光催化材料活化的辐射的包含和照射涂层的溶液接触。 所述方法的特征在于它不包括在大于250℃的温度下的热处理

公开(公告)号：US08542426B2

公开(公告)日：2013-09-24

申请号：US13497217

申请日：2010-09-24

申请人： Samuel Archambeau ,  Claudine Biver ,  Jean-Paul Cano ,  Sandrine Duluard

发明人： Samuel Archambeau ,  Claudine Biver ,  Jean-Paul Cano ,  Sandrine Duluard

IPC分类号： G02F1/153

CPC分类号： G02F1/1521 ,  G02F1/155 ,  G02F2001/1512 ,  G02F2001/1557

摘要： The invention relates to a transparent electrochromic system (100) which includes two pairs of transparent supply electrodes (1-4), which are intended for being electrically connected to variable power sources (20, 21). The electrodes of the two pairs are supported by separate outer walls (10, 11) of the system, on either side of a closed volume which contains electroactive substances. The electrochromic system has superior dynamics and switching rate. Various embodiments of the invention correspond to various modes for connecting the electrodes to the power sources, and to various partitions of the closed volume into separate cells (13).

摘要翻译： 本发明涉及透明电致变色系统（100），其包括两对透明供电电极（1-4），其旨在电连接到可变电源（20,21）。 两对电极由系统的分开的外壁（10,11）支撑，在包含电活性物质的封闭体积的两侧。 电致变色系统具有优异的动态和开关率。 本发明的各种实施例对应于用于将电极连接到电源的各种模式，以及将闭合容积的各个分隔件分成单独的电池（13）。

公开(公告)号：US20130142945A1

公开(公告)日：2013-06-06

申请号：US13817394

申请日：2011-08-16

申请人： Claudine Biver ,  Sandrine Duluard

发明人： Claudine Biver ,  Sandrine Duluard

IPC分类号： G02F1/15

CPC分类号： G02F1/15 ,  C09K9/00 ,  C23C18/16 ,  G02F1/1533 ,  G02F2202/36

摘要： The present invention relates to a process for manufacturing an electrochromic article, comprising the following successive steps: (a) deposition of a layer of an electrochromic compound on the surface of a transparent or translucent electroconductive substrate; (b) deposition of a redox agent, which is a reducing agent or an oxidizing agent for the electrochromic compound, on the layer of electrochromic compound at a multitude of discrete points or areas thereon; (c) bringing the layer of electrochromic compound, deposited in step (a), and the redox agent, deposited in step (b), into contact with a liquid electrolyte for a time long enough to allow the electrochromic compound to be reduced or oxidized by the redox agent; and (d) elimination of the electrolyte by rinsing and/or drying, the layer of electrochromic compound being a porous layer of open porosity and/or an electrically conductive layer.

摘要翻译： 本发明涉及电致变色制品的制造方法，包括以下连续步骤：（a）在透明或半透明导电基材的表面上沉积电致变色化合物层; （b）在其上的多个离散点或区域上在电致变色化合物层上沉积作为电致变色化合物的还原剂或氧化剂的氧化还原剂; （c）使步骤（a）中沉积的电致变色化合物层和步骤（b）中沉积的氧化还原剂与电解液接触足够长的时间以使电致变色化合物被还原或氧化 由氧化还原剂; 和（d）通过冲洗和/或干燥除去电解质，电致变色化合物层是开放孔隙度的多孔层和/或导电层。

公开(公告)号：US20120307340A1

公开(公告)日：2012-12-06

申请号：US13498107

申请日：2010-09-24

申请人： Samuel Archambeau ,  Claudine Biver ,  Christian Bovet ,  Jean-Paul Cano ,  Sandrine Duluard ,  Anthony Saugey

发明人： Samuel Archambeau ,  Claudine Biver ,  Christian Bovet ,  Jean-Paul Cano ,  Sandrine Duluard ,  Anthony Saugey

IPC分类号： G02F1/155

CPC分类号： G02F1/1521 ,  G02F1/155 ,  G02F2001/1512 ,  G02F2001/1557

摘要： The invention relates to transparent electrochromic systems which each include one pair of supply electrodes and at least one pair of polarisation electrodes. The polarisation electrodes prevent a reaction of mutual neutralisation of the electroactive substances of the systems from causing unnecessary consumption of electric current. Said electrodes also prevent a neutralisation reaction from limiting a lower value of light transmission of the systems. For this purpose, the polarisation electrodes produce an electric field inside the systems, which attracts the electroactive substances that have already reacted with the supply electrodes to different areas.

摘要翻译： 本发明涉及透明电致变色系统，每个系统包括一对供电电极和至少一对偏振电极。 极化电极防止系统的电活性物质的相互中和的反应引起不必要的电流消耗。 所述电极还防止中和反应限制系统的较低的光透射值。 为此，极化电极在系统内产生电场，吸引已经与供电电极反应的电活性物质到不同的区域。

公开(公告)号：US08736946B2

公开(公告)日：2014-05-27

申请号：US13498107

申请日：2010-09-24

申请人： Samuel Archambeau ,  Claudine Biver ,  Christian Bovet ,  Jean-Paul Cano ,  Sandrine Duluard ,  Anthony Saugey

发明人： Samuel Archambeau ,  Claudine Biver ,  Christian Bovet ,  Jean-Paul Cano ,  Sandrine Duluard ,  Anthony Saugey

IPC分类号： G02F1/15

CPC分类号： G02F1/1521 ,  G02F1/155 ,  G02F2001/1512 ,  G02F2001/1557

摘要： The invention relates to transparent electrochromic systems which each include one pair of supply electrodes and at least one pair of polarization electrodes. The polarization electrodes prevent a reaction of mutual neutralization of the electroactive substances of the systems from causing unnecessary consumption of electric current. Said electrodes also prevent a neutralization reaction from limiting a lower value of light transmission of the systems. For this purpose, the polarization electrodes produce an electric field inside the systems, which attracts the electroactive substances that have already reacted with the supply electrodes to different areas.

摘要翻译： 本发明涉及透明电致变色系统，每个系统包括一对供电电极和至少一对偏振电极。 极化电极防止系统的电活性物质的相互中和的反应引起不必要的电流消耗。 所述电极还防止中和反应限制系统的较低的光透射值。 为此，极化电极在系统内产生电场，吸引已经与供电电极反应的电活性物质到不同的区域。

公开(公告)号：US08736944B2

公开(公告)日：2014-05-27

申请号：US13386878

申请日：2010-07-19

申请人： Claudine Biver ,  Jean-Paul Cano ,  Sandrine Duluard ,  Anthony Saugey

发明人： Claudine Biver ,  Jean-Paul Cano ,  Sandrine Duluard ,  Anthony Saugey

IPC分类号： G02F1/153 ,  G02F1/15 ,  G09G3/38 ,  H04N9/16

CPC分类号： G02F1/155 ,  G02F1/133377 ,  G02F2001/1512 ,  G02F2001/1557

摘要： A transparent electrochromic system includes a cellular structure, two power supply electrodes together supported on a single wall, and at least one additional electrode. The additional electrode can be used as a reference electrode or as a polarization electrode. The additional electrode can also form a condenser with a fourth electrode that is added to the system, in order to control a migration of certain electroactive substances responsible for coloring and decoloring the system. The operation of the system can thus be improved.

摘要翻译： 透明电致变色系统包括蜂窝结构，一起支撑在单个壁上的两个电源电极和至少一个附加电极。 附加电极可以用作参考电极或用作极化电极。 附加电极还可以形成具有添加到系统中的第四电极的冷凝器，以便控制负责系统着色和脱色的某些电活性物质的迁移。 因此可以提高系统的操作。

公开(公告)号：US20120176661A1

公开(公告)日：2012-07-12

申请号：US13497217

申请日：2010-09-24

申请人： Samuel Archambeau ,  Claudine Biver ,  Jean-Paul Cano ,  Sandrine Duluard

发明人： Samuel Archambeau ,  Claudine Biver ,  Jean-Paul Cano ,  Sandrine Duluard

IPC分类号： G02F1/153

CPC分类号： G02F1/1521 ,  G02F1/155 ,  G02F2001/1512 ,  G02F2001/1557

摘要： The invention relates to a transparent electrochromic system (100) which includes two pairs of transparent supply electrodes (1-4), which are intended for being electrically connected to variable power sources (20, 21). The electrodes of the two pairs are supported by separate outer walls (10, 11) of the system, on either side of a closed volume which contains electroactive substances. The electrochromic system has superior dynamics and switching rate. Various embodiments of the invention correspond to various modes for connecting the electrodes to the power sources, and to various partitions of the closed volume into separate cells (13).

摘要翻译： 本发明涉及透明电致变色系统（100），其包括两对透明供电电极（1-4），其旨在电连接到可变电源（20,21）。 两对电极由系统的分开的外壁（10,11）支撑，在包含电活性物质的封闭体积的两侧。 电致变色系统具有优异的动态和开关率。 本发明的各种实施例对应于用于将电极连接到电源的各种模式，以及将闭合容积的各个分隔件分成单独的电池（13）。

公开(公告)号：US20110070361A1

公开(公告)日：2011-03-24

申请号：US12995290

申请日：2009-06-23

申请人： Sandrine Duluard ,  Claudine Biver

发明人： Sandrine Duluard ,  Claudine Biver

IPC分类号： B05D5/06 ,  B05D5/12 ,  B05D3/10

CPC分类号： C23C18/54

摘要： The invention relates to a method for the non-electrolytic deposition of a compound, preferably an electrochromic compound, comprising the following successive steps: (a) an electroconductive layer is deposited on a non-conductive solid substrate; (b) a reducing agent or an oxidizing agent (=redox agent) is deposited on an area of said electroconductive layer, said area covering only a portion of the surface of said electroconductive layer; and (c) a solution of a precursor of the compound to be deposited is brought into contact both with the redox agent and with at least a portion of the area of said electroconductive layer not covered by the redox agent, said precursor being chosen from those having an oxidation-reduction potential higher or lower than the redox agent and forming, after an oxidation-reduction reaction, a compound insoluble in the solution of the precursor of the compound to be deposited.

摘要翻译： 本发明涉及一种用于非电解沉积化合物，优选电致变色化合物的方法，包括以下连续步骤：（a）导电层沉积在非导电固体基质上; （b）还原剂或氧化剂（=氧化还原剂）沉积在所述导电层的区域上，所述区域仅覆盖所述导电层表面的一部分; 和（c）待沉积的化合物的前体的溶液与氧化还原剂接触，并且所述导电层的至少一部分区域未被氧化还原剂覆盖，所述前体选自那些 具有高于或低于氧化还原剂的氧化还原电位，并且在氧化还原反应之后形成不溶于待沉积化合物的前体溶液中的化合物。

公开(公告)号：US09001410B2

公开(公告)日：2015-04-07

申请号：US13817394

申请日：2011-08-16

申请人： Claudine Biver ,  Sandrine Duluard

发明人： Claudine Biver ,  Sandrine Duluard

IPC分类号： G02F1/01 ,  G02F1/15 ,  C09K9/00 ,  G02F1/153 ,  C23C18/16

CPC分类号： G02F1/15 ,  C09K9/00 ,  C23C18/16 ,  G02F1/1533 ,  G02F2202/36

摘要： The present invention relates to a process for manufacturing an electrochromic article, comprising the following successive steps: (a) deposition of a layer of an electrochromic compound on the surface of a transparent or translucent electroconductive substrate; (b) deposition of a redox agent, which is a reducing agent or an oxidizing agent for the electrochromic compound, on the layer of electrochromic compound at a multitude of discrete points or areas thereon; (c) bringing the layer of electrochromic compound, deposited in step (a), and the redox agent, deposited in step (b), into contact with a liquid electrolyte for a time long enough to allow the electrochromic compound to be reduced or oxidized by the redox agent; and (d) elimination of the electrolyte by rinsing and/or drying, the layer of electrochromic compound being a porous layer of open porosity and/or an electrically conductive layer.

摘要翻译： 本发明涉及电致变色制品的制造方法，包括以下连续步骤：（a）在透明或半透明导电基材的表面上沉积电致变色化合物层; （b）在其上的多个离散点或区域上在电致变色化合物层上沉积作为电致变色化合物的还原剂或氧化剂的氧化还原剂; （c）使步骤（a）中沉积的电致变色化合物层和步骤（b）中沉积的氧化还原剂与电解液接触足够长的时间以使电致变色化合物被还原或氧化 由氧化还原剂; 和（d）通过冲洗和/或干燥除去电解质，电致变色化合物层是开放孔隙度的多孔层和/或导电层。

公开(公告)号：US08551561B2

公开(公告)日：2013-10-08

申请号：US12995290

申请日：2009-06-23

申请人： Sandrine Duluard ,  Claudine Biver

发明人： Sandrine Duluard ,  Claudine Biver

IPC分类号： B05D5/12 ,  G02F1/153

CPC分类号： C23C18/54

摘要： The invention relates to a method for the non-electrolytic deposition of a compound, preferably an electrochromic compound, comprising the following successive steps: (a) an electroconductive layer is deposited on a non-conductive solid substrate; (b) a reducing agent or an oxidizing agent (=redox agent) is deposited on an area of said electroconductive layer, said area covering only a portion of the surface of said electroconductive layer; and (c) a solution of a precursor of the compound to be deposited is brought into contact both with the redox agent and with at least a portion of the area of said electroconductive layer not covered by the redox agent, said precursor being chosen from those having an oxidation-reduction potential higher or lower than the redox agent and forming, after an oxidation-reduction reaction, a compound insoluble in the solution of the precursor of the compound to be deposited.

摘要翻译： 本发明涉及一种用于非电解沉积化合物，优选电致变色化合物的方法，包括以下连续步骤：（a）导电层沉积在非导电固体基质上; （b）还原剂或氧化剂（=氧化还原剂）沉积在所述导电层的区域上，所述区域仅覆盖所述导电层表面的一部分; 和（c）待沉积的化合物的前体的溶液与氧化还原剂接触，并且所述导电层的至少一部分区域未被氧化还原剂覆盖，所述前体选自那些 具有高于或低于氧化还原剂的氧化还原电位，并且在氧化还原反应之后形成不溶于待沉积化合物的前体溶液中的化合物。