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公开(公告)号：US4584318A
公开(公告)日：1986-04-22
申请号：US505606
申请日：1983-06-20
IPC分类号： A01N35/10 , A01N37/40 , A01N37/48 , A01N47/22 , A01N55/00 , A01N55/10 , C07C69/00 , A01N37/02 , A01N37/06
摘要： A method is described for the control of nematodes in agricultural crops which comprises applying to the situs of infestation of a nematicidal composition containing as active ingredient a compound of the formula ##STR1## wherein Q is hydroxy, carbamoyloxy, or acyloxy, R is alkyl, alkenyl, alkynyl, X is halogen or methyl, n is 1 or 2. Preparation of active ingredient compounds is described, and nematicidal utility of compositions is exemplified.
摘要翻译： 描述了一种用于控制农作物中线虫的方法，其包括将含有作为活性成分的化合物（其中Q为羟基，氨基甲酰氧基或酰氧基）的化合物，R为烷基， 烯基，炔基，X为卤素或甲基，n为1或2.描述了活性成分化合物的制备，并列举了组合物的杀线虫效用。
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公开(公告)号：US4603147A
公开(公告)日：1986-07-29
申请号：US675111
申请日：1984-11-27
申请人： Clinton J. Peake , John F. Engel
发明人： Clinton J. Peake , John F. Engel
摘要： A method is described for the control of nematodes and soil-borne insects in agricultural crops which comprises applying to the situs of infestation a composition containing as active ingredient a compound of the formulaR--Z--(CH.sub.2).sub.n --Qwherein R is an alkyl radical of one or two carbon atoms carrying one-to-four fluorine substituents and one-to-three chlorine or bromine substituents represented as CF.sub.p X.sub.(3-p) -- or CF.sub.r X.sub.(3-r) --CF.sub.s X.sub.(2-s) --; Z is --(CH.sub.2 --CHX)-- or --(CH.dbd.CH)--; X is chlorine or bromine; Q is methyl, isopropyl, tert-butyl, or C.sub.3 -C.sub.6 cycloalkyl; n is 5 to 12 as required to yield in the compound a chain of 10 to 16 carbon atoms; p is 1 or 2; r is 2 or 3; s is 0 or 1 or 2. A process for preparation of active ingredient compounds is described, and utility of compositions against nematodes and soil-borne insects is exemplified.
摘要翻译： 描述了一种用于控制农作物中的线虫和土传昆虫的方法，其包括向侵染地点施用含有式RZ-（CH2）nQ的化合物作为活性成分的组合物，其中R是一个烷基 或具有一至四个氟取代基的两个碳原子和表示为CFpX（3-p） - 或CFrX（3-r）-CFX（2-s） - 的一至三个氯或溴取代基; Z是 - （CH 2 -CHX） - 或 - （CH = CH） - ; X是氯或溴; Q是甲基，异丙基，叔丁基或C 3 -C 6环烷基; 根据需要，n为5至12，以在化合物中产生10至16个碳原子的链; p为1或2; r为2或3; s是0或1或2.描述了制备活性成分化合物的方法，并且例示了针对线虫和土传昆虫的组合物的效用。
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3.发明授权Method of producing layered lithium metal oxides free of localized cubic spinel-like structural phases 有权不含局部立方尖晶石状结构相的层状锂金属氧化物的制造方法公开(公告)号：US06620400B2
公开(公告)日：2003-09-16
申请号：US09952357
申请日：2001-09-12
申请人： Yuan Gao , Marina Yakovleva , Hugh H. Wang , John F. Engel
发明人： Yuan Gao , Marina Yakovleva , Hugh H. Wang , John F. Engel
IPC分类号： C01D1500
CPC分类号： H01M4/525 , C01G1/02 , C01G45/1228 , C01G51/42 , C01G51/44 , C01G53/42 , C01G53/44 , C01P2002/32 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2002/86 , C01P2002/88 , C01P2006/40 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M10/052 , H01M10/0525 , H01M2004/028
摘要： The present invention includes substantially single-phase lithium metal oxide compounds having hexagonal layered crystal structures that are substantially free of localized cubic spinel-like structural phases. The lithium metal oxides of the invention have the formula Li&agr;M&bgr;A&ggr;O2, wherein M is one or more transition metals, A is one or more dopants having an average oxidation state N such that +2.5≦N≦+3.5, 0.90≦&agr;≦1.10, and &bgr;+&ggr;=1. The present invention also includes dilithiated forms of these compounds, lithium and lithium-ion secondary batteries using these compounds as positive electrode materials, and methods of preparing these compounds.
摘要翻译： 本发明包括基本上没有局部立方尖晶石状结构相的具有六方层状晶体结构的单相锂金属氧化物化合物。 本发明的锂金属氧化物具有式LialphaMetaAgammaO2，其中M是一种或多种过渡金属，A是一种或多种具有平均氧化态N的掺杂剂，使得+2.5≤N≤3.5,0.90< = 1.10，β+γ= 1。 本发明还包括这些化合物的稀释形式，使用这些化合物作为正极材料的锂和锂离子二次电池及其制备方法。
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公开(公告)号：US5605872A
公开(公告)日：1997-02-25
申请号：US459585
申请日：1995-06-02
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 制备以下一般结构的单官能胺引发剂的烃溶液的方法：MQnZN（A（R1R2R3））2金属，选自锂，钠和钾，Q是衍生的饱和或不饱和烃基 通过并入选自共轭二烯烃和烯基取代的芳族烃的化合物; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。
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公开(公告)号：US5600021A
公开(公告)日：1997-02-04
申请号：US458602
申请日：1995-06-02
IPC分类号： C07F1/02 , C08C19/44 , C08F4/08 , C08F4/42 , C08F4/46 , C08F4/48 , C08F8/00 , C08F36/00 , C08F36/04 , C08F279/00 , C08F279/02 , C07C43/04
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure:M--Z--O--C(R.sup.1 R.sup.2 R.sup.3)wherein M is an alkali metal; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, aryl or substituted aryl groups, and their employment as initiators in the anionic polymerization of olefin containing monomers in an inert, hydrocarbon solvent comprising reacting an omega-protected-1-haloalkyl with lithium metal dispersion having a particle size between 10 and 300 millimicrons in size, at a temperature between 35.degree. and 130.degree. C. in an alkane solvent containing 5 to 10 carbon atoms.
摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Z-O-C（R 1 R 2 R 3）其中M为碱金属; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; 并且R 1，R 2和R 3独立地选自氢，烷基，取代的烷基，芳基或取代的芳基，并且它们用作惰性烃溶剂中含烯烃单体的阴离子聚合中的引发剂，包括使ω-保护的 - 在具有5至10个碳原子的烷烃溶剂中，在35至130℃之间的温度下，具有尺寸在10-300毫微米之间的锂金属分散体的1-卤代烷基。
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公开(公告)号：US5567774A
公开(公告)日：1996-10-22
申请号：US460300
申请日：1995-06-02
IPC分类号： C07F1/02 , C08C19/44 , C08F4/08 , C08F4/42 , C08F4/46 , C08F4/48 , C08F8/00 , C08F36/00 , C08F36/04 , C08F279/00 , C08F279/02 , C08F8/30 , C08F8/08
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure:M--Z--O--C(R.sup.1 R.sup.2 R.sup.3)wherein M is an alkali metal; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, aryl or substituted aryl groups, and their employment as initiators in the anionic polymerization of olefin containing monomers in an inert, hydrocarbon solvent comprising reacting an omega-protected-1-haloalkyl with lithium metal dispersion having a particle size between 10 and 300 millimicrons in size, at a temperature between 35.degree. and 130.degree. C. in an alkane solvent containing 5 to 10 carbon atoms.
摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Z-O-C（R 1 R 2 R 3）其中M为碱金属; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; 并且R 1，R 2和R 3独立地选自氢，烷基，取代的烷基，芳基或取代的芳基，并且它们用作惰性烃溶剂中含烯烃单体的阴离子聚合中的引发剂，包括使ω-保护的 - 在具有5至10个碳原子的烷烃溶剂中，在35至130℃之间的温度下，具有尺寸在10-300毫微米之间的锂金属分散体的1-卤代烷基。
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公开(公告)号：US5527753A
公开(公告)日：1996-06-18
申请号：US354998
申请日：1994-12-13
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 制备以下一般结构的单官能胺引发剂的烃溶液的方法：MQnZN（A（R1R2R3））2金属，选自锂，钠和钾，Q是衍生的饱和或不饱和烃基 通过并入选自共轭二烯烃和烯基取代的芳族烃的化合物; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。
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8.发明授权1R,Cis-3-(2-halo-3,3,3-trifluoro-1-propenyl)-2,2-di methylcyclopropanecarboxylic acid derivatives 失效1R，顺式-3-（2-卤代-3,3,3-三氟-1-丙烯基）-2,2-二甲基环丙烷甲酸衍生物
公开(公告)号：US4395567A
公开(公告)日：1983-07-26
申请号：US327839
申请日：1981-12-07
申请人： John F. Engel
发明人： John F. Engel
CPC分类号： C07C57/38 , A01N37/10 , A01N53/00 , C07C61/40 , C07F9/5442
摘要： 1R,cis-trifluoromethylethenylcyclopropanecarbonyl compounds of the formula ##STR1## in which X is halogen and R is halogen, hydroxy, lower alkoxy or an optionally substituted 1,1'-biphenyl-3-methyloxy group, their method of preparation and utility as insecticides and intermediates therefore are described and exemplified.
摘要翻译： 1R，其中X为卤素且R为卤素，羟基，低级烷氧基或任选取代的1,1'-联苯-3-甲氧基的式“IMAGE”的顺式 - 三氟甲基乙酰基环丙烷羰基化合物，其制备方法及其用作杀虫剂 因此描述和示例中间体。
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9.发明授权
公开(公告)号：US4235927A
公开(公告)日：1980-11-25
申请号：US55212
申请日：1979-07-06
申请人： John F. Engel
发明人： John F. Engel
IPC分类号： A01N37/10 , A01N53/00 , A01N53/04 , C07C17/26 , C07C29/52 , C07C35/32 , C07C57/38 , C07C61/40 , C07F9/54 , A01N9/28 , C07D307/54
CPC分类号： C07F9/5442 , A01N37/10 , A01N53/00 , C07C17/2635 , C07C29/52 , C07C35/32 , C07C57/38 , C07C61/40
摘要： Perhaloalkylvinylcyclopropanecarboxylates having the general formula ##STR1## are disclosed wherein one of Y and Z is a perhaloalkyl group and the other is hydrogen, halogen, or lower alkyl. Compounds in which R is hydroxy, halogen or lower alkoxy are intermediates for preparation of insecticidal esters in which R is an optionally substituted benzylfurylmethoxy group. The insecticidal efficacy and preparation of the compounds and intermediates therefor are described and exemplified.
摘要翻译： 公开了具有通式“IMAGE”I的全卤代烷基乙烯基环丙烷羧酸酯，其中Y和Z之一是全卤代烷基，另一个是氢，卤素或低级烷基。 其中R是羟基，卤素或低级烷氧基的化合物是制备杀虫剂的中间体，其中R是任选取代的苄基甲氧基。 化合物及其中间体的杀虫功效及其制备方法进行了说明和实例。
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10.发明授权Layered lithium metal oxides free of localized cubic spinel-like structural phases and methods of making same 有权层状锂金属氧化物不含局部立方尖晶石结构相及其制造方法公开(公告)号：US07074382B2
公开(公告)日：2006-07-11
申请号：US10170180
申请日：2002-06-12
申请人： Yuan Gao , Marina Yakovleva , Hugh H. Wang , John F. Engel
发明人： Yuan Gao , Marina Yakovleva , Hugh H. Wang , John F. Engel
CPC分类号： H01M4/525 , C01G1/02 , C01G45/1228 , C01G51/42 , C01G51/44 , C01G53/42 , C01G53/44 , C01P2002/32 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2002/86 , C01P2002/88 , C01P2006/40 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M10/052 , H01M10/0525 , H01M2004/028
摘要： The present invention includes substantially single-phase lithium metal oxide compounds having hexagonal layered crystal structures that are substantially free of localized cubic spinel-like structural phases. The lithium metal oxides of the invention have the formula LiαMβAγO2, wherein M is one or more transition metals, A is one or more dopants having an average oxidation state N such that +2.5≦N≦+3.5, 0.90≦α≦1.10, and β+γ=1. The present invention also includes dilithiated forms of these compounds, lithium and lithium-ion secondary batteries using these compounds as positive electrode materials, and methods of preparing these compounds.
摘要翻译： 本发明包括基本上没有局部立方尖晶石状结构相的具有六方层状晶体结构的单相锂金属氧化物化合物。 本发明的锂金属氧化物具有下式：其中M是 一种或多种过渡金属，A是一种或多种具有平均氧化态N的掺杂剂，使得+2.5≤N≤3.5,0.90<=α1= 1.10和β+γ= 1。 本发明还包括这些化合物的稀释形式，使用这些化合物作为正极材料的锂和锂离子二次电池及其制备方法。
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