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公开(公告)号:US20240050959A1
公开(公告)日:2024-02-15
申请号:US18253015
申请日:2021-11-05
申请人: Continental Reifen Deutschland GmbH , Fraunhofer Gesellschaft zur Förderung der angewandten Forschung e.V.
发明人: Carla Recker , Frank Behm , Katharina Herzog , Norbert Janczak , Carsten Venz , Dirk Prüfer , Christian Schulze Gronover
摘要: The invention relates to a process for obtaining natural rubber from plant material containing at least the step of milling the plant material with at least one ball mill comprising milling media. The invention further relates to the natural rubber obtained by this process and to the use of at least one ball mill comprising milling media for milling plant material when obtaining natural rubber from plant material.
In the process, the ball mill has a nonmetallic lining and/or the milling media have at least a nonmetallic surface.-
2.
公开(公告)号:US20230391894A1
公开(公告)日:2023-12-07
申请号:US18246388
申请日:2021-09-14
申请人: Continental Reifen Deutschland GmbH , Fraunhofer Gesellschaft zur Förderung der angewandten Forschung e.V.
发明人: Carla Recker , Katharina Herzog , Frank Behm , Norbert Janczak , Carsten Venz , Lowis-Gerrit-Boje Müller , Dirk Prüfer , Christian Schulze Gronover
摘要: The present invention relates to a process for obtaining aging-resistant natural rubber, to a rubber composition comprising the thus-obtained natural rubber and to the use of this composition for producing consumer goods.
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3.
公开(公告)号:US20240294730A1
公开(公告)日:2024-09-05
申请号:US18564972
申请日:2022-05-03
发明人: David-Raphael Dauer , Julien Davin , Nils Hojdis , Norbert Müller , Carla Recker , Fabian Schax , Julia Schöffel , Gesa Tarantola , Christine Weber
CPC分类号: C08K3/06 , B60C1/0016 , C08K3/36 , C08K5/548 , C08L9/06 , C08K2201/014
摘要: A sulfur-crosslinkable rubber mixture, to the vulcanizate thereof, and to a vehicle tire. The sulfur-crosslinkable rubber mixture comprises at least the following constituents: —at least one solution-polymerized styrene-butadiene rubber (SSBR) having a glass transition temperature Tg according to DSC of −35° C. to −85° C.; and —at least one silica; and —1 to 30 phf of at least one silane A having the general empirical formula A-I) (R1)oSi—R2—(S—R3)q—S—X; and —0.5 to 30 phf of at least one silane B having the general empirical formula B-I) (R1)oSi—R2—(S—R3)u—S—R2—Si(R1)o, where q=1 or 2 or 3; and u=1 or 2 or 3; and X is a hydrogen atom or a —C(═O)—R8 group where R8 is selected from hydrogen, C1-C20 alkyl groups, C6-C20 aryl groups, C2-C20 alkenyl groups and C7-C20 aralkyl groups.
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公开(公告)号:US11142594B2
公开(公告)日:2021-10-12
申请号:US16596506
申请日:2019-10-08
发明人: Emily Baird Anderson , John Dayton Baker, Jr. , Terri Roxanne Carvagno , Judicael Jacques Chapelet , Wei Min Cheng , Liu Deng , Jacobus Gillis De Hullu , Sebastian Finger , Hubert Hirschlag , Christopher Lee Lester , Wentao Li , Mutombo Joseph Muvundamina , Mark Stanley Pavlin , Fabian Peters , Carla Recker , Christopher Thomas Scilla
IPC分类号: C08F12/22 , C08F12/08 , C08F20/14 , C08L7/00 , C08L9/06 , C08L53/02 , C09J125/10 , C09J131/04 , C09J133/10
摘要: Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.
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公开(公告)号:US10858499B1
公开(公告)日:2020-12-08
申请号:US16622966
申请日:2018-05-14
发明人: Andreas Jacob , David-Raphael Dauer , Julian Strohmeier , Julia Schoeffel , Carla Recker , Kirsten Schwekendiek , Norbert Mueller
摘要: The invention relates to a silane, to a rubber mixture comprising the silane and to a vehicle tire comprising the rubber mixture in at least one component.The inventive silane has the following formula I) (R1)oSi—R2—X-A-Y-[A-Y-]m-A-Sk-A-[-Y-A]mY-A-X—R2—Si(R1)o, wherein, according to the invention, the silane has spacer groups between the respective silyl groups and the Sk moiety which have at least two aromatic groups A and the linking units X and Y, wherein the groups X within a molecule may be identical or different from each other and are selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R3NC(═O)NR3—, —R3NC(═NR3)NR3—, —R3NC(═S)NR3—, wherein at least one R3 within each group X is a hydrogen atom; and wherein the groups Y within a molecule may be identical or different from each other and are selected from the groups —HNC(═O)—, —C(═O)NH—, —C(═O)O—, —OC(═O)—, —OC(═O)NH—, —HNC(═O)O—, —R4NC(═O)NR4—, —R4NC(═NR4)NR4—, —R4NC(═S)NR4—, wherein at least one R4 within each group Y is a hydrogen atom. The inventive rubber mixture comprises at least one inventive silane.
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6.
公开(公告)号:US20200377702A1
公开(公告)日:2020-12-03
申请号:US16765051
申请日:2018-08-09
发明人: Julia Schoeffel , Norbert Mueller , Carla Recker , Christine Weber , Gesa Tarantola , David-Raphael Dauer , Fabian Schax , Nils Hojdis
摘要: The invention relates to a sulfur-crosslinkable rubber mixture, to a vulcanizate thereof and to a vehicle tire. The sulfur-crosslinkable rubber mixture contains at least the following constituents: at least one diene rubber; and 10 to 300 phr of at least one silica; and 1 to 30 phf of at least one silane A having general empirical formula A-I) and/or A-XI) A-I) (R1)oSi—R2—(S—R3)q—Sx—(R3—S)q—R2—Si(R1)o; A-XI) (R1)oSi—R2—(S—R3)s—S—X; and 0.5 to 30 phf of at least one silane B having general empirical formula B-I) B-I) (R1)oSi—R4—Si(R1)o wherein x is an integer from 2 to 10, q is 0, 1, 2 or 3 and s is 1, 2 or 3 and X is a hydrogen atom or a C(═O)—R8 group wherein R8 is selected from hydrogen C1-C20-alkyl groups, C6-C20-aryl groups, C2-C20-alkenyl groups and C7-C20-aralkyl groups.
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公开(公告)号:US20200277471A1
公开(公告)日:2020-09-03
申请号:US16603823
申请日:2018-04-09
发明人: Fabian Peters , Emily Baird Anderson , John Dayton Baker, Jr. , Terri Roxanne Carvagno , Judicael Jacques Chapelet , Wei Min Cheng , Liu Deng , Jacobus Gillis de Hullu , Sebastian Finger , Hubert Hirschlag , Christopher Lee Lester , Wentao Li , Mutombo Joseph Muvundamina , Mark Stanley Pavlin , Carla Recker , Christopher Thomas Scilla
IPC分类号: C08L7/00 , C08F257/02 , C09J123/08 , C08F12/22 , C08F8/42 , C08F30/08 , C09J123/20 , B60C1/00 , B60C13/00 , B60C11/00
摘要: Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.
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公开(公告)号:US20190194428A1
公开(公告)日:2019-06-27
申请号:US16325210
申请日:2017-08-14
发明人: Carla Recker , Catarina Sa , Kathrin Wehming-Bomkamp , Viktoria Pavon Sierra , Norbert Mueller , Michael Radke
CPC分类号: C08L9/06 , B29B7/7495 , B60C1/00 , B60C1/0016 , C08C19/22 , C08C19/25 , C08C19/44 , C08K3/04 , C08K3/36 , C08K5/548 , C08L15/00 , C08L2312/00
摘要: The invention relates to a sulfur-crosslinkable rubber mixture, containing: a rubber blend of at least one high-molecular-weight, solution-polymerized diene polymer A and at least one low-molecular-weight, solution-polymerized polymer B, wherein at least one of the polymers A or B is functionalized at the chain end and/or along the polymer chain and/or in a coupling center with at least one group selected from epoxy groups, hydroxy groups, carboxy groups, silane-sulfide groups, amino groups, siloxane groups, organosilicon groups, phthalocyanine groups, and from alkoxysilyl groups containing amino groups, and as a filler, at least one silicic acid and/or at least one carbon black in an amount of 25 to 300 phr, wherein the ratio of carbon black to silicic acid in the mixture is 100:0 to 3:97.
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公开(公告)号:US10214635B2
公开(公告)日:2019-02-26
申请号:US15310862
申请日:2015-03-18
IPC分类号: C08K5/548 , B60C1/00 , C08L9/00 , C08K3/36 , B29B7/74 , C08L9/06 , C08K3/06 , C08K3/22 , C08K5/09 , C08K5/31 , C08L7/00 , C08L91/00
摘要: The invention relates to a sulfur-crosslinkable rubber mixture, in particular for treads of vehicle tires, and to a vehicle tire. The rubber mixture contains at least the following components: at least one diene rubber and 10 to 200 phr of at least one silicic acid and 2 to 20 phf of at least one silane having general empirical formula I) [(R1)3Si—X]mSn(R2)2-m, wherein the residues R1 within a molecule can be the same or different and are alkoxy groups having 1 to 10 carbon atoms or cyclic dialkoxy groups having 2 to 10 carbon atoms or cycloalkoxy groups having 4 to 10 carbon atoms or phenoxy groups or aryl groups having 6 to 20 carbon atoms or alkyl groups having 1 to 10 carbon atoms or alkenyl groups having 2 to 20 carbon atoms or aralkyl groups having 7 to 20 carbon atoms or halides and wherein X is a polar organic group containing urea and wherein m assumes the value 1 or 2 and wherein n is an integer from 1 to 8 and wherein R2 is a hydrogen atom or an acyl group having 1 to 20 carbon atoms.
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公开(公告)号:US09683088B2
公开(公告)日:2017-06-20
申请号:US14635634
申请日:2015-03-02
发明人: Carla Recker , Lena Mueller , Thomas Voelker
CPC分类号: C08J11/28 , B29B7/7495 , C08J11/10 , C08J2317/00 , C08J2321/00 , C08K5/5398 , C08K5/548 , Y02T10/862 , Y02W30/702 , Y02W30/706
摘要: A process for regenerating sulfur-crosslinked rubber vulcanizates to regenerates, wherein at least one regenerating agent is used in the regeneration. The regenerating agent is selected from the group consisting of dithiophosphoryl polysulfides and/or silanes having a polysulfane group. Regenerates which have been produced by means of the process lead to improved or equal rolling resistance indicators and a lower compression set in vulcanized rubber mixtures compared to regenerates known in the prior art.
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