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公开(公告)号：US06348510B1
公开(公告)日：2002-02-19
申请号：US09595031
申请日：2000-06-16
IPC分类号： C07C2700
CPC分类号： C10G2/342
摘要： Optimized process for effecting the production of heavy hydrocarbons according to the Fischer-Tropsch method which comprises: (a) feeding the reagent gases into a reactor; (b) at least partially recovering the heavy hydrocarbons formed in step (a) by their external or internal separation from the catalytic particles; the above process being characterized in that in step (a) the reaction takes place: (1) in t he presence of solid particles which have a particle Reynolds number (Rep) greater than 0.1, (2) keeping the solid particles suspended at a height H, with Us, Ul, and Ug value s which are such as to have a Bodenstein number Bos≦1, preferably ≦0.4.
摘要翻译： 用于根据费 - 托法进行重烃生产的优化方法包括：（a）将反应气供给到反应器中;（b）至少部分地通过其外部或外部的步骤（a）回收步骤（a）中形成的重质烃， 内部与催化剂颗粒分离;上述方法的特征在于在步骤（a）中发生反应：（1）在具有大于0.1的颗粒雷诺数（Rep）的固体颗粒的存在下，（2） 将固体颗粒保持在高度H处，其中Us，Ul和Ug值s具有博登斯坦数Bos <= 1，优选<= 0.4。
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公开(公告)号：US5827902A
公开(公告)日：1998-10-27
申请号：US907010
申请日：1997-08-06
申请人： Cristina Maretto , Vincenzo Piccolo
发明人： Cristina Maretto , Vincenzo Piccolo
CPC分类号： C10G2/342
摘要： Process for the optimum operation of a slurry bubble column reactor in the presence of a gas phase and a liquid phase, particularly for the Fischer-Tropsch reaction, characterized in that: 1) the process is carried out in a number of stages in series of .gtoreq.2;2) the flow conditions of the gas phase and liquid phase containing the solids are essentially plug flow conditions, with a gas rate of between 3 cm/s and 200 cm/s and a liquid rate of between 0 and 10 cm/s; 3) the concentration of solids in each stage is essentially constant and equal for each single stage, and is between 5 and 50% (vol./vol.).
摘要翻译： 在气相和液相存在下，特别是费 - 托反应的浆液鼓泡塔反应器的最佳操作的方法，其特征在于：1）该方法以多个阶段进行 > / = 2; 2）包含固体的气相和液相的流动条件基本上是气流条件，气体速率在3cm / s至200cm / s之间，液体速率在0至10cm / s之间; 3）每个阶段中固体的浓度基本上是恒定的，对于每个单一阶段是相同的，并且在5至50％（体积/体积）之间。
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3.发明授权Process for regenerating a catalyst contained within a bubble-column reactor with draft-tube and process for the production of a hydrocarbon 有权用起泡管再生含有气泡塔式反应器内的催化剂的方法和用于生产烃的方法
公开(公告)号：US6162754A
公开(公告)日：2000-12-19
申请号：US147736
申请日：1999-03-18
IPC分类号： B01J38/10 , B01J8/22 , B01J38/48 , B01J38/58 , C07C1/04 , C07C9/02 , C10G2/00 , B01J20/34 , B01J38/56
CPC分类号： C10G2/342 , B01J8/226 , B01J38/48 , B01J2208/00132 , B01J2208/0084 , B01J2219/00033 , C07C1/049 , Y02P20/584
摘要： Continuous process for the production of prevalently heavy hydrocarbons starting from synthesis gas in the presence of a gas phase, a liquid and a solid catalyst, the above process being carried out using a bubble column, characterized in that the bubble column internally has: (a) at least one draft-tube; (b) at least one device for the inlet of the synthesis gas; (c) at least one device for the inlet of the regenerating gas; (d) at least one device for activating/interrupting the stream of regenerating gas; (e) optional devices suitable for minimizing the mixing of the synthesis gas with the regenerating gas.
摘要翻译： PCT No.PCT / EP98 / 03874 371 1999年3月18日 102（e）1999年3月18日PCT提交1998年6月20日PCT公布。 公开号WO99 / 00191 日期1999年1月7日在气相，液体和固体催化剂存在下从合成气开始生产普遍重质烃的连续方法，上述方法使用气泡塔进行，其特征在于气泡塔 内部具有：（a）至少一个通气管; （b）用于合成气入口的至少一个装置; （c）用于再生气体入口的至少一个装置; （d）用于激活/中断再生气体流的至少一个装置; （e）适于最小化合成气与再生气体的混合的可选装置。
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公开(公告)号：US20100016455A1
公开(公告)日：2010-01-21
申请号：US12520002
申请日：2007-12-18
申请人： Vincenzo Piccolo , Susi Bonomi , Marzio Piazza
发明人： Vincenzo Piccolo , Susi Bonomi , Marzio Piazza
CPC分类号： B01J8/22 , B01J8/008 , B01J8/1836 , B01J2208/00132 , B01J2219/0002 , B01J2219/0286
摘要： Modular reactor for exothermic/endothermic chemical reactions which take place in three-phase systems, comprising a series of modules, superimposed with respect to each other, fixed to each other by means of coupling flanges, each module consisting of an external cylindrical body and a series of tube bundles, for the circulation of a thermal-exchange fluid, positioned inside said body.
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5.发明授权Reactor for chemical reactions in triphasic systems having superimposed thermal exchange sections 有权具有叠加热交换部分的三相系统中的化学反应反应器
公开(公告)号：US6132690A
公开(公告)日：2000-10-17
申请号：US172272
申请日：1998-10-14
IPC分类号： B01J19/00 , B01J8/00 , B01J8/18 , B01J8/20 , B01J8/22 , B01J19/24 , B01J19/26 , C07C1/04 , C10G2/00
CPC分类号： C10G2/342 , B01J8/0065 , B01J8/1836 , B01J8/22 , B01J8/228 , B01J2208/00212 , B01J2219/0077
摘要： Reactor for chemical reactions which are carried out in triphasic systems (liquid, gas, solid) which includes a bottom head into which the reagent gas is fed, through an inlet nozzle; one or more superimposed thermal exchange sections, each of these sections being immersed in the corresponding synthesis sections; a head containing outlet nozzles for discharging the suspension and outlet nozzles for discharging the non-reacted gas and a group of inclined transversal diaphragms for separating the particles of liquid and/or solid drawn therein.
摘要翻译： 通过入口喷嘴在三相系统（液体，气体，固体）中进行的用于化学反应的反应器，其包括通过反应气供给的底部头; 一个或多个叠加的热交换部分，这些部分中的每一个都浸没在相应的合成部分中; 用于排出悬浮液的出口喷嘴和用于排出未反应的气体的出口喷嘴的头部和用于分离其中抽吸的液体和/或固体的颗粒的一组倾斜的横向隔膜。
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公开(公告)号：US6121333A
公开(公告)日：2000-09-19
申请号：US335484
申请日：1999-06-18
申请人： Gabriele Carlo Ettore Clerici , Vincenzo Piccolo , Giuseppe Belmonte , Paul Broutin , Fran.cedilla.ois Hugues
发明人： Gabriele Carlo Ettore Clerici , Vincenzo Piccolo , Giuseppe Belmonte , Paul Broutin , Fran.cedilla.ois Hugues
IPC分类号： B01J23/648 , C07B61/00 , C07C1/04 , C07C9/14 , C07C9/22 , C10G2/00 , C10G47/12 , C10G47/26 , C10G69/02 , C07C27/00 , C07C1/00 , C07C5/00
摘要： Process for the production of hydrocarbons from synthesis gas which comprises:a) feeding to a reactor for Fischer-Tropsch reactions, containing a catalyst based on supported cobalt, a synthesis gas in molar ratios H.sub.2 /CO ranging from 1 to 3;b) discharging from the reactor a hydrocarbon liquid phase containing the catalyst, in suspension;c) feeding the suspension to a hydrocracking reactor operating at a temperature ranging from 200 to 500.degree. C.;d) discharging a vapour phase from the head of the hydrocracking reactor and from the bottom a suspension containing heavier products which is recycled to the Fischer-Tropsch reactor;e) cooling and condensing the vapour phase.
摘要翻译： 用于从合成气生产烃的方法，其包括：a）进料到费 - 托反应的反应器，其包含基于负载的钴的催化剂，摩尔比H2 / CO范围为1至3的合成气; b）将悬浮液中含有催化剂的烃液相从反应器中排出; c）将所述悬浮液供给到在200-500℃的温度下操作的加氢裂化反应器; d）从加氢裂化反应器的头部排出气相，从底部排出含有较重产物的悬浮液，再循环至费 - 托反应器; e）冷却和冷凝气相。
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公开(公告)号：US6096789A
公开(公告)日：2000-08-01
申请号：US295416
申请日：1999-04-21
IPC分类号： B01J23/75 , B01D21/26 , B01J8/00 , B01J8/22 , C07B61/00 , C07C1/04 , C07C1/06 , C10G2/00 , C07C27/00
CPC分类号： C10G2/343 , B01J8/0055 , B01J8/228 , C07C1/066
摘要： Process for the production of hydrocarbons from synthesis gas which comprises: a) feeding to the bottom of a reactor for Fischer-Tropsch reactions a synthesis gas with molar ratios H.sub.2 /CO ranging from 1 to 3;b) discharging from the head of the reactor a hydrocarbon liquid phase containing the catalyst, in suspension;c) feeding the suspension to at least a first hydrocyclone to obtain a partially separated product containing from 0.5 to 15% by volume of solid particles;d) feeding the partially separated product to at least a second hydrocyclone to obtain a stream of liquid substantially without solid particles.
摘要翻译： 从合成气生产碳氢化合物的方法，其包括：a）将摩尔比H 2 / CO范围为1至3的合成气送入用于费 - 托反应的反应器的底部; b）从反应器的头部排出含有催化剂的烃液相悬浮液; c）将悬浮液供给到至少第一水力旋流器以获得含有0.5至15体积％的固体颗粒的部分分离的产物; d）将部分分离的产物供给到至少第二个水力旋流器以获得基本上没有固体颗粒的液体流。
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公开(公告)号：US5248814A
公开(公告)日：1993-09-28
申请号：US944041
申请日：1992-09-11
IPC分类号： C08H99/00
摘要： Process for preparing regenerated humic acids from coal by means of the continuous oxidation on fluidized bed, characterized in that a coal of lignite, sub-bituminous or bituminous type is submitted to a preliminary oxidation under mild conditions in order to reduce the hydrogen content of said coal by an amount of 5 to 25% of hydrogen initially present in the starting coal, and that the resulting coal is subsequently submitted to an oxidation in order to produce the desired humic acids.
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公开(公告)号：US08092747B2
公开(公告)日：2012-01-10
申请号：US12520002
申请日：2007-12-18
申请人： Vincenzo Piccolo , Susi Bonomi , Marzio Piazza
发明人： Vincenzo Piccolo , Susi Bonomi , Marzio Piazza
CPC分类号： B01J8/22 , B01J8/008 , B01J8/1836 , B01J2208/00132 , B01J2219/0002 , B01J2219/0286
摘要： Modular reactor for exothermic/endothermic chemical reactions which take place in three-phase systems, comprising a series of modules, superimposed with respect to each other, fixed to each other by means of coupling flanges, each module consisting of an external cylindrical body and a series of tube bundles, for the circulation of a thermal-exchange fluid, positioned inside said body.
摘要翻译： 在三相系统中发生的用于放热/吸热化学反应的模块化反应器，包括通过联接凸缘相互相对重叠的一系列模块，每个模块由外部圆柱体和 一系列管束，用于定位在所述体内的热交换流体的循环。
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公开(公告)号：US06689819B2
公开(公告)日：2004-02-10
申请号：US10404041
申请日：2003-04-02
申请人： Giuseppe Bellussi , Roberto Zennaro , Vincenzo Piccolo , Enrico Radaelli , Magalie Roy-Auberger
发明人： Giuseppe Bellussi , Roberto Zennaro , Vincenzo Piccolo , Enrico Radaelli , Magalie Roy-Auberger
IPC分类号： C07C2706
CPC分类号： C10G2/332 , B01J21/04 , B01J23/75 , B01J35/023 , B01J35/10 , B01J35/1019 , B01J35/1038 , C07C1/0425
摘要： A supported cobalt-based catalyst, characterized in that the carrier has an average particle diameter, measured by Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured by the B.E.T. method. The catalyst is particularly useful in the Fischer-Tropsch reaction.
摘要翻译： 一种负载的钴基催化剂，其特征在于载体的平均粒径由Coulter LS230测量，范围为70-250μm，表面积高于175m 2 / g，孔体积高于0.35cm <3> / g，由BET测量 方法。 催化剂在费 - 托反应中特别有用。
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