摘要:
A flexible single- or multilayer non-oriented or mono- or biaxially oriented film in which at least one layer comprises a cycloolefin copolymer, wherein the cycloolefin copolymer has a mechanical loss factor (tan .delta.) of .gtoreq.0.015 at 50.degree. C. below the glass transition temperature.
摘要:
A rigid single- or multilayer non-oriented or mono- or biaxially oriented film in which at least one layer comprises a cycloolefin copolymer, wherein the cycloolefin copolymer has an intrinsic E modulus (E.sub.i) which has the following dependence on the glass transition temperature T.sub.g :E.sub.i =(0.0025[GPa/.degree.C.].times.T.sub.g [.degree.C.])+B[GPa]where B=2.93-3.19 and T.sub.g is the glass transition temperature.
摘要:
A material of a cycloolefin copolymer has a structure of alternating cycloolefin sequences, and has crystallinity in a temperature range from 210.degree. to 320.degree. C. The cycloolefin is prepared by polymerization of at least one polycyclic olefin, monocyclic and/or acyclic olefin with an open-chain olefin using a catalyst of a metallocene and an aluminoxane.
摘要:
Cycloolefin block copolymers and a process for their preparation Cycloolefin block copolymers, which in particular are suitable as phase promoters, are preferably obtained by copolymerization of polycyclic olefins, such as norbornene, with acyclic olefins, such as ethylene, by, at a molecular weight distribution M.sub.w /M.sub.n of the polymer block forming of less than 2, changing the reaction conditions one or more times in such a way that the monomer/comonomer ratio changes by at least 10% or a further polymerizable monomer is metered into the monomer or the monomers.
摘要:
A fiber-reinforced cycloolefin polymer material comprises 1 to 99% by weight of reinforcing fibers, in particular glass fibers, and 99 to 1% by weight of a cycloolefin copolymer which is built up froma) at least one (polycyclo)olefin which is derived from norbornene, for example tetracyclododecene, and b) at least one olefin which is chosen from monocycloolefins having 4 to 12 C atoms (VII) and/or the group of acyclic olefins VIII ##STR1## in which R.sup.9, R.sup.10, R.sup.11 and R.sup.12 are identical or different and are a hydrogen atom or a C.sub.1 -C.sub.8 -alkyl radical. VII is preferably ethylene. The monomer units of the (polycyclo)olefin in the cycloolefin copolymer molecule are in each case separated by monomer units of the cyclic olefins VII and/or of the acyclic olefins of the formula VIII.
摘要翻译:纤维增强的环烯烃聚合物材料包含1至99重量%的增强纤维,特别是玻璃纤维,和99至1重量%的环烯烃共聚物,其由以下组成:a)至少一种(多环)烯烃,其是 衍生自降冰片烯,例如四环十二碳烯,和b)至少一种选自具有4-12个碳原子的单环烯烃(VII)和/或非环烯烃VIII(VIII)的烯烃,其中R 9,R 10, R 11和R 12相同或不同,为氢原子或C1-C8-烷基。 VII优选为乙烯。 在环烯烃共聚物分子中的(多环)烯烃的单体单元各自由环状烯烃VII和/或式VIII的无环烯烃的单体单元分离。
摘要:
Chemically homogeneous cycloolefin copolymers of polycyclic olefins, such as, for example, norbornene or tetracyclododecene, with cycloolefins and/or acyclic olefins are obtained without ring opening and in a high space-time yield if a catalyst system is used which comprises an aluminoxane and a stereorigid metallocene compound of an element from groups IVb to VIb, of the formula ##STR1## the part of the metallocene molecule formed by M.sup.1 and the substituents R.sup.16 -R.sup.17 having C.sub.1 -symmetry or being in the meso-form.
摘要:
The present invention relates to a fiber which comprises at least one partly crystalline cycloolefin copolymer which can be prepared by polymerization of a symmetrical polycyclic olefin, an acyclic olefin and, if desired, a monocyclic olefin in the presence of a catalyst system comprising an aluminoxane and a metallocene compound of the formula
摘要:
Thermoplastic cycloolefin copolymers (COCs) having high tear strength and low optical attenuation, a process for their preparation, and their use as optical waveguides (optical fibers).
摘要:
The present invention relates to a fiber which comprises at least one partly crystalline cycloolefin copolymer which can be prepared by polymerization of a symmetrical polycyclic olefin, an acyclic olefin and, if desired, a monocyclic olefin in the presence of a catalyst system comprising an aluminoxane and a metallocene compound of the formula