Cycloolefin block copolymers and a process for their preparation
    5.
    发明授权
    Cycloolefin block copolymers and a process for their preparation 失效
    环烯烃嵌段共聚物及其制备方法

    公开(公告)号:US5475060A

    公开(公告)日:1995-12-12

    申请号:US240823

    申请日:1994-05-10

    CPC分类号: C08F297/08 C08F210/02

    摘要: Cycloolefin block copolymers and a process for their preparation Cycloolefin block copolymers, which in particular are suitable as phase promoters, are preferably obtained by copolymerization of polycyclic olefins, such as norbornene, with acyclic olefins, such as ethylene, by, at a molecular weight distribution M.sub.w /M.sub.n of the polymer block forming of less than 2, changing the reaction conditions one or more times in such a way that the monomer/comonomer ratio changes by at least 10% or a further polymerizable monomer is metered into the monomer or the monomers.

    摘要翻译: 环烯烃嵌段共聚物及其制备方法环烯烃嵌段共聚物,特别适合作为相促进剂,优选通过使多环烯烃如降冰片烯与非环烯烃如乙烯共聚而得到,分子量分布 聚合物嵌段的Mw / Mn小于2,改变反应条件一次或多次,使得单体/共聚单体比例变化至少10%,或者将另外的可聚合单体计量加入单体或单体 。

    Fiber-reinforced cycloolefin copolymer material, process for its
preparation and shaped articles from the material
    6.
    发明授权
    Fiber-reinforced cycloolefin copolymer material, process for its preparation and shaped articles from the material 失效
    纤维增强环烯烃共聚物材料,其制备方法和成型制品

    公开(公告)号:US5428098A

    公开(公告)日:1995-06-27

    申请号:US187224

    申请日:1994-01-27

    CPC分类号: C08F232/08 C08K7/14

    摘要: A fiber-reinforced cycloolefin polymer material comprises 1 to 99% by weight of reinforcing fibers, in particular glass fibers, and 99 to 1% by weight of a cycloolefin copolymer which is built up froma) at least one (polycyclo)olefin which is derived from norbornene, for example tetracyclododecene, and b) at least one olefin which is chosen from monocycloolefins having 4 to 12 C atoms (VII) and/or the group of acyclic olefins VIII ##STR1## in which R.sup.9, R.sup.10, R.sup.11 and R.sup.12 are identical or different and are a hydrogen atom or a C.sub.1 -C.sub.8 -alkyl radical. VII is preferably ethylene. The monomer units of the (polycyclo)olefin in the cycloolefin copolymer molecule are in each case separated by monomer units of the cyclic olefins VII and/or of the acyclic olefins of the formula VIII.

    摘要翻译: 纤维增强的环烯烃聚合物材料包含1至99重量%的增强纤维,特别是玻璃纤维,和99至1重量%的环烯烃共聚物,其由以下组成:a)至少一种(多环)烯烃,其是 衍生自降冰片烯,例如四环十二碳烯,和b)至少一种选自具有4-12个碳原子的单环烯烃(VII)和/或非环烯烃VIII(VIII)的烯烃,其中R 9,R 10, R 11和R 12相同或不同,为氢原子或C1-C8-烷基。 VII优选为乙烯。 在环烯烃共聚物分子中的(多环)烯烃的单体单元各自由环状烯烃VII和/或式VIII的无环烯烃的单体单元分离。

    Fibers made of cycloolefin copolymers
    10.
    发明授权
    Fibers made of cycloolefin copolymers 失效
    由环烯烃共聚物制成的纤维

    公开(公告)号:US06458919B1

    公开(公告)日:2002-10-01

    申请号:US08456373

    申请日:1995-06-01

    IPC分类号: C08F608

    CPC分类号: C08F232/08 C08F6/02 C08L45/00

    摘要: The present invention relates to a fiber which comprises at least one partly crystalline cycloolefin copolymer which can be prepared by polymerization of a symmetrical polycyclic olefin, an acyclic olefin and, if desired, a monocyclic olefin in the presence of a catalyst system comprising an aluminoxane and a metallocene compound of the formula

    摘要翻译: 本发明涉及一种纤维,其包含至少一种部分结晶的环烯烃共聚物,其可以通过对称多环烯烃,非环烯烃和如果需要的话,在包含铝氧烷的催化剂体系和 下式的金属茂化合物