公开(公告)号：US20090093597A1

公开(公告)日：2009-04-09

申请号：US12158722

申请日：2006-12-08

申请人： Cyril Aymonier ,  Francois Cansell ,  Stefan Mecking ,  Sandy Moisan ,  Victor Martinez

发明人： Cyril Aymonier ,  Francois Cansell ,  Stefan Mecking ,  Sandy Moisan ,  Victor Martinez

IPC分类号： C08L83/00 ,  C08G77/04

CPC分类号： B01J35/0013 ,  B01J23/44 ,  B01J23/50 ,  B01J31/04 ,  B01J31/064 ,  B01J31/068 ,  B01J31/4007 ,  B22F1/0014 ,  B22F1/0018 ,  B22F1/0059 ,  B22F9/26 ,  B22F2999/00 ,  B82Y30/00 ,  C08G83/002 ,  C08G83/005 ,  Y02P20/584 ,  B22F2201/013 ,  B22F2201/04

摘要： The invention relates to a method of preparing a particle-based composition, comprising: (i) bringing into contact a mixture comprising a dendritic structure and a metal compound precursor in a fluid, under temperature and pressure conditions such that the mixture is not soluble in the fluid; and (ii) chemically converting the metal compound precursor.

摘要翻译： 本发明涉及一种制备基于颗粒的组合物的方法，其包括：（i）在温度和压力条件下，在流体中使包含树枝状结构和金属化合物前体的混合物接触，使得所述混合物不溶于 流体; 和（ii）化学转化金属化合物前体。

公开(公告)号：US20100307648A1

公开(公告)日：2010-12-09

申请号：US12809315

申请日：2008-12-18

申请人： Christine Marraud ,  Samuel Marre ,  Francois Cansell ,  Cyril Aymonier

发明人： Christine Marraud ,  Samuel Marre ,  Francois Cansell ,  Cyril Aymonier

IPC分类号： C06B45/18 ,  B05D7/00 ,  C06B45/22

CPC分类号： C06B45/20 ,  C06B21/0083 ,  C06B23/005 ,  C06B23/009 ,  Y02P20/544

摘要： Subjects of the present invention are: a method of desensitizing crystals of an energetic explosive substance by coating them, said method comprising the deposition, carried out within a fluid, outside the normal temperature and pressure conditions, preferably under supercritical conditions, of a metal and/or polymer film, advantageously of a metal film or of a polymer film, on the surface of said crystals, the metal(s) and/or polymer(s) in question having been firstly dissolved in a solvent; the coated crystals of an energetic explosive substance obtainable by said method; and the energetic materials containing said crystals coated by said method and/or said crystals desensitized by said method.

摘要翻译： 本发明的主题是：通过涂布能量的爆炸性物质的晶体脱敏的方法，所述方法包括沉积，在常温常压和超压临界条件以外的流体内进行沉积，金属和 /或有利地为金属膜或聚合物膜的聚合物膜，在所述晶体的表面上，所述金属和/或聚合物首先溶解在溶剂中; 通过所述方法可获得的能量爆炸性物质的涂层晶体; 并且包含所述方法包被的所述晶体的能量物质和/或通过所述方法脱敏的所述晶体。

公开(公告)号：US20140051903A1

公开(公告)日：2014-02-20

申请号：US13979224

申请日：2012-01-09

申请人： Francois Cansell

发明人： Francois Cansell

IPC分类号： C02F1/72 ,  B01J19/24 ,  C02F11/06

CPC分类号： C02F1/72 ,  B01J19/2415 ,  C02F1/727 ,  C02F11/06 ,  C02F11/086 ,  C02F2101/30 ,  C02F2103/32 ,  C02F2103/34 ,  C02F2209/001 ,  C02F2209/05 ,  C02F2209/08 ,  C02F2209/29 ,  C02F2301/066 ,  C02F2303/08

摘要： The present invention relates to a process for hydrothermal oxidation of organic compounds, optionally with oxidizable inorganic compounds, contained in an aqueous effluent, wherein said aqueous effluent is injected within a tubular reactor wherein the effluent is brought to a supercritical pressure and wherein the temperature of the effluent is gradually increased from its initial temperature up to a supercritical temperature, without any intermediate decrease in temperature, by introducing within said tubular reactor a sufficient amount of oxidizing agent for totally oxidizing the organic compounds and optionally for at least partly oxidizing oxidizable inorganic compounds, the oxidizing agent being introduced in a fractionated way in several points increasingly located downstream, and wherein the composition and/or the concentration of the organic compounds and/or oxidizable organic compounds within the effluent to be treated varies over time, and, upstream from the tubular reactor wherein oxidation is carried out, the TOD of the effluent to be treated is measured and monitored at a value of more than 120 g/L and of less than 250 g/L prior to its injection into the tubular reactor.

摘要翻译： 本发明涉及包含在含水流出物中的任选含有可氧化的无机化合物的有机化合物的水热氧化方法，其中将所述含水流出物注入管式反应器中，其中流出物达到超临界压力，其中温度 通过在所述管式反应器内引入足够量的用于全部氧化有机化合物的氧化剂和任选地至少部分氧化可氧化的无机化合物的氧化剂，将流出物从其初始温度逐渐升高至超临界温度，而没有任何中间的温度降低 在多个位置逐渐位于下游的情况下以分级方式引入氧化剂，并且其中待处理流出物内的有机化合物和/或可氧化有机化合物的组成和/或浓度随时间变化，并且在上游 管状反应器 其中进行氧化，在注入到管式反应器中之前，测量和监测待处理流出物的TOD值，其值大于120g / L且小于250g / L。

公开(公告)号：US20080190866A1

公开(公告)日：2008-08-14

申请号：US11629659

申请日：2005-06-17

申请人： Francois Cansell ,  Marie Gaudre ,  Jean-Michel Tauzia

发明人： Francois Cansell ,  Marie Gaudre ,  Jean-Michel Tauzia

IPC分类号： C02F1/72

CPC分类号： C02F1/686 ,  C02F1/025 ,  C02F1/52 ,  C02F1/68 ,  C02F1/72 ,  C02F11/086 ,  C02F2101/163 ,  C02F2101/166 ,  C02F2103/16 ,  C02F2301/066 ,  Y10S210/903 ,  Y10S210/912 ,  Y10S210/913

摘要： The invention relates to a method for processing an aqueous effluent (E) containing in solution at least one type of metal (M) nitrite or nitrate whose oxide is stable in an aqueous medium consisting (I) in introducing cations NH4+ in aqueous solution, generally in the form of an aqueous ammonia solution, into the aqueous effluent and, subsequently (II) in processing the obtainable medium at a temperature ranging from 100 to 700° C. and a pressure of 1-50 MPa (i.e. from 10 to 500 bar), thereby converting the metal (M) nitrite or nitrate into metal (M) oxide, nitrogen and water.

摘要翻译： 本发明涉及一种处理在溶液中含有至少一种类型的金属（M）亚硝酸盐或硝酸盐的水性流出物（E）的方法，所述金属（M）亚硝酸盐或硝酸盐的氧化物在水介质中是稳定的，所述水性介质由（I）引入阳离子NH 4， 通常以氨水溶液的形式存在于水溶液中，然后（II）在100-700℃的温度和1- 50MPa（即10-500巴），从而将金属（M）亚硝酸盐或硝酸盐转化成氧化金属（M），氮和水。

公开(公告)号：US20060237352A1

公开(公告)日：2006-10-26

申请号：US11455177

申请日：2006-06-19

申请人： Francois Cansell ,  Manuel Bottreau

发明人： Francois Cansell ,  Manuel Bottreau

IPC分类号： C02F1/72

CPC分类号： C02F1/72 ,  C02F11/08 ,  C02F2303/16 ,  Y02E20/12

摘要： A method for starting up a system for oxidating organic bodies. The system includes a tubular body wherein an aqueous body is injected into the inlet thereof at a pressure P1, the tubular body having a first zone extending the inlet thereof, a second zone into which an oxidating compound can be injected into the output thereof. The inventive method includes the following steps: a first amount of thermal energy Q1 is provided in the first zone, the amount of thermal energy being able to raise the temperature of the liquid flowing through the tubular body from an initial temperature to a higher temperature T1; and a determined amount of a combustible mixture which can react at the intermediate temperature T1 in order to provide an amount of thermal energy Q2 bringing the temperature of the liquid to a reaction temperature T2 is injected.

摘要翻译： 一种启动有机物氧化体系的方法。 该系统包括管状体，其中水分体以压力P 1注入入口，管状体具有延伸入口的第一区域，可将氧化化合物注入其中的第二区域。 本发明的方法包括以下步骤：在第一区域中提供第一量的热能Q 1，热能量能够将流过管状体的液体的温度从初始温度升高到更高的温度 T 1; 并且注入确定量的可在中间温度T 1下反应的可燃混合物，以便提供使液体的温度达到反应温度T 2的一定量的热能Q 2。

公开(公告)号：US09073769B2

公开(公告)日：2015-07-07

申请号：US13979224

申请日：2012-01-09

申请人： Francois Cansell

发明人： Francois Cansell

IPC分类号： A62D3/38 ,  C02F1/72 ,  C02F11/08 ,  B01J19/24 ,  C02F11/06 ,  C02F101/30 ,  C02F103/32 ,  C02F103/34

CPC分类号： C02F1/72 ,  B01J19/2415 ,  C02F1/727 ,  C02F11/06 ,  C02F11/086 ,  C02F2101/30 ,  C02F2103/32 ,  C02F2103/34 ,  C02F2209/001 ,  C02F2209/05 ,  C02F2209/08 ,  C02F2209/29 ,  C02F2301/066 ,  C02F2303/08

摘要： Hydrothermal oxidation of organic compounds, optionally with oxidizable inorganic compounds, is contained in an aqueous effluent. The aqueous effluent is injected within a tubular reactor and brought to supercritical pressure, and temperature is increased to a supercritical temperature, without any intermediate decrease in temperature, by introducing sufficient amounts of oxidizing agent within the tubular for totally oxidizing the organic compounds, and optionally for partly oxidizing oxidizable inorganic compounds. The oxidizing agent is introduced in a fractionated way in several points increasingly located downstream, and the composition and/or the concentration of the organic compounds and/or oxidizable organic compounds within the effluent to be treated varies over time. Further, upstream from the tubular reactor where oxidation is carried out, the effluent's total chemical oxygen demand of the effluent to be treated is measured and monitored at more than 120 grams/liter (g/L) and less than 250 g/L prior to injecting the tubular reactor.

摘要翻译： 有机化合物（任选含有可氧化的无机化合物）的水热氧化被包含在含水流出物中。 将含水流出物注入管式反应器中并进入超临界压力，并通过在管内引入足够量的氧化剂来完全氧化有机化合物，并且任选地将温度升高至超临界温度，而不会中间降低温度 用于部分氧化可氧化的无机化合物。 氧化剂以逐渐位于下游的几个点以分级方式引入，待处理流出物中的有机化合物和/或可氧化有机化合物的组成和/或浓度随时间变化。 此外，在进行氧化的管式反应器的上游，在待处理的流出物的流出物的总化学需氧量以超过120克/升（g / L）和小于250g / L的速率被测量和监测，然后 注入管式反应器。

公开(公告)号：US07326337B2

公开(公告)日：2008-02-05

申请号：US11455177

申请日：2006-06-19

申请人： Francois Cansell ,  Manuel Bottreau

发明人： Francois Cansell ,  Manuel Bottreau

IPC分类号： C02F1/72

CPC分类号： C02F1/72 ,  C02F11/08 ,  C02F2303/16 ,  Y02E20/12

摘要： A method for starting up a system for oxidating organic bodies. The system includes a tubular body wherein an aqueous body is injected into the inlet thereof at a pressure P1, the tubular body having a first zone extending the inlet thereof, a second zone into which an oxidating compound can be injected into the output thereof. The inventive method includes the following steps: a first amount of thermal energy Q1 is provided in the first zone, the amount of thermal energy being able to raise the temperature of the liquid flowing through the tubular body from an initial temperature to a higher temperature T1; and a determined amount of a combustible mixture which can react at the intermediate temperature T1 in order to provide an amount of thermal energy Q2 bringing the temperature of the liquid to a reaction temperature T2 is injected.

摘要翻译： 一种启动有机物氧化体系的方法。 该系统包括管状体，其中水分体以压力P 1注入入口，管状体具有延伸入口的第一区域，可将氧化化合物注入其中的第二区域。 本发明的方法包括以下步骤：在第一区域中提供第一量的热能Q 1，热能量能够将流过管状体的液体的温度从初始温度升高到更高的温度 T 1; 并且注入确定量的可在中间温度T 1下反应的可燃混合物，以便提供使液体的温度达到反应温度T 2的一定量的热能Q 2。