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1.发明申请公开(公告)号：US20150011687A1
公开(公告)日：2015-01-08
申请号：US14374318
申请日：2013-02-08
IPC分类号： C08K5/3437 , C08K5/053 , C08K3/04 , C08K5/06 , C08K5/23 , C08K5/3417
CPC分类号： C08K5/3437 , C08K3/04 , C08K5/053 , C08K5/06 , C08K5/23 , C08K5/3417 , C09B67/0013 , C09B67/0033 , C09B67/0041 , C09B67/009 , C09D11/106 , C09D11/107 , C09D11/326
摘要： The present invention is an aqueous pigment dispersion liquid for inkjet comprising a pigment and a pigment dispersant. The pigment dispersant is at least any one of a graft copolymer and a block copolymer each comprising a polymer chain A and a polymer chain B, wherein the polymer chain A comprises 20 to 60 mass % of a constituent unit derived from a first cycloalkyl group-containing (meth)acrylate, 10 to 35 mass % of a constituent unit derived from (meth)acrylic acid, and 5 to 70 mass % of a constituent unit derived from another (meth)acrylate and the polymer chain B comprises at least any one of a constituent unit derived from a second cycloalkyl group-containing (meth)acrylate and a constituent unit derived from a vinyl monomer or (meth)acrylate having an aromatic ring.
摘要翻译： 本发明是一种用于喷墨的水性颜料分散液，其包含颜料和颜料分散剂。 颜料分散剂是接枝共聚物和嵌段共聚物中的至少任一种，各自包含聚合物链A和聚合物链B，其中聚合物链A包含20至60质量％的衍生自第一环烷基 - 含有（甲基）丙烯酸酯的10〜35质量％的衍生自（甲基）丙烯酸的结构单元和5〜70质量％的来源于其它（甲基）丙烯酸酯的构成单元，所述聚合物链B包含至少任意一种 衍生自含有第二环烷基的（甲基）丙烯酸酯的结构单元和衍生自乙烯基单体或具有芳环的（甲基）丙烯酸酯的结构单元。
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公开(公告)号：US11746247B2
公开(公告)日：2023-09-05
申请号：US17438812
申请日：2020-03-17
发明人： Yosuke Sakai , Misaki Narita , Yasuhiro Yoshida , Shinichiro Aoyagi , Yoshikazu Murakami , Hiroyuki Shimanaka
IPC分类号： C09D17/00 , C08F220/18 , C08F220/14 , C08F220/34 , C08F226/06 , C08K5/00 , C09B67/46 , C08G65/08 , C08G65/333 , G03G9/08
CPC分类号： C09D17/001 , C08F220/14 , C08F220/1804 , C08F220/1807 , C08F220/34 , C08F226/06 , C08G65/08 , C08G65/33303 , C08K5/0041 , C09B67/009 , C09D17/003 , G03G9/0806 , C08K2201/003
摘要： The present invention provides an aqueous pigment dispersion liquid being such that a pigment is finely dispersed, and the viscosity, and the particle diameters of the pigment are unlikely to fluctuate, being excellent in storage stability, and enabling preparation of an emulsion-polymerized toner having properly controlled particle diameters while improving the pigment utilization rate. The aqueous pigment dispersion liquid is an aqueous pigment dispersion liquid for an emulsion-polymerized toner containing a pigment, a dispersant, and an aqueous medium. The dispersant is a polymer containing a constitutional unit (A) derived from a monomer (A) such that a group containing a (meth)acryloyloxy group or the like is bonded to one end of a particular polyethylene glycol chain or the like, and a constitutional unit (B) derived from a monomer (B) having a carboxy group or the like, the polymer has a number average molecular weight in terms of polystyrene of 4,000 to 15,000, as measured by gel permeation chromatography, the polymer is contained in a state of being not ionized substantially, and the aqueous pigment dispersion liquid has a pH of 3.0 to 8.4.
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3.发明授权公开(公告)号：US09260589B2
公开(公告)日：2016-02-16
申请号：US14374318
申请日：2013-02-08
IPC分类号： C09D11/10 , C08K5/3437 , C09B67/08 , C09B67/46 , C09D11/106 , C09D11/107 , C09D11/326 , C08K3/04 , C08K5/053 , C08K5/06 , C08K5/23 , C08K5/3417 , C09B67/22
CPC分类号： C08K5/3437 , C08K3/04 , C08K5/053 , C08K5/06 , C08K5/23 , C08K5/3417 , C09B67/0013 , C09B67/0033 , C09B67/0041 , C09B67/009 , C09D11/106 , C09D11/107 , C09D11/326
摘要： The present invention is an aqueous pigment dispersion liquid for inkjet comprising a pigment and a pigment dispersant. The pigment dispersant is at least any one of a graft copolymer and a block copolymer each comprising a polymer chain A and a polymer chain B, wherein the polymer chain A comprises 20 to 60 mass % of a constituent unit derived from a first cycloalkyl group-containing (meth)acrylate, 10 to 35 mass % of a constituent unit derived from (meth)acrylic acid, and 5 to 70 mass % of a constituent unit derived from another (meth)acrylate and the polymer chain B comprises at least any one of a constituent unit derived from a second cycloalkyl group-containing (meth)acrylate and a constituent unit derived from a vinyl monomer or (meth)acrylate having an aromatic ring.
摘要翻译： 本发明是一种用于喷墨的水性颜料分散液，其包含颜料和颜料分散剂。 颜料分散剂是接枝共聚物和嵌段共聚物中的至少任一种，各自包含聚合物链A和聚合物链B，其中聚合物链A包含20至60质量％的衍生自第一环烷基 - 含有（甲基）丙烯酸酯的10〜35质量％的衍生自（甲基）丙烯酸的结构单元和5〜70质量％的来源于其它（甲基）丙烯酸酯的构成单元，所述聚合物链B包含至少任意一种 衍生自含有第二环烷基的（甲基）丙烯酸酯的结构单元和衍生自乙烯基单体或具有芳环的（甲基）丙烯酸酯的结构单元。
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公开(公告)号：US09644106B2
公开(公告)日：2017-05-09
申请号：US14781217
申请日：2014-04-17
发明人： Hiroyuki Shimanaka , Yoshikazu Murakami , Shinichiro Aoyagi , Sachio Yoshikawa , Mitsuo Yamazaki
IPC分类号： C08L53/00 , C09J7/02 , A61K9/16 , C04B35/634 , C08L33/06 , C09D11/00 , C09D11/328 , C09D17/00 , C08L33/08 , C08F293/00 , C09D153/00 , C09D11/106 , C09D11/107 , C09D11/32 , C09B67/46 , C08K5/23 , C08K5/3417 , C08K5/3437 , C09D11/322 , C09D11/324
CPC分类号： C09D11/328 , C08F293/005 , C08K5/23 , C08K5/3417 , C08K5/3437 , C08L33/08 , C08L53/00 , C09B67/009 , C09D11/106 , C09D11/107 , C09D11/32 , C09D11/322 , C09D11/324 , C09D17/00 , C09D153/00 , C08F2220/185 , C08F220/20 , C08F220/06 , C08F2220/1841 , C08F220/14 , C08F2220/1825 , C08F212/08
摘要： A novel aqueous emulsion solution is provided that can be used as a binder for forming a coating film suitable for an inkjet printing system. The present invention is an aqueous emulsion solution containing a polymer I and a polymer II mixed together therein, wherein the polymer I is an A-B block copolymer formed from 90 mass % or more of a methacrylate-based monomer, the A-B block copolymer neutralized with an alkali, a polymer block A is substantially water-insoluble and has a number average molecular weight of 1000 to 10000 and a polydispersity index of 1.5 or less, a polymer block B is synthesized using a monomer containing at least a methacrylic acid and has an acid value of 30 to 250 mgKOH/g, the A-B block copolymer has a number average molecular weight of 5000 to 20000, a content of the polymer block A of 5 to 60% in the A-B block copolymer, and a polydispersity index as a whole of 1.6 or less, the polymer II is a polymer obtained by polymerizing a hydrophobic addition polymerizable monomer and having a glass transition temperature of 70° C. or lower, and further the mass ratio of the polymer I and the polymer II is 5 to 80:95 to 20.
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公开(公告)号：US10982020B2
公开(公告)日：2021-04-20
申请号：US15313179
申请日：2014-06-25
发明人： Hiroyuki Shimanaka , Yoichi Tagi , Yoshikazu Murakami , Shinichiro Aoyagi , Kazutaka Arai , Sachio Yoshikawa
IPC分类号： C08F8/36 , C08F293/00 , C08F8/34 , C09D17/00 , C08F8/44 , C09D11/107 , C08L71/00 , C08F2/06 , C09C3/10 , C09D11/10 , C09D11/326 , C08F8/42 , C09B69/10
摘要： There is provided a resin-treated pigment that is useful as a coloring agent for color filters or inkjet inks, that can expand a hue range and improve performances such as color density, color developability, and transparency, and that is excellent in properties such as dispersibility and dispersion stability of pigments, re-dissolvability, and alkali-solubility. An A-B block copolymer 90% by mass or more of which is constituted by a methacrylate-based monomer or methacrylate-based monomers, in which the block A has a carboxy group-containing methacrylate as a constituent, and the block B has an ionic bond moiety represented by formula (1) as a constitutional unit, the ionic bond moiety containing a methacrylate, and an organic coloring matter having one or more sulfonate ions each being bonded thereto and each being a counter ion of a nitrogen cation of a quaternary ammonium salt.
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