Abstract:
A battery structure includes a plurality of batteries each made of lithium-ion secondary battery; and a plurality of arrangement portions in which the plurality of batteries are arranged. The plurality of arrangement portions are divided into two groups of: a upper heat transfer group having heat transfer orders higher than a center value of the heat transfer orders, where the heat transfer orders are respective amount of heat transfer from the batteries being ranked in descending order; and a lower heat transfer group having the heat transfer orders lower than the center value. A battery among the plurality of batteries showing the highest value of a lithium deposition tolerance which represents a degree of lithium being unlikely to deposit during charge/discharge operation, is disposed in a high tolerance arrangement portion in the plurality of arrangement portions, the high tolerance arrangement portion belonging to the upper heat transfer group.
Abstract:
A positive-electrode active material for a non-aqueous electrolyte rechargeable battery includes a core portion and a shell portion. The core portion contains an inorganic oxide with a polyanionic structure. The shell portion coats the core portion. The shell portion contains a carbon and an inorganic accelerator that accelerates generation of the shell portion by the carbon. The content of the inorganic accelerator is 0.2 mass % or more of the inorganic oxide when the mass of the inorganic oxide is defined as 100%.
Abstract:
An electrode includes an electrode material, which includes: a core part made of an active substance having a polyanion structure having Mn; and a shell part obtained by covering a surface of the core part with carbon. In addition, an amount of water, as measured by Karl Fischer's method when the electrode is held at 250° C. for 40 minutes after adsorbed water is volatilized by heating, is 1500 ppm or less.
Abstract:
An electrode includes an electrode material, which includes: a core part made of an active substance having a polyanion structure having Mn; and a shell part obtained by covering a surface of the core part with carbon. In addition, an amount of water, as measured by Karl Fischer's method when the electrode is held at 250° C. for 40 minutes after adsorbed water is volatilized by heating, is 1500 ppm or less.
Abstract:
A method for producing an alkali-metal-including active material by pre-doping an active material with an alkali metal ion includes: mixing the alkali metal, an organic solvent with which the alkali metal is solvated, and a ligand having an electrophilic substitution reactivity to produce an alkali metal complex; and contacting and reacting the alkali metal complex and the active material with each other to pre-dope the active material with the alkali metal ion.
Abstract:
A positive-electrode active material for a non-aqueous electrolyte rechargeable battery includes a core portion and a shell portion. The core portion includes at least one of an inorganic oxide having a polyanionic structure and an inorganic compound oxide having a polyanionic structure and including a carbon. The shell portion includes a carbon and covers the core portion. The positive-electrode active material has a property that indicates a continuous pore distribution curve in a graph where a horizontal axis represents a pore diameter and a vertical axis represents a log differentiation pore volume. The positive-electrode active material is manufactured by wet-cracking the inorganic oxide or the inorganic compound oxide with an organic acid solution, and sintering a cracked substance in an inert atmosphere.
Abstract:
An electrode active material for a nonaqueous electrolyte secondary battery includes: a core part including at least one of an inorganic oxide and a carbon-composite inorganic composite oxide; and a shell part for carbon coating on the core part. The electrode active material has a specific surface area of 6.0 m2/g or more. The electrode active material has a moisture content of 400 ppm or less, which is measured by a Karl Fischer method such that the electrode active material is heated in a heat-evaporating manner, and continuously maintained at 250° C. for 40 minutes without exposing to an atmosphere after the electrode active material is exposed to the atmosphere to absorb moisture to be saturated.
Abstract:
An assembled battery includes a plurality of secondary cells, a first arithmetic operator, a second arithmetic operator, and a discharger. The first arithmetic operator calculates a voltage change rate of each of the secondary cells during charging/discharging thereof. The second arithmetic operator determines a discharge condition for each of the secondary cells from the voltage change rate calculated in the first arithmetic operator and a state of charge of each of the secondary cells. The discharger performs discharging of each of the secondary cells on the basis of the discharge condition when the assembled battery is neither being charged nor being discharged. The second arithmetic operator determines the discharge condition of each of the secondary cells such that each of the secondary cells after the discharging has the same state of charge.