公开(公告)号：US20180237645A1

公开(公告)日：2018-08-23

申请号：US15752746

申请日：2016-09-01

Applicant: DIC Corporation

Inventor： Hiroshi Tsutsumi ,  Akinori Takahashi ,  Hiroaki Nakano ,  Takayuki Odashima ,  Ichiro Azuma

IPC: C09D7/63 ,  C09D11/106 ,  C09D201/06 ,  C08K5/3465 ,  C08K5/098

Abstract: To provide a curing accelerator for an oxidatively polymerizable unsaturated resin which can decrease the amount of cobalt metal soap used and has curing performance equal to or higher than excellent curing performance of the cobalt metal soap, and a printing ink and a coating material using the same. A curing accelerator for an oxidatively polymerizable unsaturated resin including a manganese or cobalt complex (α) containing quinolinol compound ions represented by Structural Formula (1) as a ligand, and a printing ink and a coating material including the curing accelerator. In the formula, R1 is any of a hydrogen atom, a hydrocarbon group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a hydroxyl group, an amino group, a nitro group, a nitroso group, a sulfo group, and a halogen atom, and n is an integer of 1 to 6.

公开(公告)号：US20170260357A1

公开(公告)日：2017-09-14

申请号：US15507834

申请日：2015-09-09

Applicant: DIC Corporation ,  National University Corporation, Iwate University

Inventor： Shujiro Otsuki ,  Takayuki Odashima ,  Hidetoshi Hirahara

IPC: C08K5/098 ,  B60C9/00 ,  C07C53/128 ,  B60C1/00

Abstract: A rubber-metal adhesion promoter characterized by including a compound (1) represented by the following general formula (A): (in the formula, Z represents a structure selected from the following formulae (z-1) to (z-4); M represents titanium or zirconium; and (RCOO) represents a residue of an aliphatic carboxylic acid having 2 to 25 carbon atoms)

公开(公告)号：US20230019574A1

公开(公告)日：2023-01-19

申请号：US17955678

申请日：2022-09-29

Applicant: DIC Corporation

Inventor： Akinori Takahashi ,  Takayuki Odashima

IPC: C08L57/00 ,  C09D7/63 ,  C08K5/098 ,  C08K5/3445 ,  C08L87/00 ,  C09D11/03 ,  C09F9/00

Abstract: Provided are a curing accelerator for an oxidative polymerization type unsaturated resin having a high curing accelerating ability, and a printing ink and a coating material each including the curing accelerator for an oxidative polymerization type unsaturated resin. Specifically, there are provided a curing accelerator for an oxidative polymerization type unsaturated resin containing a metal salt (A) and an imidazole compound (B), a curing accelerator for an oxidative polymerization type unsaturated resin containing a metal salt (A), a ligand compound (C) and an imidazole compound (B), a curing accelerator for an oxidative polymerization type unsaturated resin containing a metal complex (D) and an imidazole compound (B), and a printing ink and a coating material using the curing accelerator for an oxidative polymerization type unsaturated resin.

公开(公告)号：US10738203B2

公开(公告)日：2020-08-11

申请号：US15752746

申请日：2016-09-01

Applicant: DIC Corporation

Inventor： Hiroshi Tsutsumi ,  Akinori Takahashi ,  Hiroaki Nakano ,  Takayuki Odashima ,  Ichiro Azuma

IPC: C09D7/63 ,  C09D201/02 ,  C09D11/105 ,  C09D11/03 ,  C09D11/106 ,  C09D201/06 ,  C08K5/00 ,  C08F4/70 ,  C08K5/098 ,  C08K5/3465

Abstract: To provide a curing accelerator for an oxidatively polymerizable unsaturated resin which can decrease the amount of cobalt metal soap used and has curing performance equal to or higher than excellent curing performance of the cobalt metal soap, and a printing ink and a coating material using the same. A curing accelerator for an oxidatively polymerizable unsaturated resin including a manganese or cobalt complex (α) containing quinolinol compound ions represented by Structural Formula (1) as a ligand, and a printing ink and a coating material including the curing accelerator. In the formula, R1 is any of a hydrogen atom, a hydrocarbon group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a hydroxyl group, an amino group, a nitro group, a nitroso group, a sulfo group, and a halogen atom, and n is an integer of 1 to 6.

公开(公告)号：US11053372B2

公开(公告)日：2021-07-06

申请号：US16614915

申请日：2018-05-15

Applicant: DIC Corporation

Inventor： Akinori Takahashi ,  Takayuki Odashima

IPC: C07D213/46 ,  C07D215/14 ,  C08K5/3465 ,  C09D7/63 ,  C09D11/03 ,  C09D201/00 ,  C07D213/55

Abstract: Provided are a curing accelerator for an oxidative polymerization type unsaturated resin having a high curing accelerating ability, and a printing ink and a coating material. Specifically, there are provided a curing accelerator for an oxidative polymerization type unsaturated resin, containing a metal complex (β) having an anion compound (α) represented by the following structural formula (1-1) or (1-2) as a ligand: wherein R1 is any one of a hydroxyl group, an amino group, a nitro group, a nitroso group, a sulfo group, a halogen atom, a hydrocarbon group which may have a substituent, a hydrocarbon oxy group which may have a substituent, and a hydrocarbon oxycarbonyl group which may have a substituent, m is 0 or an integer of 1 to 3, n is 0 or an integer of 1 to 6, and X is any one of a carboxylate group, a hydrogen atom, and the R1 group.

公开(公告)号：US20170253722A1

公开(公告)日：2017-09-07

申请号：US15507848

申请日：2015-09-09

Applicant: DIC Corporation ,  National University Corporation, Iwate University

Inventor： Shujiro Otsuki ,  Takayuki Odashima ,  Hidetoshi Hirahara

IPC: C08K5/098 ,  C07C53/128 ,  C07C53/124 ,  B60C1/00 ,  B60C9/00

CPC classification number: C08K5/098 ,  B60C1/00 ,  B60C9/0007 ,  C07C53/124 ,  C07C53/128 ,  C08K5/52 ,  C08K5/55 ,  C08L21/00

Abstract: A rubber-metal adhesion promoter characterized by including: a metal salt (1) of a carboxylic acid which is a metal salt of an aliphatic carboxylic acid having 2 to 25 carbon atoms and in which the metal is bismuth, copper, antimony, silver or niobium; or a compound (2) represented by the following general formula (A): [wherein Z represents a structure selected from the following formulae (z-1) to (z-4); M represents bismuth, copper, antimony, silver or niobium; (RCOO) represents a residue of an aliphatic carboxylic acid having 2 to 25 carbon atoms; and x represents the valence of M minus 1].

公开(公告)号：US11427698B2

公开(公告)日：2022-08-30

申请号：US16549201

申请日：2019-08-23

Applicant: DIC Corporation ,  National University Corporation, Iwate University

Inventor： Shujiro Otsuki ,  Takayuki Odashima ,  Hidetoshi Hirahara

IPC: C08K5/098 ,  C08K5/52 ,  C08K5/55 ,  B60C1/00 ,  B60C9/00 ,  C07C53/124 ,  C07C53/128

Abstract: A rubber-metal adhesion promoter characterized by including: a metal salt (1) of a carboxylic acid which is a metal salt of an aliphatic carboxylic acid having 2 to 25 carbon atoms and in which the metal is bismuth, copper, antimony, silver or niobium; or a compound (2) represented by the following general formula (A): [wherein Z represents a structure selected from the following formulae (z-1) to (z-4); M represents bismuth, copper, antimony, silver or niobium; (RCOO) represents a residue of an aliphatic carboxylic acid having 2 to 25 carbon atoms; and x represents the valence of M minus 1].

公开(公告)号：US10450439B2

公开(公告)日：2019-10-22

申请号：US15507834

申请日：2015-09-09

Applicant: DIC Corporation ,  National University Corporation, Iwate University

Inventor： Shujiro Otsuki ,  Takayuki Odashima ,  Hidetoshi Hirahara

IPC: C08K5/098 ,  B60C1/00 ,  C08K5/52 ,  C08K5/55 ,  C08L21/00 ,  B60C9/00 ,  C07C53/128

Abstract: A rubber-metal adhesion promoter characterized by including a compound (1) represented by the following general formula (A): (in the formula, Z represents a structure selected from the following formulae (z-1) to (z-4); M represents titanium or zirconium; and (RCOO) represents a residue of an aliphatic carboxylic acid having 2 to 25 carbon atoms)