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公开(公告)号：US11542344B2
公开(公告)日：2023-01-03
申请号：US17057766
申请日：2019-05-29
摘要： The heterogeneous procatalyst of this disclosure includes a titanium species; a hydrocarbon soluble transition metal compound having a structure M(OR1)z; a chlorinating agent having a structure A(Cl)x(R2)3-x, and a magnesium chloride component. M of M(OR1)z is a non-reducing transition metal other than titanium, the non-reducing transition metal being in an oxidation state of +2 or +3. Each R1 is independently (C1-C30)hydrocarbyl or —C(O)R11, where R11 is (C1-C30)hydrocarbyl. Subscript z of M(OR1)z is 2 or 3. Each R1 and R11 may be optionally substituted with one or more than one halogen atoms, or one or more than one —Si(RS)3, where each RS is (C1-C30)hydrocarbyl. A of A(Cl)x(R2)3-x is aluminum or boron; R2 is (C1-C30)hydrocarbyl; and x is 1, 2, or 3; and a magnesium chloride component.
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公开(公告)号：US09512049B2
公开(公告)日：2016-12-06
申请号：US14367542
申请日：2012-12-21
发明人： Max Markus Tirtowidjojo , Brien A. Stears , William J. Kruper, Jr. , Kurt F. Hirsekorn , Debashis Chakraborty
IPC分类号： C07C2/86
CPC分类号： C07C2/861 , C07C2531/02 , C07C11/06 , C07C11/173
摘要： Processes for the production of alkenes are provided. The processes make use of methane as a low cost starting material.
摘要翻译： 提供了生产烯烃的方法。 这些方法使用甲烷作为低成本起始材料。
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公开(公告)号：US09451707B2
公开(公告)日：2016-09-20
申请号：US13712997
申请日：2012-12-13
发明人： Kurt F. Hirsekorn
CPC分类号： H05K3/181 , C23C18/1653 , C23C18/1893 , C23C18/2086 , C23C18/30 , H05K1/0346 , H05K3/387 , H05K2201/0215 , H05K2203/0709
摘要： Zero-valent silver compositions include 4-dimethylaminopyridine as stabilizers. The zero-valent silver and the 4-diemthylaminopyridine form stabilized nano-particles in solution. The zero-valent silver compositions may be used as catalysts in the metallization of non-conductive substrates.
摘要翻译： 零价银组合物包括4-二甲基氨基吡啶作为稳定剂。 零价银和4-二乙氨基吡啶在溶液中形成稳定的纳米颗粒。 零价银组合物可用作非导电衬底的金属化中的催化剂。
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公开(公告)号：US11857935B2
公开(公告)日：2024-01-02
申请号：US17056534
申请日：2019-05-23
发明人： Mingzhe Yu , David Gordon Barton , Kurt F. Hirsekorn , Sadeka Onam , Peter N. Nickias , Andrew T. Heitsch , Thomas H. Peterson
IPC分类号： C08F4/646 , C08F4/657 , B01J3/00 , B01J21/06 , B01J20/04 , B01J31/14 , B01J35/10 , C08F2/06 , C08F4/02 , C08F210/16 , C08F4/685
CPC分类号： B01J21/063 , B01J20/046 , B01J31/143 , B01J35/1019 , C08F2/06 , C08F4/022 , C08F4/6576 , C08F4/6574 , C08F4/685 , C08F210/16 , C08F2410/03
摘要： A heterogeneous procatalyst includes a titanium species, a magnesium chloride component, and a chlorinating agent having a structure A(Cl)x(R1)3-x, where A is aluminum or boron, R1 is a (C1-C30) hydrocarbyl, and x is 1, 2, or 3. The magnesium chloride component may be thermally treated at a temperature greater than 100 C for at least 30 minutes before or after introduction of the chlorinating agent and titanium species to the heterogeneous procatalyst. The heterogeneous procatalyst having the thermally treated magnesium chloride exhibits improved average molecular weight capability. Processes for producing the heterogeneous procatalyst and processes for producing ethylene-based polymers utilizing the heterogeneous procatalyst are also disclosed.
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公开(公告)号：US20210205786A1
公开(公告)日：2021-07-08
申请号：US17057774
申请日：2019-05-29
发明人： Linfeng Chen , Kurt F. Hirsekorn , Mehmet Demirors
摘要： A procatalyst including a preformed magnesium chloride catalyst support having a surface area of greater than or equal to 100 m2/g, a titanium containing component, a chlorinating agent, and a hydrocarbon soluble transition metal compound having an oxidation state of greater than or equal to 5+. The hydrocarbon soluble transition metal compound having an oxidation state of greater than or equal to 5+ is not vanadium.
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公开(公告)号：US20230235156A1
公开(公告)日：2023-07-27
申请号：US18007814
申请日：2021-06-04
发明人： Alexander Williamson , Shadid Askar , Joel D. Wieliczko , Cornelis F.J. Den Doelder , Mridula Kapur , Kurt F. Hirsekorn , Evelyn Auyeung , Bo Liu , Maria C. Zandueta , John P. O'Brien , Stephanie M. Whited
CPC分类号： C08L23/0815 , C08L23/06 , C08L2205/025 , C08L2314/02
摘要： Embodiments are directed towards polyolefin compositions including a high molecular weight polyolefin and a low molecular weight polyolefin.
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公开(公告)号：US20220389137A1
公开(公告)日：2022-12-08
申请号：US17630798
申请日：2020-07-30
IPC分类号： C08F210/16
摘要： The catalyst system includes a heterogeneous procatalyst, an electron donor, and a hydrogenation procatalyst. The heterogeneous procatalyst includes a titanium species, an aluminum species, and a magnesium chloride component. The hydrogenation procatalyst has the formula Cp2TiXnTiCp2 or Cp2TiXn. In formula Cp2TiXn, each Cp is a cyclopentadienyl substituted with at least one R1, wherein R1 is (C1-C10)alkyl; and each X is independently monoanionic or neutral, wherein each X is independently (C1-C40)hydrocarbon, (C1-C40)heterohydrocarbon, (C1-C40)hydrocarbyl, (C1—C40)heterohydrocarbyl, or a halogen atom.
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公开(公告)号：US20220275114A1
公开(公告)日：2022-09-01
申请号：US17630791
申请日：2020-07-28
IPC分类号： C08F4/6592 , C08F4/659 , C08F4/655 , C08F2/04
摘要： The catalyst system includes a heterogeneous procatalyst and a hydrogenation procatalyst. The heterogeneous procatalyst includes a titanium species, an aluminum species, and a magnesium chloride component. The hydrogenation procatalyst has the formula Cp2TiX2, In formula Cp2TiX2, each Cp is a cyclopentadienyl substituted with at least one R1, wherein R1 is (C1-C10)alkyl; and each X is independently a halogen atom.
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公开(公告)号：US20220220292A1
公开(公告)日：2022-07-14
申请号：US17615352
申请日：2020-05-29
发明人： Teresa P. Karjala , Kurt F. Hirsekorn , Marlos Giuntini de Oliveira , Gregory J. Brennan , Elva L. Lugo , Yongchao Zeng , Brayden E. Glad , Jon W. Hobson , Linfeng Chen
IPC分类号： C08L23/08 , C08F210/02 , C08J5/18 , C08L23/06
摘要： Embodiments of the present disclosure are specifically related to LLDPE compositions produced from heterogeneous procatalyst compositions and blown and cast films incorporating these LLDPE compositions.
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10.发明授权公开(公告)号：US11939417B2
公开(公告)日：2024-03-26
申请号：US17056473
申请日：2019-05-29
发明人： Linfeng Chen , Mingzhe Yu , Mehmet Demirors , Andrew T. Heitsch , Jeffrey A. Sims , David Gordon Barton , Kurt F. Hirsekorn , Peter N. Nickias
CPC分类号： C08F4/6557 , C08F2/06 , C08F4/685 , C08F10/02
摘要： A heterogeneous procatalyst includes a preformed heterogeneous procatalyst and a metal-ligand complex. The preformed heterogeneous procatalyst includes a titanium species and a magnesium chloride (MgCl2) support. The metal-ligand complex has a structural formula (L)aM(Y)m(XR2)b, where M is a metal cation; each L is a neutral ligand or (═O); each Y is a halide or (C1-C20)alkyl; each XR2 is an anionic ligand in which X is a heteroatom or a heteroatom-containing functional group and R2 is (C1-C20)hydrocarbyl or (C1-C20) heterohydrocarbyl; n is 0, 1, or 2; m is 0-4; and b is 1-6. The metal-ligand complex is overall charge neutral. The heterogeneous procatalyst exhibits improved average molecular weight capability. A catalyst system includes the heterogeneous procatalyst and a cocatalyst. Processes for producing the heterogeneous procatalyst and processes for producing ethylene-based polymers utilizing the heterogeneous procatalyst are also disclosed.
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