公开(公告)号：US20170240499A1

公开(公告)日：2017-08-24

申请号：US15515069

申请日：2015-10-08

Applicant: Dow Global Technologies LLC

Inventor： Patrick S. Hanley ,  Jossian Oppenheimer ,  Matthias S. Ober ,  William J. Kruper, Jr. ,  Arkady L. Krasovskiy

IPC: C07C67/343 ,  C07D317/60 ,  C07C2/86 ,  C07C67/31 ,  C07C41/30 ,  C07D213/55 ,  C07C231/12

CPC classification number: C07C67/343 ,  C07C2/868 ,  C07C41/30 ,  C07C67/31 ,  C07C231/12 ,  C07C2531/20 ,  C07C2531/22 ,  C07C2531/24 ,  C07D213/55 ,  C07D317/60 ,  C07C69/734 ,  C07C69/65 ,  C07C69/618 ,  C07C69/76 ,  C07C15/52 ,  C07C15/50 ,  C07C43/215 ,  C07C233/65

Abstract: The present disclosure describes a method of coupling a first compound to a second compound, the method comprising: providing the first compound having a fluorosulfonate substituent; providing the second compound comprising an alkene; and reacting the first compound and the second compound in a reaction mixture, the reaction mixture including a catalyst having at least one group 10 atom, the reaction mixture under conditions effective to couple the first compound to the second compound.

公开(公告)号：US08926918B2

公开(公告)日：2015-01-06

申请号：US14024023

申请日：2013-09-11

Applicant: Dow Global Technologies LLC

Inventor： Max Markus Tirtowidjojo ,  Hua Bai ,  Debashis Chakraborty ,  Juergen Eiffler ,  Heinz Groenewald ,  Kurt Frederick Hirsekorn ,  Manfred Kokott ,  William J. Kruper, Jr. ,  Thomas Ulrich Luebbe ,  Avani Maulik Patel ,  Shirley Shaw Sexton ,  Peter Wenzel ,  Marcus Wobser

IPC: B01J19/24 ,  B01J8/06 ,  F28D7/00 ,  F28D7/16 ,  F27B15/14 ,  B01J19/00 ,  C07C17/20 ,  C07C17/269

CPC classification number: B01J19/2425 ,  B01J19/0026 ,  B01J19/006 ,  B01J19/2405 ,  B01J2219/00063 ,  B01J2219/00081 ,  B01J2219/00159 ,  B01J2219/00162 ,  B01J2219/00166 ,  B01J2219/00247 ,  B01J2219/0227 ,  C07C17/206 ,  C07C17/269 ,  C07C21/18 ,  C07C21/04

Abstract: The present invention provides isothermal multitube reactors suitable for the production of chlorinated and/or fluorinated propene and higher alkenes from the reaction of chlorinated and/or fluorinated alkanes and chlorinated and/or fluorinated alkenes. The reactors utilize a feed mixture inlet temperature at least 20° C. different from a desired reaction temperature.

Abstract translation: 本发明提供了适于从氯化和/或氟化烷烃和氯化和/或氟化烯烃的反应生产氯化和/或氟化丙烯和更高级烯烃的等温多管反应器。 反应器利用不同于所需反应温度的进料混合物入口温度至少20℃。

公开(公告)号：US10125082B2

公开(公告)日：2018-11-13

申请号：US15515069

申请日：2015-10-08

Applicant: Dow Global Technologies LLC

Inventor： Patrick S. Hanley ,  Jossian Oppenheimer ,  Matthias S. Ober ,  William J. Kruper, Jr. ,  Arkady L. Krasovskiy

IPC: C07C67/343 ,  C07C41/30 ,  C07C231/12 ,  C07D213/55 ,  C07C2/86 ,  C07D317/60 ,  C07C67/31

Abstract: The present disclosure describes a method of coupling a first compound to a second compound, the method comprising: providing the first compound having a fluorosulfonate substituent; providing the second compound comprising an alkene; and reacting the first compound and the second compound in a reaction mixture, the reaction mixture including a catalyst having at least one group 10 atom, the reaction mixture under conditions effective to couple the first compound to the second compound.

公开(公告)号：US20170174582A1

公开(公告)日：2017-06-22

申请号：US15129282

申请日：2015-03-27

Applicant: Dow Global Technologies LLC ,  Dow AgroSciences LLC

Inventor： Patrick S. Hanley ,  Gregory T. Whiteker ,  Matthias S. Ober ,  William J. Kruper, Jr. ,  Arkady L. Krasovskiy

IPC: C07C1/32 ,  C07B37/04 ,  C07D213/16 ,  C07C22/04 ,  C07C233/00 ,  C07C211/45 ,  C07C22/08 ,  C07C15/14 ,  C07D263/54

CPC classification number: C07C1/322 ,  C07B37/04 ,  C07C1/321 ,  C07C15/14 ,  C07C17/263 ,  C07C22/04 ,  C07C22/08 ,  C07C41/30 ,  C07C45/70 ,  C07C67/343 ,  C07C211/45 ,  C07C231/12 ,  C07C233/00 ,  C07C253/30 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2531/28 ,  C07D213/127 ,  C07D213/16 ,  C07D263/54 ,  C07C233/65 ,  C07C255/50 ,  C07C43/205 ,  C07C49/784 ,  C07C69/76

Abstract: In one aspect, there is provided a method of coupling a first aromatic compound having a fluorosulfonate substituent to a second aromatic compound having a boron-containing substituent. In another aspect, there is provided a method of coupling a first aromatic compound having a hydroxyl substituent to a second aromatic compound having a boron-containing substituent in a one-pot reaction.

公开(公告)号：US10023685B2

公开(公告)日：2018-07-17

申请号：US15125372

申请日：2015-02-26

Applicant: Dow Global Technologies LLC

Inventor： Michael L. Tulchinsky ,  William J. Kruper, Jr. ,  Tzu-Chi Kuo ,  David C. Molzahn ,  Mark F. Sonnenschein

IPC: C08G59/00 ,  C08G59/22 ,  C07D303/04 ,  C07D303/22 ,  C08G59/68 ,  C09D163/00

Abstract: A novel byproduct compound having the following chemical formula B: wherein R is hydrogen or CH3; a composition including an admixture of: (A) a product having the following chemical formula A: wherein R is hydrogen or CH3; and (B) the above novel byproduct compound having the chemical formula B; and a composition including a reaction product of: (a) an aromatic epoxy resin; (b) hydrogen; (c) a catalyst; and (d) a solvent; wherein the reaction product produced is a cycloaliphatic epoxy resin admixture of the combination of (i) the above product having the chemical formula A and (ii) the novel byproduct compound having the chemical formula B; wherein the above product having the chemical formula A includes at least a cis-cis isomer, a cis-trans isomer, and a trans-trans isomer; and the novel byproduct compound having the chemical formula B includes at least a cis isomer and a trans isomer.

公开(公告)号：US09512049B2

公开(公告)日：2016-12-06

申请号：US14367542

申请日：2012-12-21

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Max Markus Tirtowidjojo ,  Brien A. Stears ,  William J. Kruper, Jr. ,  Kurt F. Hirsekorn ,  Debashis Chakraborty

IPC: C07C2/86

CPC classification number: C07C2/861 ,  C07C2531/02 ,  C07C11/06 ,  C07C11/173

Abstract: Processes for the production of alkenes are provided. The processes make use of methane as a low cost starting material.

Abstract translation: 提供了生产烯烃的方法。 这些方法使用甲烷作为低成本起始材料。

公开(公告)号：US08933280B2

公开(公告)日：2015-01-13

申请号：US14046312

申请日：2013-10-04

Applicant: Dow Global Technologies, LLC

Inventor： Max Markus Tirtowidjojo ,  Patrick Ho-Sing Au-Yeung ,  Debashis Chakraborty ,  Juergen Eiffler ,  Heinz Groenewald ,  Kurt Frederick Hirsekorn ,  Manfred Kokott ,  William J. Kruper, Jr. ,  Thomas Ulrich Luebbe ,  Holger Meeman ,  Shirley Shaw Sexton ,  Peter Wenzel ,  Marcus Wobser

IPC: C07C21/20 ,  C07C17/26 ,  C07C17/20 ,  C07C17/269

CPC classification number: C07C17/26 ,  C07C17/206 ,  C07C17/269 ,  Y02P20/582 ,  C07C21/18 ,  C07C21/04

Abstract: The present invention provides continuous, gas phase, free radical processes for the production of chlorinated and/or fluorinated propenes or higher alkenes from the reaction of chlorinated and/or fluorinated alkanes and chlorinated and/or fluorinated alkenes, wherein wherein at least a portion of any intermediate boiler by-products generated by the process are removed from the process.

Abstract translation: 本发明提供连续的气相自由基方法，用于从氯化和/或氟化烷烃和氯化和/或氟化烯烃的反应生产氯化和/或氟化丙烯或更高级烯烃，其中至少一部分 该过程产生的任何中间锅炉副产物将从该过程中移除。