摘要:
A process to produce an ionomer comprising reacting alkyl-cis-cyclooctene and cis-cyclooctene in a mole ratio from 1:0 to 0:1, in the presence of a difunctional chain transfer agent under ring opening metathesis polymerization conditions to form an unsaturated polyolefin reactive telechelic pre-polymer; hydrogenating the unsaturated polyolefin reactive telechelic pre-polymer to produce a hydrogenated polyolefin reactive telechelic pre-polymer; reacting the hydrogenated polyolefin reactive telechelic pre-polymer with at least one compound according to the formula aMx+b(R)y, wherein M is a metal, x is a charge of M, R is an alkyl, aryl, oxide, or fatty acid, y is a charge of R, a and b are integers of at least 1, and ax+by=0, to form an ionomer is provided. Further provided are ionomers produced thereby.
摘要:
A process to produce an ionomer comprising reacting alkyl-cis-cyclooctene and cis-cyclooctene in a mole ratio from 1:0 to 0:1, in the presence of a difunctional chain transfer agent under ring opening metathesis polymerization conditions to form an unsaturated polyolefin reactive telechelic pre-polymer; hydrogenating the unsaturated polyolefin reactive telechelic pre-polymer to produce a hydrogenated polyolefin reactive telechelic pre-polymer; reacting the hydrogenated polyolefin reactive telechelic pre-polymer with at least one compound according to the formula aMx·b(R)y, wherein M is a metal, x is a charge of M, R is an alkyl, aryl, oxide, or fatty acid, y is a charge of R, a and b are integers of at least 1, and ax+by=0, to form an ionomer is provided. Further provided are ionomers produced thereby.
摘要:
A process to produce a polyolefin reactive telechelic pre-polymer comprising reacting alkyl-cis-cyclooctene, and optionally cis-cyclooctene, in the presence of a multifunctional chain transfer agent possessing two or more amino groups wherein the two or more amino groups are protected by one or more protecting groups under ring opening metathesis polymerization conditions to form a dicarbamate telechelic unsaturated polyolefin pre-polymer is provided.
摘要:
A dicarbamate telechelic unsaturated polyolefin pre-polymer comprising a reaction product of reacting alkyl-cis-cyclooctene and optionally cis-cyclooctene, in the presence of a multifunctional chain transfer agent possessing two or more amino groups wherein the two or more amino groups are protected by one or more protecting groups under ring opening metathesis polymerization conditions is provided.
摘要:
A process to produce a polyolefin reactive telechelic pre-polymer comprising reacting alkyl-cis-cyclooctene and optionally cis-cyclooctene, in the presence of a difunctional chain transfer agent under ring opening metathesis polymerization conditions to form an unsaturated polyolefin reactive telechelic pre-polymer is provided. Further provided are unsaturated and hydrogenated reactive pre-polymers, crosslinked elastomers and high molecular weight elastomers.
摘要:
A process to produce a polyolefin reactive telechelic pre-polymer comprising reacting alkyl-c/5-cyclooctene and optionally czs-cyclooctene, in the presence of a multifunctional chain transfer agent possessing two or more amino groups wherein the two or more amino groups are protected by one or more protecting groups under ring opening metathesis polymerization conditions to form a dicarbamate telechelic unsaturated polyolefm pre-polymer is provided.
摘要:
A process to produce a polyolefin reactive telechelic pre-polymer comprising reacting alkyl-cis-cyclooctene and optionally cis-cyclooctene, in the presence of a difunctional chain transfer agent under ring opening metathesis polymerization conditions to form an unsaturated polyolefin reactive telechelic pre-polymer is provided. Further provided are unsaturated and hydrogenated reactive pre-polymers, crosslinked elastomers and high molecular weight elastomers.
摘要:
A thermoplastic vulcanizate composition includes (A) greater than 15 wt % of a block composite that has (i) an ethylene/alpha-olefin/diene interpolymer in which the alpha-olefin is an alpha olefin monomer having from 3 to 10 carbon atoms and the diene is a diene monomer having from 2 to 25 carbon atoms, (ii) a propylene based polymer, and (iii) a block copolymer comprising a soft block and a hard block in which the soft block has the same composition as the ethylene/alpha-olefin/diene polymer and the hard block has the same composition as the propylene based polymer; and (B) a remainder of a curative system and optionally at least one of a vulcanizable elastomer, a thermoplastic polyolefin, and an oil.
摘要:
A thermoplastic vulcanizate composition includes (A) greater than 15 wt % of a block composite that has (i) an ethylene/alpha-olefin/diene interpolymer in which the alpha-olefin is an alpha olefin monomer having from 3 to 10 carbon atoms and the diene is a diene monomer having from 2 to 25 carbon atoms, (ii) a propylene based polymer, and (iii) a block copolymer comprising a soft block and a hard block in which the soft block has the same composition as the ethylene/alpha-olefin/diene polymer and the hard block has the same composition as the propylene based polymer; and (B) a remainder of a curative system and optionally at least one of a vulcanizable elastomer, a thermoplastic polyolefin, and an oil.
摘要:
The invention provides functionalized block composites and crystalline block composites. In particular, the invention provides a functionalized olefin-based polymer formed from at least (A) and (B): (A) a crystalline block composite comprising: a block copolymer comprising a propylene-based crystalline block and crystalline ethylene-based block; a propylene-based crystalline polymer; and, a crystalline ethylene-based polymer; and (B) at least one functionalization agent or a functionalized olefin-based polymer formed from at least (A) and (B): (A) a crystalline block composite comprising: a block copolymer comprising a propylene-based crystalline block and crystalline ethylene-based block; a propylene-based crystalline polymer; and, a crystalline ethylene-based polymer; and (B) at least one functionalization agent.