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1.发明授权公开(公告)号：US08815124B2
公开(公告)日：2014-08-26
申请号：US12040776
申请日：2008-02-29
申请人： Darin W. Laird , Reza Stegamat , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada , Malika Daadi
发明人： Darin W. Laird , Reza Stegamat , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y99/00 , H01G9/2004 , H01L31/0256 , H01L51/0036 , H01L51/0046 , H01L51/4253 , H01L2031/0344 , Y02E10/549 , Y02P70/521 , Y10S977/734 , Y10S977/735 , Y10S977/737 , Y10S977/738 , Y10S977/778 , Y10S977/784 , Y10S977/948
摘要： Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.
摘要翻译： 包含作为p型材料的共聚聚合物如聚噻吩和区域性聚噻吩的活性层的光伏电池，以及至少一种富勒烯衍生物作为n型材料。 富勒烯衍生物可以是C60，C70或C84。 富勒烯也可以用茚基官能化。 可以提高效率。
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2.发明申请公开(公告)号：US20120318359A1
公开(公告)日：2012-12-20
申请号：US13526414
申请日：2012-06-18
申请人： Darin W. Laird , Reza Stegamat , Malika Daadi , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
发明人： Darin W. Laird , Reza Stegamat , Malika Daadi , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y99/00 , H01G9/2004 , H01L31/0256 , H01L51/0036 , H01L51/0046 , H01L51/4253 , H01L2031/0344 , Y02E10/549 , Y02P70/521 , Y10S977/734 , Y10S977/735 , Y10S977/737 , Y10S977/738 , Y10S977/778 , Y10S977/784 , Y10S977/948
摘要： Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.
摘要翻译： 包含作为p型材料的共聚聚合物如聚噻吩和区域性聚噻吩的活性层的光伏电池，以及至少一种富勒烯衍生物作为n型材料。 富勒烯衍生物可以是C60，C70或C84。 富勒烯也可以用茚基官能化。 可以提高效率。
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3.发明授权公开(公告)号：US08217260B2
公开(公告)日：2012-07-10
申请号：US11743587
申请日：2007-05-02
申请人： Darin W. Laird , Reza Stegamat , Malika Daadi, legal representative , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
发明人： Darin W. Laird , Reza Stegamat , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
IPC分类号： H01L31/00
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y99/00 , H01G9/2004 , H01L31/0256 , H01L51/0036 , H01L51/0046 , H01L51/4253 , H01L2031/0344 , Y02E10/549 , Y02P70/521 , Y10S977/734 , Y10S977/735 , Y10S977/737 , Y10S977/738 , Y10S977/778 , Y10S977/784 , Y10S977/948
摘要： Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.
摘要翻译： 包含作为p型材料的共聚聚合物如聚噻吩和区域性聚噻吩的活性层的光伏电池，以及至少一种富勒烯衍生物作为n型材料。 富勒烯衍生物可以是C60，C70或C84。 富勒烯也可以用茚基官能化。 可以提高效率。
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4.发明申请公开(公告)号：US20100132782A1
公开(公告)日：2010-06-03
申请号：US11743587
申请日：2007-05-02
申请人： Darin W. Laird , Reza Stegamat , Malika Daadi , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
发明人： Darin W. Laird , Reza Stegamat , Malika Daadi , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y99/00 , H01G9/2004 , H01L31/0256 , H01L51/0036 , H01L51/0046 , H01L51/4253 , H01L2031/0344 , Y02E10/549 , Y02P70/521 , Y10S977/734 , Y10S977/735 , Y10S977/737 , Y10S977/738 , Y10S977/778 , Y10S977/784 , Y10S977/948
摘要： Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.
摘要翻译： 包含作为p型材料的共聚聚合物如聚噻吩和区域性聚噻吩的活性层的光伏电池，以及作为n型材料的至少一种富勒烯衍生物。 富勒烯衍生物可以是C60，C70或C84。 富勒烯也可以用茚基官能化。 可以提高效率。
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公开(公告)号：US08697988B2
公开(公告)日：2014-04-15
申请号：US13526414
申请日：2012-06-18
申请人： Darin W. Laird , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada , Malika Daadi
发明人： Darin W. Laird , Reza Stegamat , Henning Richter , Viktor Vejins , Larry Scott , Thomas A. Lada
IPC分类号： H01L31/00
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y99/00 , H01G9/2004 , H01L31/0256 , H01L51/0036 , H01L51/0046 , H01L51/4253 , H01L2031/0344 , Y02E10/549 , Y02P70/521 , Y10S977/734 , Y10S977/735 , Y10S977/737 , Y10S977/738 , Y10S977/778 , Y10S977/784 , Y10S977/948
摘要： Photovoltaic cells comprising an active layer comprising, as p-type material, conjugated polymers such as polythiophene and regioregular polythiophene, and as n-type material at least one fullerene derivative. The fullerene derivative can be C60, C70, or C84. The fullerene also can be functionalized with indene groups. Improved efficiency can be achieved.
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6.发明授权Organic photovoltaic devices comprising fullerenes and derivatives thereof and improved methods of making fullerene derivatives 有权包含富勒烯及其衍生物的有机光伏器件和制备富勒烯衍生物的改进方法公开(公告)号：US08715606B2
公开(公告)日：2014-05-06
申请号：US12340587
申请日：2008-12-19
IPC分类号： C01B31/02
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08G2261/3223 , C08G2261/91 , C08L65/00 , H01L51/0036 , Y02E10/549 , Y02P70/521
摘要： Improved methods of fullerene derivative production including use of less solvent, or elimination of solvent, as well as use of shorter reaction times and higher reaction temperatures. Methods useful for production of bis-, tris-, tetra-, penta-, and hexa-fullerene derivatives. Indene is a preferred derivative. The derivatives used in active layers for solar cell applications.
摘要翻译： 富勒烯衍生物生产的改进方法包括使用较少溶剂或消除溶剂，以及使用较短的反应时间和较高的反应温度。 用于生产双 - ，三 - ，四 - ，五 - 和六 - 富勒烯衍生物的方法。 茚是优选的衍生物。 用于太阳能电池应用的有源层的衍生物。
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7.发明申请ORGANIC PHOTOVOLTAIC DEVICES COMPRISING FULLERENES AND DERIVATIVES THEREOF AND IMPROVED METHODS OF MAKING FULLERENE DERIVATIVES 有权包含富勒烯及其衍生物的有机光伏器件及其制备富勒烯衍生物的改进方法公开(公告)号：US20090176994A1
公开(公告)日：2009-07-09
申请号：US12340587
申请日：2008-12-19
IPC分类号： C07D333/02 , C07C13/465
CPC分类号： H01L51/0047 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08G2261/3223 , C08G2261/91 , C08L65/00 , H01L51/0036 , Y02E10/549 , Y02P70/521
摘要： Improved methods of fullerene derivative production including use of less solvent, or elimination of solvent, as well as use of shorter reaction times and higher reaction temperatures. Methods useful for production of bis-, tris-, tetra-, penta-, and hexa-fullerene derivatives. Indene is a preferred derivative. The derivatives used in active layers for solar cell applications.
摘要翻译： 富勒烯衍生物生产的改进方法包括使用较少溶剂或消除溶剂，以及使用较短的反应时间和较高的反应温度。 用于生产双 - ，三 - ，四 - ，五 - 和六 - 富勒烯衍生物的方法。 茚是优选的衍生物。 用于太阳能电池应用的有源层的衍生物。
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公开(公告)号：US07569159B2
公开(公告)日：2009-08-04
申请号：US11350271
申请日：2006-02-09
申请人： Troy D. Hammond , Shawn P. Williams , Elena Sheina , Darin W. Laird , Christopher Greco , Brian Woodworth
发明人： Troy D. Hammond , Shawn P. Williams , Elena Sheina , Darin W. Laird , Christopher Greco , Brian Woodworth
CPC分类号： H01B1/127 , C08G2261/141 , C08G2261/212 , C08G2261/312 , C08G2261/3223 , C08G2261/512 , C08L65/00 , H01L51/002 , H01L51/0036 , H01L51/0043 , H01L51/5048 , H01L51/5052 , H01L51/5088 , Y10T428/31504 , C08L2666/02 , C08L2666/10
摘要： Compositions for use in HIL/HTL applications include intrinsically conductive polymer, planarizing agent, and dopant, which are soluble in non-aqueous solvents. Block copolymers of regioregular alkyl/alkoxy- and aryl-substituted polythiophenes can be used. The compositions can be formed into thin films. Excellent efficiency and lifetime stability can be achieved.
摘要翻译： 用于HIL / HTL应用的组合物包括可溶于非水溶剂的固有导电聚合物，平面化剂和掺杂剂。 可以使用区域性烷基/烷氧基 - 和芳基取代的聚噻吩的嵌段共聚物。 组合物可以形成薄膜。 可以实现极好的效率和寿命稳定性。
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公开(公告)号：US07888427B2
公开(公告)日：2011-02-15
申请号：US11496024
申请日：2006-07-31
IPC分类号： C08G75/02 , C08L81/02 , C08F28/06 , C08F34/04 , C08F128/06 , C08F134/04 , C07D333/06
CPC分类号： H01L51/002 , C08L65/00 , H01B1/127 , H01L51/0003 , H01L51/0036 , H01L51/5048 , H01L51/5052 , Y02E10/549
摘要： Latent doping is provided wherein a conducting polymer is mixed with a dopant in solution without the doping reaction occurring unless solvent is removed. Regioregular polythiophenes are a particularly important embodiment. A composition comprising (i) at least one polymer comprising conjugation in the polymer backbone, (ii) at least one dopant for the polymer, (iii) at least one solvent for the polymer and latent dopant, wherein the polymer, the latent dopant, and the solvent are formulated so that the latent dopant does not substantially dope the polymer when formulated, but does substantially react with the polymer when the solvent is removed. Formulation of the composition can comprise adjusting the order of mixing, the amounts of the components, and the temperature. Methods of formulating the compositions and methods of using the compositions are also provided. OLED, PLED, photovoltaic, and other organic electronic devices can be fabricated.
摘要翻译： 提供潜在掺杂，其中除非除去溶剂，否则导电聚合物与溶液中的掺杂剂混合而不发生掺杂反应。 区域聚噻吩是特别重要的实施方案。 一种组合物，其包含（i）至少一种包含在聚合物主链中共轭的聚合物，（ii）聚合物的至少一种掺杂剂，（iii）至少一种用于聚合物和潜在掺杂剂的溶剂，其中聚合物，潜在掺杂剂， 并且配制溶剂使得潜在掺杂剂在配制时基本上不掺杂聚合物，但当除去溶剂时基本上与聚合物反应。 组合物的配方可以包括调节混合的顺序，组分的量和温度。 还提供了配制组合物的方法和使用组合物的方法。 可以制造OLED，PLED，光电和其它有机电子器件。
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10.发明申请Doped interfacial modification layers for stability enhancement for bulk heterojunction organic solar cells 审中-公开掺杂的界面改性层用于体异质结有机太阳能电池的稳定性增强公开(公告)号：US20100147386A1
公开(公告)日：2010-06-17
申请号：US12591509
申请日：2009-11-20
申请人： Jessica Benson-smith , Christohper T. Brown , Shijun Jia , Darin W. Laird , Christine L. McGuiness , Bal Mukund Dhar
发明人： Jessica Benson-smith , Christohper T. Brown , Shijun Jia , Darin W. Laird , Christine L. McGuiness , Bal Mukund Dhar
IPC分类号： H01L31/0256
CPC分类号： H01L51/002 , C08G2261/91 , H01L51/0036 , H01L51/0037 , H01L51/424 , H01L51/4253 , H01L51/441 , Y02E10/549
摘要： Organic photovoltaic (OPV) devices comprising an organic semiconductor doped with a metal or organic dopant to form an interfacial modification layer, where the layer is disposed on an active layer including a conjugated polymer and a fullerene are described. In the layer, the organic semiconductor can be BPhen or TPBI, and the dopant can be a metal or an organic material. In the active layer, the conjugated polymer can be P3HT and the fullerene can be PCBM or indenyl-substituted fullerene. Improved OPV efficiency and lifetime can be achieved. Good testing results are obtained despite high humidity and high temperature, and modules can be made.
摘要翻译： 描述了包含掺杂有金属或有机掺杂剂的有机半导体以形成界面改性层的有机光伏（OPV）器件，其中该层设置在包含共轭聚合物和富勒烯的有源层上。 在该层中，有机半导体可以是BPhen或TPBI，掺杂剂可以是金属或有机材料。 在活性层中，共轭聚合物可以是P3HT，富勒烯可以是PCBM或茚基取代的富勒烯。 可以实现OPV效率和寿命的提高。 尽管高湿度和高温也能获得良好的测试结果，但可以制成模块。
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