Soluble self-orienting materials and conductive polymer compositions having the same
    1.
    发明授权
    Soluble self-orienting materials and conductive polymer compositions having the same 失效
    可溶性自取向材料和具有相同的导电聚合物组合物

    公开(公告)号:US07064178B2

    公开(公告)日:2006-06-20

    申请号:US10472334

    申请日:2002-02-26

    IPC分类号: C08G63/02 C08F6/00

    摘要: The present invention relates to an electrically conductive polymer, and more particularly to an additive for enhancing electrical conductivity of the polymer and electrically conductive polymer composition containing the additive. The present invention provides a soluble self-orienting material (SOM) and an electrically conductive polymer composition containing the SOM. The SOM can be provided as a form of a monomer having an aromatic ring with various polarity, flexible side chain and hydrophilic dibasic acid, as a form of a complex consisting of the monomers linked by a hydrogen bond or a metal coordinate bond or as a form of a whole aromatic polymer having —NRCO—, —NROSO—(R: side chain including —H, —CO2H, —(CH2)nSO3H, —(CH2)nCO2H or -tert-butyloxycarbonyl) and —OCO—. And also, the composition of the present invention have higher electrical conductivity, in excess of 103 S/cm, than a conventional conductive polymer, and also have improved processability.

    摘要翻译: 本发明涉及一种导电聚合物,更具体地说,涉及一种用于提高聚合物导电性的添加剂和含有该添加剂的导电聚合物组合物。 本发明提供了一种可溶性自取向材料(SOM)和含有SOM的导电聚合物组合物。 SOM可以作为具有各种极性的芳香环,柔性侧链和亲水二元酸的单体的形式提供,作为由通过氢键或金属配位键连接的单体组成的络合物的形式,或作为 具有-NRCO-,-NROSO-(R:侧链包括-H,-CO 2 H, - (CH 2)2)的整个芳族聚合物的形式 H 3 - , - (CH 2)n CO 2 H或 - 叔丁氧基羰基)和-OCO-。 此外,本发明的组合物比常规的导电聚合物具有更高的导电率,超过103S / cm,并且还具有改进的加工性能。

    Soluble self-orienting materials and conductive polymer compositons having the same
    2.
    发明申请
    Soluble self-orienting materials and conductive polymer compositons having the same 失效
    具有相同的可溶性自取向材料和导电聚合物组合物

    公开(公告)号:US20040162397A1

    公开(公告)日:2004-08-19

    申请号:US10472334

    申请日:2004-03-23

    IPC分类号: C08L077/00

    摘要: The present invention relates to an electrically conductive polymer, and more particularly to an additive for enhancing electrical conductivity of the polymer and electrically conductive polymer composition containing the additive. The present invention provides a soluble self-orienting material (SOM) and an electrically conductive polymer composition containing the SOM. The SOM can be provided as a form of a monomer having an aromatic ring with various polarity, flexible side chain and hydrophilic dibasic acid, as a form of a complex consisting of the monomers linked by a hydrogen bond or a metal coordinate bond or as a form of a whole aromatic polymer having nullNRCOnull, nullNROSOnull (R: side chain including nullH, nullCO2H, null(CH2)nSO3H, null(CH2)nCO2H or -tert-butyloxycarbonyl) and nullOCOnull. And also, the composition of the present invention have higher electrical conductivity, more in excess of 103 S/cm, than a conventional conductive polymer, and also have improved prodessability processability.

    摘要翻译: 本发明涉及一种导电聚合物,更具体地说,涉及一种用于提高聚合物导电性的添加剂和含有该添加剂的导电聚合物组合物。 本发明提供了一种可溶性自取向材料(SOM)和含有SOM的导电聚合物组合物。 SOM可以作为具有各种极性的芳香环,柔性侧链和亲水二元酸的单体的形式提供,作为由通过氢键或金属配位键连接的单体组成的络合物的形式,或作为 具有-NRCO-,-NROSO-(R:侧链包括-H,-CO 2 H, - (CH 2)n SO 3 H, - (CH 2)n CO 2 H或 - 叔丁氧羰基)和-OCO-的整个芳族聚合物的形式。 而且,本发明的组合物比常规的导电聚合物具有更高的导电率,超过103S / cm,并且还具有改善的可加工性加工性。

    Polyurethane film-forming dispersions in alcohol-water system
    3.
    发明授权
    Polyurethane film-forming dispersions in alcohol-water system 有权
    聚氨酯成膜分散体在酒精 - 水体系中

    公开(公告)号:US06605666B1

    公开(公告)日:2003-08-12

    申请号:US09627110

    申请日:2000-07-27

    IPC分类号: C08J303

    摘要: A polyurethane dispersion and method of making are provided. The dispersion is stable in an alcohol-water mixture. The dispersion is a reaction product of: (i) at least one oligomeric polyactive hydrogen compound, wherein said compound is an alkyl, aryl, or aralkyl structure optionally substituted in and/or on the chain by N, O, S and combinations thereof, and wherein the compound is insoluble in 50:50 weight percent of said alcohol-water mixture; (ii) at least one polyisocyanate, and (iii) at least one polyactive hydrogen compound soluble in the alcohol-water mixture selected from the group consisting of a compound containing an ionic group, a compound containing a moiety capable of forming an ionic group, a compound containing a polyester, polyether, or polycarbonate group having a ratio of 5 or less carbon atoms for each oxygen atom, and mixtures thereof; and (b) at least one polyfunctional chain extender.

    摘要翻译: 提供聚氨酯分散体和制备方法。 分散体在醇 - 水混合物中是稳定的。 分散体是:(i)至少一种低聚多官能氢化合物的反应产物,其中所述化合物是在N,O,S及其组合中任选地在链中和/或链上取代的烷基,芳基或芳烷基结构, 并且其中所述化合物不溶于50:50重量百分比的所述醇 - 水混合物; (ii)至少一种多异氰酸酯,和(iii)可溶于所述醇 - 水混合物中的至少一种多活性氢化合物,所述醇 - 水混合物选自含有离子基团的化合物,含有能够形成离子基团的部分的化合物, 含有每个氧原子具有5个或更少碳原子比的聚酯,聚醚或聚碳酸酯基团的化合物及其混合物; 和(b)至少一种多官能扩链剂。

    Particle and liquid adhesion reduction coating in polycarbonate sheet
    4.
    发明申请
    Particle and liquid adhesion reduction coating in polycarbonate sheet 审中-公开
    聚碳酸酯薄片中的颗粒和液体附着力降低涂层

    公开(公告)号:US20030129409A1

    公开(公告)日:2003-07-10

    申请号:US10265510

    申请日:2002-10-04

    IPC分类号: B32B027/36

    摘要: A substrate having the outer surface facing the atmosphere a coating composition having a silicone modified acrylate polymer additive sufficient to allow ease of removing solid particles (dirt) and/or liquids on the surface by reducing the adhesion of such particles and/or liquids to the substrate. The coating composition may also have in combination therewith an ultra violet absorber and/or a mar resistant coating along with a polymer matrix such as an acrylate polymer and a solvent such as methoxypropanol. The amount of silicone modifier acrylate polymer may range from about 0.5 to about 6.0 weight % based on the total weight of the coating composition. A preferred ultra violet absorber is a polybenzoylresorcinol. The preferred substrate is a transparent aromatic polycarbonate resin sheet or multiwall polycarbonate at least two polycarbonate sheets having interdisposed therebetween and joining said sheets a structure of essentially any configuration.

    摘要翻译: 具有面向大气的外表面的基底具有硅氧烷改性的丙烯酸酯聚合物添加剂的涂料组合物,其足以通过降低这些颗粒和/或液体对该表面的粘附性而容易地除去表面上的固体颗粒(污物)和/或液体 基质。 涂料组合物还可以与其一起使用紫外线吸收剂和/或耐磨涂层以及聚合物基质如丙烯酸酯聚合物和溶剂如甲氧基丙醇。 基于涂料组合物的总重量,硅氧烷改性剂丙烯酸酯聚合物的量可以为约0.5至约6.0重量%。 优选的紫外吸收剂是聚苯甲酰间苯二酚。 优选的基材是透明的芳族聚碳酸酯树脂片或多壁聚碳酸酯,至少两个聚碳酸酯片具有介于其间并与所述片接合的结构基本上是任何构型。

    Polyester film base having uniform high optical density
    5.
    发明授权
    Polyester film base having uniform high optical density 失效
    具有均匀高光密度的聚酯薄膜基材

    公开(公告)号:US3905938A

    公开(公告)日:1975-09-16

    申请号:US39214973

    申请日:1973-08-27

    申请人: EASTMAN KODAK CO

    摘要: Biaxially-oriented polyester film base having uniform high optical density and free of pinholes or other opacity defects is produced by forming a dispersion of carbon black and polyvinylpyrrolidone (PVP) in ethylene glycol in a high shear mill, adding the dispersion along with polyester forming reactants to an ester exchange reactor, and carrying out the production of the polyester monomer and its subsequent conversion to polyester prepolymer and polyester in the presence of the dispersed carbon and PVP.

    摘要翻译: 通过在高剪切研磨机中在乙二醇中形成炭黑和聚乙烯吡咯烷酮(PVP)的分散体,加入分散体与聚酯形成反应物一起制备具有均匀高光密度并且没有针孔或其它不透明度缺陷的双轴取向聚酯膜基材 到酯交换反应器,并且在分散的碳和PVP的存在下进行聚酯单体的生产并随后转化成聚酯预聚物和聚酯。

    Floor mop having pivotable handle for changing directions air-drying coating composition of an acrylic enamel and an isocyanate cross-linking agent
    6.
    发明授权
    Floor mop having pivotable handle for changing directions air-drying coating composition of an acrylic enamel and an isocyanate cross-linking agent 失效
    具有改变方向的地板手柄丙烯酸酯和异氰酸酯交联剂的空气干燥涂料组合物

    公开(公告)号:US3844993A

    公开(公告)日:1974-10-29

    申请号:US26804372

    申请日:1972-06-30

    申请人: DU PONT

    发明人: MILLER L

    摘要: WHEREIN R9 IS A DIIVALENT AROMATIC HYDROCARBN CONSISTING OF POLYISCOYANATE OF THEFORMULA O=C=N-R9-N(-CO-NH-R9-N=C=O)2 WHEREIN R9 IS A DIVALENT AROMATIC HYDROCARBON RADICAL HAVING 1-12 CARBON ATOMS AND METHYLENE BIS(4-CYCLOHEXYL ISOCYANATE) AND AN AROMATIC SOLVENT FOR THE POLYISOCYANATE THAT IS COMPATIBLE WITH THE COATING COMPOSITION.

    O=C=N-(R9)-N(-CO-NH-(R9)-N=C=O)2

    WHEREIN R1 IS A HYDROCARBON GROUP HAVING 2-20 CARBON ATOMS; R2 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN AND AN ALKYL GROUP HAVING 1-4 CARBON ATOMS; R3 AND R4 ARE R8-COO-CH2-; R5 IS AN ALIPHATIC HYDROCARBON GROUP HAVING 1-6 CARBON ATOMS; R6 AND R7 ARE INDIVIDUALLY SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, A SATURATED ALIPHATIC HYDROCARBON GROUP HAVING 1-6 CARBON ATOMS; AND R8 IS FROM DRYING OIL FATTY ACIDS, AND CORRESPONDINGLY (2) 5-60% BY WEIGHT OF AN ALKYD RESIIN OR A BLEND OF ALKYD RESNS; WHEREIN THE ALKYD RESIN IIS THE ESTERFICATION PRODUCT OF DRYIING OIL FATTY ACIDS, A POLYHYDRIC ALCOHOL AND AN AROMATIC DICARBOXYLIC ACID OR AN ANHYCARBOXYLIC ACID AND AN ANHYDRIDE OF AN AROMATIC DICARBOXYLIC ACIID; AND UTILIIZED WIITH SAID COATING COMPOSITION ABOUT 0.5-200% BY WEIGHT, BASED ON THE WEIGHT OF THE COATIING COMPOSITION, OF A OLYISOCYANATE SOLU-

    -COO-R5-N(-R6)-R7

    AND HAVING ATTACHED TO THE POLYMER BACKBONE 0.515% BY WEIGHT, BASED ON THE WEIGHT OF THE POLYMER, OF PENDENT AMINO ESTER GROUPS OF THE FORMULA

    -(C(-R1)(-C
    1. A COATING COMPOSITION COMPRISJNG 5-60% BY WEIGHT OF A POLYMER BLEND AND 95-40% BY WEIGHT OF A SOLVENT FOR THE POLYMER BLEND IN WHICH THE BLEND CONSISTS ESSENTIALLY OF (1) 40-95% BY WEIGHT OF AN ACRYLIC VINYL OXAZOLINE ESTER POLYMER THAT HAS A RELATIVE VISCOSITY OF ABOUT 1.03-1.30 MEASURED ACCODING TO ASTM-D-445-64T, METHOD B AT 25*C. AND WHICH CONSISTS ESSENTIALLY OF A BACKBONE OF 50-96.5% BY WEIGHT, BASED ON THE WEIGHT OF THE POLYMER, OF POLYMERIZED ETHYLENICALLY UNSATURATED MONOMERS SELECTED FROM THE GROUP CONSISTING OF AN ALKYL METHACRYLATE HAVING 1-8 CARBON ATOMS IN THE ALKYL GROUP, CYCLOHEXYL METHACRYLATE, ACRYLONITRILE, STYRENE AND MIXTURES OF THESE MONOMERS AND UP TO 20% BY WEIGHT, BASED ON THE WEIGHT OF THE POLYMER, OF A HYDROXY CONTAINING MONOMER SELECTED FROM THE GROUP CONSISTING OF HYDROXY ALKYL ACRYLATE AND HYDROXY ALKYL METHACRYLATE HAVING 2-4 IN THE ALKYL GROUPS AND CONTAINING IN THE BACKBONE 3-35% BY WEIHT, BASED ON THE WEIGHT OF THE POLYMER, OF POLYMERIZED VINYL OXAZOLIINE ESTERS OF THE FORMULA