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    Highly activated bimetallic complexes and polymerization process
    4.
    发明授权
    Highly activated bimetallic complexes and polymerization process 有权
    高活性双金属络合物和聚合过程

    公开(公告)号：US06284698B1

    公开(公告)日：2001-09-04

    申请号：US09528787

    申请日：2000-03-17

    申请人： Eugene Y. Chen ,  Shaoguang S. Feng ,  David D. Graf ,  Jasson T. Patton ,  David R. Wilson

    发明人： Eugene Y. Chen ,  Shaoguang S. Feng ,  David D. Graf ,  Jasson T. Patton ,  David R. Wilson

    IPC分类号： B01J3100

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F2410/03 ,  C08F4/6592

    摘要： Catalyst compositions comprising 1) one or more bimetallic Group 3-6 or Lanthanide metal complexes corresponding to the formula:  wherein: M and M′ are independently Group 3, 4, 5, 6, or Lanthanide metals; L is a divalent group (or trivalent group if bound to Q) having up to 50 nonhydrogen atoms and containing an aromatic &pgr;-system through which the group is bound to M, said L also being bound to Z; L′ is a monovalent group or a divalent group (if bound to L″ or Q), or a trivalent group (if bound to both L″ and Q) having up to 50 nonhydrogen atoms and containing an aromatic &pgr;-system through which the group is bound to M′; L″ is a monovalent group or a divalent group (if bound to L′ or Q), or a trivalent group (if bound to both L′ and Q) having up to 50 nonhydrogen atoms and containing an aromatic &pgr;-system through which the group is bound to M′, or L″ is a moiety comprising boron or a member of Group 14 of the Periodic Table of the Elements, and optionally also comprising nitrogen, phosphorus, sulfur or oxygen, said L″ having up to 20 non-hydrogen atoms; Z is a moiety comprising boron or a member of Group 14 of the Periodic Table of the Elements, and also comprising nitrogen, phosphorus, sulfur or oxygen, said Z having up to 20 non-hydrogen atoms; X, X′ and X″ are as defined in the specification; Q is a divalent anionic ligand group bound at one terminus to either Z or L and bound at the remaining terminus to either L′ or L″, said Q having up to 20 nonhydrogen atoms; and x, x′, and x″ are independently integers from 0 to 3; and 2) one or more activating cocatalysts; wherein activating cocatalyst component 2) causes both metal centers, M and M′, of the one or more bimetallic metal complexes 1) to be catalytically active for the polymerization of addition polymerizable monomers.

    摘要翻译： 催化剂组合物包含1）一种或多种对应于下式的双金属组3-6或镧系元素金属络合物：其中：M和M'独立地为第3,4,5,6族或镧系金属; L为二价基团（或三价 基团如果结合Q）具有多达50个非氢原子并且含有基团与M结合的芳族π系统，所述L也与Z结合; L'是一价基团或二价基团（如果与 L“或Q）或三价基团（如果与L”和Q两者结合），其具有多达50个非氢原子并且含有该基团通过其与M'结合的芳族π系统; L“是 一价基团或二价基团（如果与L'或Q键合）或三价基团（如果与L'和Q两者结合）具有多达50个非氢原子并含有芳族π-系统，通过该基团键合该基团 M'或L“是包含元素周期表第14族的硼或元素的部分，并且任选地也包含氮，磷 所述L“具有多达20个非氢原子; Z是包含元素周期表第14族的硼或元素的部分，并且还包含氮，磷，硫或氧， 所述Z具有至多20个非氢原子; X，X'和X“如说明书中所定义; Q是在一个末端与Z或L结合的二价阴离子配体基团，并在剩余的末端结合至 L'或L“，所述Q具有至多20个非氢原子; 和x，x'独立地为0至3的整数; 和2）一种或多种活化助催化剂;其中活化助催化剂组分2）使得一种或多种双金属金属络合物1）的金属中心M和M'两者对于可加聚单体的聚合具有催化活性。