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公开(公告)号：USRE34250E
公开(公告)日：1993-05-11
申请号：US733704
申请日：1991-07-22
申请人： Dean A. Van Leirsburg , Donald H. Mohr , Paul W. Tamm , Robert L. Jacobson , Thomas R. Hughes , Charles R. Wilson
发明人： Dean A. Van Leirsburg , Donald H. Mohr , Paul W. Tamm , Robert L. Jacobson , Thomas R. Hughes , Charles R. Wilson
IPC分类号： B01J29/90 , B01J38/18 , B01J38/42 , C10G35/095
CPC分类号： B01J38/18 , B01J29/90 , B01J38/42 , C10G35/095
摘要： The present invention is a process for regenerating a sulfur-contaminated, highly selective, large-pore zeolite catalyst. It comprises a multistep process involving exposure of the catalyst to a combination of oxidizing conditions, reducing conditions and treatment with a halogen acid gas. These conditions are effective to agglomerate a Group VIII metal and remove sulfur. Thereafter, the catalyst is oxychlorinated to redisperse the Group VIII metal over the catalyst surface. A carbon removal step is optionally included.
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公开(公告)号：US4851380A
公开(公告)日：1989-07-25
申请号：US80111
申请日：1987-07-31
申请人： Dean A. Van Leirsburg , Donald H. Mohr , Paul W. Tamm , Robert L. Jacobson , Thomas R. Hughes , Charles R. Wilson
发明人： Dean A. Van Leirsburg , Donald H. Mohr , Paul W. Tamm , Robert L. Jacobson , Thomas R. Hughes , Charles R. Wilson
IPC分类号： B01J29/035 , B01J29/90 , C10G11/02 , C10G35/095
CPC分类号： C10G35/095 , B01J29/90 , Y10S502/517
摘要： The present invention is a process for regenerating a sulfur-contaminated, highly selective, large-pore zeolite catalyst. It comprises a multistep process involving exposure of the catalyst to a combination of oxidizing conditions, reducing conditions and treatment with a halogen acid gas. These conditions are effective to agglomerate a Group VIII metal and remove sulfur. Thereafter, the catalyst is oxychlorinated to redisperse the Group VIII metal over the catalyst surface. A carbon removal step is optionally included.
摘要翻译： 本发明是一种再生含硫污染的高选择性大孔沸石催化剂的方法。 它包括一个多步骤过程，包括将催化剂暴露于氧化条件的组合，还原条件和用卤酸气处理。 这些条件对于聚集第Ⅷ族金属并除去硫是有效的。 此后，催化剂被氧氯化以将VIII族金属重新分散在催化剂表面上。 任选地包括碳去除步骤。
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公开(公告)号：US4460457A
公开(公告)日：1984-07-17
申请号：US178658
申请日：1980-08-18
CPC分类号： C10G35/09
摘要： In a process for reforming light naphtha with a bimetallic or multimetallic reforming catalyst, such as a platinum-rhenium-halogen catalyst, at conventional reforming conditions, wherein the catalyst is used for an extended continuous on-stream period, the aromatics selectivity of the catalyst is rapidly increased by contacting the naphtha and hydrogen with the catalyst at increased severity operating conditions, such as a reduced pressure less than 90% of the normal reforming pressure, during an initial portion of the on-stream period.
摘要翻译： 在通过双金属或多金属重整催化剂如铂 - 铼 - 卤素催化剂重整轻石脑油的方法中，在常规重整条件下，其中催化剂用于延长的连续原油期，催化剂的芳烃选择性 通过在增加的苛刻度操作条件（例如小于正常重整压力的90％的减压）下在接通时段的初始部分期间使石脑油和氢与催化剂接触而快速增加。
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4.发明授权
公开(公告)号：US4049542A
公开(公告)日：1977-09-20
申请号：US729244
申请日：1976-10-04
CPC分类号： B01J23/868 , C10G2400/02
摘要： A hydrocarbon feed containing an olefinic component and sulfur-containing impurities is upgraded in a sulfur removal process without hydrogenating the olefins by contacting a mixture of the feed and hydrogen gas with a catalyst comprising copper under conditions, including a temperature in the range of about 120.degree. C to 400.degree. C.
摘要翻译： 包含烯烃组分和含硫杂质的烃进料在除硫过程中升级，而不会使进料和氢气的混合物与包含铜的催化剂接触，在包括约120℃的温度的条件下 ℃至400℃
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5.发明授权Method of producing high aromatic yields through aromatics removal and recycle of remaining material 失效通过芳烃去除和再循环剩余材料生产高芳族收率的方法
公开(公告)号：US4648961A
公开(公告)日：1987-03-10
申请号：US641638
申请日：1984-08-17
IPC分类号： B01J29/00 , B01J29/068 , C10G35/095 , C10G35/06 , C07C2/52
CPC分类号： C10G35/095 , B01J29/068
摘要： A naphtha feed is contacted in a reaction vessel with a dehydrocyclization catalyst comprising a large-pore zeolite containing at least one Group VIII metal to produce an aromatics product and a gaseous stream, the aromatics product is separated from the gaseous stream and is passed through a molecular sieve which adsorbs paraffins present in the aromatics product, then the gaseous stream is used to strip the paraffins from the molecular sieve, and the gaseous stream and the paraffins are recycled to the reaction vessel.
摘要翻译： 将石脑油进料在反应容器中与脱氢环化催化剂接触，所述脱氢环化催化剂包含含有至少一种Ⅷ族金属的大孔沸石以产生芳族化合物产物和气态物流，芳烃产物与气流分离并通过 分子筛，其吸附存在于芳族化合物产物中的链烷烃，然后使用气流从分子筛中剥离链烷烃，并将气态物流和链烷烃再循环到反应容器中。
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公开(公告)号：US4459204A
公开(公告)日：1984-07-10
申请号：US535147
申请日：1983-09-23
摘要： Small amounts of lower alcohols are admixed with sour hydrocarbons and the mixture is contacted with a copper-containing catalyst at an elevated temperature. The alcohol serves as the oxygen source for the catalytic oxygenative conversion to disulfides of mercaptans souring the hydrocarbon.
摘要翻译： 少量的低级醇与酸性烃混合，混合物在高温下与含铜催化剂接触。 醇用作催化氧化转化为硫化烃的二硫化物的氧源。
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7.发明授权Isomerization process for upgrading low-octane light paraffinic feeds using a chlorided platinum-alumina-rhenium catalyst 失效使用氯化铂 - 铼 - 铼催化剂升级低辛烷值轻石蜡原料的异构化方法
公开(公告)号：US4241231A
公开(公告)日：1980-12-23
申请号：US947792
申请日：1978-10-02
CPC分类号： C10G45/62 , C10G2400/02
摘要： Isomerizable light paraffinic hydrocarbon feeds are isomerized in an improved process using a particular super-chlorided reforming catalyst under isomerizing conditions. A chloride source in the feed stabilizes the catalyst. This process provides for a material octane improvement of the feed without excessive loss thereof to normally gaseous hydrocarbons.
摘要翻译： 在异构化条件下，使用特定的超氯化重整催化剂，改性方法异构化异构化的轻链烷烃进料。 进料中的氯化物源稳定催化剂。 该方法提供进料的材料辛烷值改善，而不会对通常的气态碳氢化合物过量损失。
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公开(公告)号：US5439583A
公开(公告)日：1995-08-08
申请号：US243
申请日：1993-01-04
申请人： Richard C. Robinson , Robert L. Jacobson , Harris E. Kluksdahl , William A. Blanton , Dennis L. Holtermann , Leslie A. Field
发明人： Richard C. Robinson , Robert L. Jacobson , Harris E. Kluksdahl , William A. Blanton , Dennis L. Holtermann , Leslie A. Field
摘要： A process is disclosed for removing residual sulfur from a hydrotreated naphtha feedstock. The feedstock is contacted with molecular hydrogen under reforming conditions in the presence of a less sulfur sensitive reforming catalyst to convert trace sulfur compounds to H.sub.2 S, and to form a first effluent. The first effluent is contacted with a solid sulfur sorbent to remove the H.sub.2 S and form a second effluent. The second effluent is then contacted with a highly selective reforming catalyst under severe reforming conditions. Also disclosed is a method using a potassium containing sulfur sorbent made from nitrogen-free potassium compounds.
摘要翻译： 公开了从加氢处理的石脑油原料中除去残余硫的方法。 在重硫条件下，在较少硫敏感的重整催化剂的存在下，原料与分子氢接触，以将痕量硫化合物转化为H 2 S，并形成第一流出物。 将第一流出物与固体硫吸附剂接触以除去H 2 S并形成第二流出物。 然后在严格的重整条件下将第二流出物与高度选择性的重整催化剂接触。 还公开了使用由无氮钾化合物制成的含钾硫吸附剂的方法。
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公开(公告)号：US5259946A
公开(公告)日：1993-11-09
申请号：US953192
申请日：1992-09-29
摘要： A process for removing residual sulfur from a hydrotreated naphtha feedstock is disclosed. The feedstock is contacted with molecular hydrogen under reforming conditions in the presence of a less sulfur sensitive reforming catalyst, thereby converting trace sulfur compounds to H.sub.2 S, and forming a first effluent. The first effluent is contacted with a solid sulfur sorbent, removing the H.sub.2 S and forming a second effluent. The second effluent is contacted with a highly selective reforming catalyst under severe reforming conditions.
摘要翻译： 公开了从加氢处理的石脑油原料中除去残余硫的方法。 在重硫条件下，在较少硫敏感的重整催化剂的存在下，原料与分子氢接触，从而将痕量硫化合物转化为H 2 S，并形成第一流出物。 将第一流出物与固体硫吸附剂接触，除去H 2 S并形成第二流出物。 在严格的重整条件下，将第二流出物与高度选择性的重整催化剂接触。
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公开(公告)号：US4204947A
公开(公告)日：1980-05-27
申请号：US915022
申请日：1978-06-12
申请人： Robert L. Jacobson , Kirk R. Gibson
发明人： Robert L. Jacobson , Kirk R. Gibson
CPC分类号： C10G25/003
摘要： Thiol impurities are absorbed and removed from hydrocarbon oils by contacting the oil in the absence of molecular oxygen with a scavenger at a temperature in the range of about 120.degree. to 400.degree. C. The scavenger is a composite having a copper component and an inorganic porous carrier component and having a surface area in the range 20 to 1000 square meters per gram. The contacting must be discontinued when the thiol impurity content of the effluent product exceeds about 0.3 ppm.
摘要翻译： 通过在不存在分子氧的情况下将油与清除剂在约120-400℃的温度下接触，从烃油中吸收和除去硫醇杂质。清除剂是具有铜组分和无机多孔 载体组分，其表面积为每克20至1000平方米。 当流出物的硫醇杂质含量超过0.3ppm时，必须停止接触。
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