Method for preparing a catalyst carrier, a catalyst containing the
carrier, and a hydrocarbon hydrodesulfurization process using the
catalyst
    3.
    发明授权
    Method for preparing a catalyst carrier, a catalyst containing the carrier, and a hydrocarbon hydrodesulfurization process using the catalyst 失效
    制备催化剂载体的方法,含有载体的催化剂和使用该催化剂的烃加氢脱硫方法

    公开(公告)号:US4341625A

    公开(公告)日:1982-07-27

    申请号:US159887

    申请日:1980-06-16

    申请人: Paul W. Tamm

    发明人: Paul W. Tamm

    摘要: A method is provided for preparing a porous catalyst carrier having a pore volume of at least 0.5 cc/g, a content of micropores in which the pore diameter is between 80 and 150 A. which constitutes at least 70% of the pore volume and a content of macropores which constitutes less than 3% of the pore volume. In the method, a powdered solid comprised of predominantly alpha-alumina monohydrate and sized in the range below 500 microns is treated with a particular amount of a monobasic acid. The acid in the resulting mixture is then at least partially neutralized by admixing with a nitrogen base such as aqueous ammonia. The treated and neutralized feed is converted into a catalyst carrier by shaping as desired, drying, and calcining. Further aspects of the invention are a hydrodesulfurization catalyst prepared using the present carrier and a hydrodesulfurization process for metals-contaminated hydrocarbon feeds using the catalyst.

    摘要翻译: 提供了一种制备孔体积为至少0.5cc / g的多孔催化剂载体的方法,孔径为80至150的微孔含量,其构成孔体积的至少70%,和 构成小于孔体积的3%的大孔的含量。 在该方法中,主要由α-氧化铝一水合物组成的粉末状固体,其尺寸在500微米以下,用特定量的一元酸处理。 然后通过与氮碱如氨水混合,将所得混合物中的酸至少部分中和。 经处理和中和的进料通过根据需要成型,干燥和煅烧而转化成催化剂载体。 本发明的其它方面是使用本载体制备的加氢脱硫催化剂和使用该催化剂的金属污染的烃进料的加氢脱硫方法。

    Combustion of pyrolyzed carbon containing solids in staged turbulent bed
    5.
    发明授权
    Combustion of pyrolyzed carbon containing solids in staged turbulent bed 失效
    在分阶段湍流床中热解含碳固体的燃烧

    公开(公告)号:US4336128A

    公开(公告)日:1982-06-22

    申请号:US268938

    申请日:1981-06-01

    申请人: Paul W. Tamm

    发明人: Paul W. Tamm

    IPC分类号: C10G1/02 C10G1/00

    CPC分类号: C10G1/02

    摘要: Process for burning a pyrolyzed carbon containing solid in a staged turbulent bed to provide hot heat transfer material for use in pyrolyzing additional carbon containing solids.

    摘要翻译: 在分阶段湍流床中燃烧含有热解碳的固体以提供用于热解另外含碳固体的热转移材料的方法。

    Hydrocarbon catalytic reforming process
    7.
    发明授权
    Hydrocarbon catalytic reforming process 失效
    烃催化重整过程

    公开(公告)号:US4129497A

    公开(公告)日:1978-12-12

    申请号:US841616

    申请日:1977-10-13

    申请人: Paul W. Tamm

    发明人: Paul W. Tamm

    摘要: A method is provided for preparing a porous catalyst carrier having a pore volume of at least 0.5 cc/g, a content of micropores in which the pore diameter is between 80 and 150 A. which constitutes at least 70% of the pore volume and a content of macropores which constitutes less than 3% of the pore volume. In the method, a powdered solid comprised of predominantly alpha-alumina monohydrate and sized in the range below 500 microns is treated with a particular amount of a monobasic acid. The acid in the resulting mixture is then at least partially neutralized by admixing with a nitrogen base such as aqueous ammonia. The treated and neutralized feed is converted into a novel catalyst carrier by shaping as desired, drying, and calcining. Further aspects of the invention are a catalytic reforming catalyst containing the present carrier and a reforming process using this catalyst.

    摘要翻译: 提供了一种制备孔体积为至少0.5cc / g的多孔催化剂载体的方法,孔径为80至150的微孔含量,其构成孔体积的至少70%,并且 构成小于孔体积的3%的大孔的含量。 在该方法中,主要由α-氧化铝一水合物组成的粉末状固体,其尺寸在500微米以下,用特定量的一元酸处理。 然后通过与氮碱如氨水混合,将所得混合物中的酸至少部分中和。 经处理和中和的进料通过根据需要成型,干燥和煅烧而转化成新的催化剂载体。 本发明的其它方面是含有本载体的催化重整催化剂和使用该催化剂的重整方法。

    Hydrocarbon hydrotreating catalyst composition
    8.
    发明授权
    Hydrocarbon hydrotreating catalyst composition 失效
    油气加氢催化剂组合物

    公开(公告)号:US4066574A

    公开(公告)日:1978-01-03

    申请号:US616334

    申请日:1975-09-24

    申请人: Paul W. Tamm

    发明人: Paul W. Tamm

    摘要: Heavy oil feedstocks containing at least 20 ppm metals, particularly residuum feedstocks, are hydrodesulfurized using a catalyst prepared by impregnating Group VIb and Group VIII metals or metal compounds into a support comprising alumina wherein the support has at least 70 volume percent of its pore volume in pores having a diameter between 80 and 150 Angstroms and less than 3 volume percent of its pore volume in pores having a diameter above 1000 Angstroms. The catalyst preferably has at least 80 volume percent of its pore volume in pores having a diameter between 80 and 150 Angstroms and less than 1.5 volume percent of its pore volume in pores having a diameter above 1000 Angstroms. An especially outstanding hydrodesulfurization catalyst in terms of very low deactivation rate is attained by using an alumina support of the above pore size distribution or the above preferred pore size distribution and wherein the metals are impregnated into the catalyst in a single step impregnation using a solution of a cobalt or nickel salt and a heteropolymolybdic acid such as phosphomolybdic acid.

    摘要翻译: 提供了一种制备孔体积为至少0.5cc / g的多孔催化剂载体的方法,孔径为80至150的微孔含量,其构成孔体积的至少70%,和 构成小于孔体积的3%的大孔的含量。 在该方法中,主要由α-氧化铝一水合物组成的粉末状固体,其尺寸在500微米以下,用特定量的一元酸处理。 然后通过与氮碱如氨水混合,将所得混合物中的酸至少部分中和。 经处理和中和的进料通过根据需要成型,干燥和煅烧而转化为催化剂载体。 本发明的其它方面是使用本载体制备的加氢脱硫催化剂和使用该催化剂的金属污染的烃进料的加氢脱硫方法。

    Multi-stage catalytic reforming with high rhenium content catalyst
    10.
    发明授权
    Multi-stage catalytic reforming with high rhenium content catalyst 失效
    具有高铼含量催化剂的多级催化重整

    公开(公告)号:US4764267A

    公开(公告)日:1988-08-16

    申请号:US115792

    申请日:1987-10-29

    摘要: A multi-stage catalytic reforming process using a catalyst having a high rhenium to platinum ratio in the first stage or stages and a catalyst having a still higher rhenium to platinum ratio for the last stage. The process comprises:(a) contacting a naphtha feed with a first stage catalyst comprising rhenium and platinum, and having a rhenium to platinum weight ratio of at least 1.7, under catalytic reforming conditions in one or more first reforming stages of a reforming unit to obtain intermediate reformate; and(b) contacting the intermediate reformate, under catalytic reforming conditions in a last stage of the reforming unit, with a last stage catalyst comprising rhenium and 0.2 to 2.0 weight percent platinum, and having sufficient rhenium so that the last stage catalyst has at least 0.5 weight percent rhenium beyond that necessary to attain a 1.7 rhenium to platinum weight ratio.

    摘要翻译: 使用在第一阶段或阶段中具有高铼与铂比的催化剂和最后阶段具有更高铼与铂比的催化剂的多阶段催化重整方法。 该方法包括:(a)在重整单元的一个或多个第一重整阶段的催化重整条件下,将石脑油进料与包含铼和铂的第一阶段催化剂并且具有至少1.7的铼与铂的重量比接触, 获得中间重整产品; 和(b)在重整单元的最后阶段的催化重整条件下,将中间重整油与最后阶段的催化剂接触,所述最后阶段的催化剂包含铼和0.2-2.0重量百分比的铂,并且具有足够的铼,使得最后阶段的催化剂至少具有 0.5重量百分比的铼超过获得1.7铼至铂重量比所需的铼。