摘要:
The invention relates to phosphorescent or luminescent conjugated polymers, whose emission is based on the phosphorescence of covalently bonded metal complexes, optionally combined with the fluorescence of the polymer chain. The invention also relates to a method for producing said polymers and to their use in electroluminescent assemblies.
摘要:
The present invention relates to compounds of the general formula (I) wherein Z corresponds a to — a C1-C22-alkyl radical substituted by halogen, phosphonic acid or phosphonic acid ester groups —P(O)(OR1)2 (wherein the radicals R1 can be identical or different and correspond to a hydrogen atom or C1-C12-alkyl), sulphonic acid groups —SO3H, halosilyl radicals —SiHalnR23−n(R2═C1-C18-alkyl, n=an integer from 1 to 3), thiol groups or trialkoxysilyl radicals —Si(OR3)3 (R3═C1-C18-alkyl), — a C5-C12-cycloalkyl radical substituted by halogen, phosphonic acid or phosphonic acid ester groups—P(O) (OR1)2 (wherein the radicals R1 can be identical or different and correspond to a hydrogen atom or C1-C12-alkyl), sulphonic acid groups —SO3H, halosilyl radicals —SiHal−nR23−n(R2═C1-C18-alkyl, n=an integer from 1 to 3), thiol groups or trialkoxysilyl radicals —Si(OR3)3 (R3═C1-C18-alkyl), — a C6-C14-aryl radical or heteroaryl radical from the group of the thienyl, pyrryl, furyl or pyridyl radicals substituted by halogen, phosphonic acid or phosphonic acid ester groups —P(O)(OR1)2 (wherein the radicals R1 can be identical or different and correspond to a hydrogen atom or C1-C12-alkyl), sulphonic acid groups —SO3H, halosilyl radicals —SiHalnR23−n (R2═C1-C18-alkyl, n=an integer from 1 to 3), thiol groups or trialkoxysilyl radicals —Si(OR3)3 (R3═C1-C18-alkyl), or — a C7-C30-aralkyl radical optionally substituted by halogen, phosphonic acid or phosphonic acid ester groups —P(O)(OR1)2 (wherein the radicals R1 can be identical or different and correspond to a hydrogen atom or C1-C12-alkyl), sulphonic acid groups —SO3H, halosilyl radicals —SiHalnR23−n (R2═C1-C18-alkyl, n=an integer from 1 to 3), thiol groups or trialkoxysilyl radicals —Si(OR3)3 (R3═C1-C18-alkyl) or a trialkylsilyl radical R5R6R7Si, in which R5, R6, R7 independently of each other are identical or different C1-C18-alkyl radicals. The present invention also relates to a semiconductor layer, an electronic component, a process for the production of an electronic component, the electronic component obtainable by this process and the use of compounds of the general formula (I).
摘要:
Dye-donor element for use according to thermal dye sublimation transfer comprising a support having on one side a dye layer and on the other side a heat-resistant layer, characterized in that said heat-resistant layer comprises a polyether containing at least 10 mol % recurring units corresponding to the following formula (I)O--E--O--E'-- (I)wherein--O--E--O-- represents a divalent diphenolate radical corresponding to the following general formula (II) ##STR1## wherein R.sub.1 and R.sub.2 (same or different) represent hydrogen, halogen, a C.sub.1 -C.sub.8 alkyl group, a C.sub.5 -C.sub.6 cycloalkyl group, a C.sub.6 -C.sub.10 aryl group or a C.sub.7 -C.sub.12 aralkyl group; andX represents the necessary atoms to close a 5- to 8-membered cycloaliphatic ring which may be substituted with one or more C.sub.1 -C.sub.6 alkyl groups or 5- to 6-membered cycloalkyl groups or carry fused-on 5- or 6-membered cycloalkyl groups;--E'-- represents a divalent radical of an aromatic sulfone corresponding to the following general formula (III) ##STR2## or a divalent radical of a diarylketone corresponding to the following general formula (IV) ##STR3## or a divalent radical of benzonitrile corresponding to the following general formula (V) ##STR4## wherein Ar and Ar' in formula III and IV (same or different) represent difunctional aromatic radicals having 6 to 50 carbon atoms.
摘要:
The present invention relates to a stabilised monomer composition comprising at least 50 wt.-%, based on the total weight of the stabilised monomer composition, of a thiophene derivative monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, and 0.001 to 10 wt.-%, based on the total weight of the stabilised monomer composition, of a stabiliser. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method, the use of a stabilised monomer composition and to the use of a stabiliser.
摘要:
The present invention relates to a stabilized monomer composition comprising at least 50 wt.-%, based on the total weight of the stabilized monomer composition, of a thiophene derivative monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, and 0.001 to 10 wt.-%, based on the total weight of the stabilized monomer composition, of a stabilizer. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method, the use of a stabilized monomer composition and to the use of a stabilizer.
摘要:
The invention relates to formulations comprising polythiophenes A) comprising at least one polythiophene containing recurring units of the general formula (I-a) and/or (I-b) and at least two further polymers, the use thereof and electroluminescent arrangements comprising hole-injecting layers comprising these formulations.
摘要:
The present invention relates to a monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, wherein the monomer has a colour in a range of a Hazen colour number determined according to test method described herein of at least 20, to a Gardner colour number determined according to test method described herein of not more than 5. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method and to the use of a monomer.
摘要:
The invention relates to novel polythiophene-polyanion complexes which are soluble or dispersible in nonpolar organic solvents, and to the use thereof.
摘要:
The invention relates to formulations comprising polythiophenes A) comprising at least one polythiophene containing recurring units of the general formula (I-a) and/or (I-b) and at least two further polymers, the use thereof and electroluminescent arrangements comprising hole-injecting layers comprising these formulations.
摘要:
The invention relates to polysulphone/polyether block copolycondensates having the recurring structural unit as in formula (I)--(--O--E--O--Ar.sup.1 --SO.sub.2 --Ar.sup.2 --)--W-- (I)whereinE is a divalent diphenolate radical andW is a polyether, polythioether or polyacetal possessing at least two hydroxyl groups and having an average molecular weight (M.sub.n) of from 400 to 30,000 andwherein the proportion of the radical W in the total polymer amounts to 5 to 99 wt. %,the preparation and use thereof for the production of moulded shapes, for example, membranes or catheter tubes.
摘要翻译:本发明涉及具有如式(I) - ( - OEO-Ar1-SO2-Ar2 - ) - W-(I)的重复结构单元的聚砜/聚醚嵌段共缩合物,其中E是二价二酚盐基,W是聚醚 具有至少两个羟基并具有400至30,000的平均分子量(+ E,ovs M + EE n)的聚硫醚或聚缩醛,并且其中基团W在总聚合物中的比例为5至99重量% %,其制备和用于生产模塑形状的用途,例如膜或导管。