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1.发明授权公开(公告)号：US06869917B2
公开(公告)日：2005-03-22
申请号：US10222057
申请日：2002-08-16
申请人： Douglas E. Deckman , Mark D. Winemiller , William L. Maxwell , David J. Baillargeon , Norman Yang , Maria Caridad B. Goze
发明人： Douglas E. Deckman , Mark D. Winemiller , William L. Maxwell , David J. Baillargeon , Norman Yang , Maria Caridad B. Goze
IPC分类号： C07C2/20 , C07B61/00 , C07C2/26 , C07C9/22 , C07C11/00 , C10M101/02 , C10M105/04 , C10M107/10 , C10M111/04 , C10M171/02 , C10M177/00 , C10N20/00 , C10N20/02 , C10N30/00 , C10N40/25 , C10N60/02 , C10N70/00
CPC分类号： C10M107/10 , C10M111/04 , C10M171/02 , C10M2205/0285 , C10N2220/022 , C10N2230/02 , C10N2230/08 , C10N2240/10 , C10N2260/02
摘要： The present invention relates to a fully formulated lubicants comprising poly α-olefins (PAOs), prepared from a mixed α-olefin feed, which exhibit superior Noack volatility at low pour points, and methods for preparing the fully formulated lubricants. The fully formulated lubricants include PAOs that include mixtures of 1-decene and 1-dodecene. The PAOs may be prepared by polymerization/oligomerization using an alcohol promoted BF3 in conjunction with a combination of co-catalysts.
摘要翻译： 本发明涉及由混合α-烯烃原料制备的聚α-烯烃（PAO）的完全配制的润滑剂，其在低倾点下表现出优异的Noack挥发性，以及制备完全配制的润滑剂的方法。 完全配制的润滑剂包括包含1-癸烯和1-十二碳烯的混合物的PAO。 PAO可以通过使用醇促进的BF 3与助催化剂的组合的聚合/低聚来制备。
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公开(公告)号：US06949688B2
公开(公告)日：2005-09-27
申请号：US10959544
申请日：2004-10-06
申请人： Maria Caridad B. Goze , Norman Yang
发明人： Maria Caridad B. Goze , Norman Yang
IPC分类号： C10G45/00 , C10G50/00 , C10G50/02 , C10G69/12 , C10M105/04 , C10M107/10 , C10M107/12 , C10M109/02 , C10M111/04 , C10M111/06 , C10M177/00 , C10N20/00 , C10N30/00 , C10N30/02 , C10N40/25 , C10N60/02 , C10N70/00 , C07C2/26
CPC分类号： C10M111/06 , C08F8/04 , C10G50/00 , C10G50/02 , C10G2300/1062 , C10G2300/1088 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M107/10 , C10M107/12 , C10M109/02 , C10M111/04 , C10M2205/0285 , C10N2260/02 , C08F210/14
摘要： The present invention relates to poly α-olefins (PAO's) which exhibit superior Noack volatility at low pour points. Mixtures of 1-decene and 1-dodecene are polymerized using an alcohol promoted BF3 in conjunction with a combination of cocatalysts. The reaction mixture is distilled to remove the unreacted monomeric and dimeric species. The resulting product is then hydrogenated to saturate the oliogomers to provide a hydrogenated product which has a viscosity of 5 cSt. This product is distilled to provide PAO's of varying viscosity grades. The 4 cSt PAO is comprised mostly of trimers and tetramers while the 6 cSt product is comprised of trimers, tetramers, and pentamers.
摘要翻译： 本发明涉及在低倾点下表现出优异的Noack挥发性的聚α-烯烃（PAO）。 使用醇促进的BF 3与助催化剂的组合结合使1-癸烯和1-十二碳烯的混合物聚合。 蒸馏反应混合物以除去未反应的单体和二聚物质。 然后将所得产物氢化以使所述橄榄醇饱和以提供粘度为5cSt的氢化产物。 将该产品蒸馏以提供不同粘度等级的PAO。 4 cSt PAO主要由三聚体和四聚体组成，而6 cSt产品由三聚体，四聚体和五聚体组成。
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公开(公告)号：US06824671B2
公开(公告)日：2004-11-30
申请号：US09860142
申请日：2001-05-17
申请人： Maria Caridad B. Goze , Norman Yang
发明人： Maria Caridad B. Goze , Norman Yang
IPC分类号： C10M15912
CPC分类号： C10M111/06 , C08F8/04 , C10G50/00 , C10G50/02 , C10G2300/1062 , C10G2300/1088 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M107/10 , C10M107/12 , C10M109/02 , C10M111/04 , C10M2205/0285 , C10N2260/02 , C08F210/14
摘要： The present invention relates to poly &agr;-olefins (PAO's) which exhibit superior Noack volatility at low pour points. Mixtures of 1-decene and 1-dodecene are polymerized using an alcohol promoted BF3 in conjunction with a combination of cocatalysts. The reaction mixture is distilled to remove the unreacted monomeric and dimeric species. The resulting product is then hydrogenated to saturate the oliogomers to provide a hydrogenated product which has a viscosity of 5 cSt. This product is distilled to provide PAO's of varying viscosity grades. The 4 cSt PAO is comprised mostly of trimers and tetramers while the 6 cSt product is comprised of trimers, tetramers, and pentamers.
摘要翻译： 本发明涉及在低倾点下表现出优异的Noack挥发性的聚α-烯烃（PAO）。 使用醇促进的BF 3与助催化剂的组合结合使1-癸烯和1-十二碳烯的混合物聚合。 蒸馏反应混合物以除去未反应的单体和二聚物质。 然后将所得产物氢化以使所述橄榄醇饱和以提供粘度为5cSt的氢化产物。 将该产品蒸馏以提供不同粘度等级的PAO。 4 cSt PAO主要由三聚体和四聚体组成，而6 cSt产品由三聚体，四聚体和五聚体组成。
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公开(公告)号：US20110137091A1
公开(公告)日：2011-06-09
申请号：US12941598
申请日：2010-11-08
CPC分类号： C07C2/34 , C07C2/22 , C07C2527/1213 , C07C2527/125 , C07C2527/126 , C07C2531/22 , C08C19/24 , C08F10/14 , C08F110/14 , C10M107/10 , C10M2203/1006 , C10M2203/1025 , C10M2205/0285 , C10M2207/2805 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2230/74 , C10N2240/10 , C07C11/02 , C08F4/12 , C08F2500/02 , C10N2260/02 , C08F4/14
摘要： In oligomerizing alpha-olefins to produce poly alpha-olefins, the feedstock consists of nonene, or a blend of alpha-olefins comprising nonene. The nonene comprising alpha-olefin feedstock and at least one catalyst are subjected to oligomerization or polymerization conditions in a reactor. Following reaction, the mixture may be subjected to distillations to removed unreacted alpha-olefins and dimers of the alpha-olefins. The resulting product may also be hydrogenated. The final product may also be fractioned to recover at least two fractions of poly alpha-olefins of differing nominal viscosities.
摘要翻译： 在低聚α-烯烃以制备聚α-烯烃时，原料由壬烯或包含壬烯的α-烯烃的共混物组成。 包含α-烯烃原料和至少一种催化剂的壬烯在反应器中进行低聚或聚合条件。 反应后，可将混合物进行蒸馏以除去α-烯烃的未反应的α-烯烃和二聚体。 所得产物也可以被氢化。 最终产物也可以分馏以回收至少两个具有不同标称粘度的聚α-烯烃馏分。
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公开(公告)号：US07652093B2
公开(公告)日：2010-01-26
申请号：US11406926
申请日：2006-04-19
申请人： Henry Wu-Hsiang Yang , Wen Li , Bruce R. Lundmark , Chon-Yie Lin , Chia Yung Cheng , Bryan R. Chapman , Petra Eiselt , Galina Ourieva , Manika Varma-Nair , James N. Coffey , Sandra Denise Schregenberger , David J. Lohse , Norman Yang , Jeffrey Theodore Zudock , Robert Jay Wittenbrink
发明人： Henry Wu-Hsiang Yang , Wen Li , Bruce R. Lundmark , Chon-Yie Lin , Chia Yung Cheng , Bryan R. Chapman , Petra Eiselt , Galina Ourieva , Manika Varma-Nair , James N. Coffey , Sandra Denise Schregenberger , David J. Lohse , Norman Yang , Jeffrey Theodore Zudock , Robert Jay Wittenbrink
CPC分类号： C08L23/10 , C08K5/0016 , C08K5/01 , C08L23/0815 , C08L23/12 , C08L23/16 , C08L23/18 , C08L23/20 , C08L23/22 , C08L57/00 , C08L91/00 , C08L2205/03 , C08L2314/06 , Y10T442/30 , Y10T442/60 , C08L53/00 , C08L2666/02 , C08L2666/06 , C08L2666/04
摘要： The present invention relates to plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.
摘要翻译： 本发明涉及包含聚烯烃和非官能化烃增塑剂的增塑聚烯烃组合物。
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公开(公告)号：US07619026B2
公开(公告)日：2009-11-17
申请号：US10640435
申请日：2003-08-12
申请人： Henry Wu-Hsiang Yang , Wen Li , Bruce R. Lundmark , Chon-Yie Lin , Chia Yung Cheng , Bryan R. Chapman , Petra Eiselt , Galina Ourieva , Manika Varma-Nair , James N. Coffey , Sandra Denise Schregenberger , David J. Lohse , Norman Yang , Jeffrey Theodore Zudock , Robert Jay Wittenbrink
发明人： Henry Wu-Hsiang Yang , Wen Li , Bruce R. Lundmark , Chon-Yie Lin , Chia Yung Cheng , Bryan R. Chapman , Petra Eiselt , Galina Ourieva , Manika Varma-Nair , James N. Coffey , Sandra Denise Schregenberger , David J. Lohse , Norman Yang , Jeffrey Theodore Zudock , Robert Jay Wittenbrink
CPC分类号： C08L23/10 , C08K5/0016 , C08K5/01 , C08L23/0815 , C08L23/12 , C08L23/16 , C08L23/18 , C08L23/20 , C08L23/22 , C08L57/00 , C08L91/00 , C08L2205/03 , C08L2314/06 , Y10T442/30 , Y10T442/60 , C08L53/00 , C08L2666/02 , C08L2666/06 , C08L2666/04
摘要： The present invention relates to plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.
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公开(公告)号：US07592497B2
公开(公告)日：2009-09-22
申请号：US11389613
申请日：2006-03-24
IPC分类号： C07C2/08
CPC分类号： C10G69/126 , C10G50/02 , C10M107/10 , C10M2205/0285 , C10N2220/022 , C10N2230/02 , C10N2230/74
摘要： The invention relates to a method of making a PAO from mixtures comprising 1-decene and 1-dodecene, characterized by a low viscosity and excellent cold temperature properties, using a promoter system comprising an alcohol. In embodiments, the product has properties similar to those obtainable using a feed of solely 1-decene.
摘要翻译： 本发明涉及一种由包含1-癸烯和1-十二碳烯的混合物制备PAO的方法，其特征在于使用包含醇的助催化剂体系，具有低粘度和优异的冷温度特性。 在实施方案中，产品具有与仅使用1-癸烯的进料可获得的那些相似的性质。
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公开(公告)号：US20070225535A1
公开(公告)日：2007-09-27
申请号：US11389613
申请日：2006-03-24
申请人： Norman Yang , Pramod Nandapurkar
发明人： Norman Yang , Pramod Nandapurkar
CPC分类号： C10G69/126 , C10G50/02 , C10M107/10 , C10M2205/0285 , C10N2220/022 , C10N2230/02 , C10N2230/74
摘要： The invention relates to a method of making a PAO from mixtures comprising 1-decene and 1-dodecene, characterized by a low viscosity and excellent cold temperature properties, using a promoter system comprising an alcohol. In embodiments, the product has properties similar to those obtainable using a feed of solely 1-decene.
摘要翻译： 本发明涉及一种由包含1-癸烯和1-十二碳烯的混合物制备PAO的方法，其特征在于使用包含醇的助催化剂体系，具有低粘度和优异的冷温度特性。 在实施方案中，产品具有与仅使用1-癸烯的进料可获得的那些相似的性质。
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公开(公告)号：US20070225534A1
公开(公告)日：2007-09-27
申请号：US11388347
申请日：2006-03-24
申请人： Maria Goze , Pramod Nandapurkar , Norman Yang
发明人： Maria Goze , Pramod Nandapurkar , Norman Yang
CPC分类号： C10G50/02
摘要： Disclosed herein is a method of making a PAO using tetradecene and particularly mixtures comprising 1-hexene, 1-decene, 1-dodecene, and 1-tetradecene, characterized by a low viscosity and excellent cold temperature properties, using a promoter system comprising an alcohol and an ester. In embodiments, the product has properties similar to those obtainable using a feed of solely 1-decene.
摘要翻译： 本文公开了使用十四碳烯，特别是包含1-己烯，1-癸烯，1-十二碳烯和1-十四碳烯的混合物制备PAO的方法，其特征在于低粘度和优异的冷温度性质，使用包含醇的助催化剂体系 和酯。 在实施方案中，产品具有与仅使用1-癸烯的进料可获得的那些相似的性质。
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公开(公告)号：US20060161034A1
公开(公告)日：2006-07-20
申请号：US11036904
申请日：2005-01-14
申请人： Phil Surana , Norman Yang , Pramod Nandapurkar
发明人： Phil Surana , Norman Yang , Pramod Nandapurkar
CPC分类号： C10G50/00 , C07C2/22 , C07C2527/126 , C08F210/14 , C10G2300/1088 , C10G2300/302 , C10G2300/304 , C10G2300/802 , C10G2400/10 , C10M107/10 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C07C11/02 , C08F2500/17 , C08F2500/02
摘要： This invention relates to the use of 1-decene/1-dodecene olefin mixture to produce high viscosity polyalphaolefins (PAOs) having a viscosity of from about 40 cSt to about 100 cSt at 100° C. (ASTM D-445) and a number average molecular weight of between about 1200 to about 4000, particularly useful as lubricant base stocks.
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