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公开(公告)号:US20090158896A1
公开(公告)日:2009-06-25
申请号:US12087632
申请日:2007-01-26
申请人: Duilio Rossoni , Reinhold Klipper , Bruno Hees , Rudolf Wagner , Stefan Neumann , Olaf Halle , Wolfgang Podszun , Michael Schelhaas
发明人: Duilio Rossoni , Reinhold Klipper , Bruno Hees , Rudolf Wagner , Stefan Neumann , Olaf Halle , Wolfgang Podszun , Michael Schelhaas
CPC分类号: C22B3/42 , B01J45/00 , C22B3/24 , C22B23/0453 , Y02P10/234
摘要: The present invention relates to the use of monodisperse, macroporous chelating resins in the recovery of metals in hydrometallurgical processes, in particular in resin-in-pulp processes.
摘要翻译: 本发明涉及单分散大孔螯合树脂在湿法冶金方法中回收金属的用途,特别是在树脂 - 纸浆法中。
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公开(公告)号:US20100307979A1
公开(公告)日:2010-12-09
申请号:US12669969
申请日:2008-07-10
CPC分类号: C08F12/36 , B01D15/00 , B01D53/02 , B01D53/64 , B01D2251/90 , B01J13/10 , B01J20/26 , B01J20/261 , B01J20/265 , B01J41/14 , B01J45/00 , C02F1/42 , C02F1/683 , C02F2101/20 , C08F8/30 , C08F8/44 , C08F2800/20 , C22B3/42 , C22B7/006 , Y02P10/234 , C08F212/08
摘要: The present application relates to novel chelate resins which contain, as a functional group, quaternary nitrogen atoms in structures of the general formula (I) in which at least one of the radicals R1 to R3 represents an optionally substituted radical of the series consisting of picolyl, methylquinoline or methylpiperidine, m represents an integer from 1 to 4 and M represents the polymer matrix and X represents a counterion of the series consisting of hydroxide OH−, halide, preferably Cl−, Br−, or sulphate SO42−, a process for their preparation and the use thereof, in particular the use of the novel chelate resins in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及新的螯合树脂,其中含有作为官能团的通式(I)结构中的季氮原子,其中基团R 1至R 3中的至少一个表示任选取代的由吡啶甲基 ,甲基喹啉或甲基哌啶,m表示1至4的整数,M表示聚合物基体,X表示由氢氧化物OH-,卤化物,优选Cl-,Br-或硫酸盐SO 4 2-组成的系列的抗衡离子, 其制备及其用途,特别是新型螯合树脂在湿法冶金和电镀中的应用。
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公开(公告)号:US20110086935A1
公开(公告)日:2011-04-14
申请号:US12919851
申请日:2009-02-27
IPC分类号: C08F8/32
CPC分类号: C08F8/30 , B01J45/00 , C01G3/003 , C02F1/285 , C02F2101/20 , C02F2101/203 , C08F8/02 , C08F8/44 , C22B3/42 , C22B15/0089 , Y02P10/234 , Y02P10/236 , C08F212/08
摘要: The present application relates to novel monodisperse, gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is a radical —(CH2)q—COOR3, R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2, q is an integer from 1 to 5 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式结构中含有叔氮原子的新型单分散,凝胶型或大孔吡甲基胺树脂 (I)作为官能团,其中R 1是由吡啶甲基,甲基喹啉和甲基哌啶组成的组中的任选取代的基团,R 2是 - (CH 2)q -COOR 3基团,R 3是由H,Na和 K,m为1〜4的整数,n和p各自独立地为0.1〜1.9的数,n与p的和为2,q为1〜5的整数, M是聚合物基质,其制备方法及其用途,特别是在湿法冶金和电镀中的应用。
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公开(公告)号:US08563622B2
公开(公告)日:2013-10-22
申请号:US12919851
申请日:2009-02-27
CPC分类号: C08F8/30 , B01J45/00 , C01G3/003 , C02F1/285 , C02F2101/20 , C02F2101/203 , C08F8/02 , C08F8/44 , C22B3/42 , C22B15/0089 , Y02P10/234 , Y02P10/236 , C08F212/08
摘要: The present application relates to novel monodisperse, gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is a radical —(CH2)q—COOR3, R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2, q is an integer from 1 to 5 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式结构中含有叔氮原子的新型单分散,凝胶型或大孔吡甲基胺树脂 (I)作为官能团,其中R 1是由吡啶甲基,甲基喹啉和甲基哌啶组成的组中的任选取代的基团,R 2是 - (CH 2)q -COOR 3基团,R 3是由H,Na和 K,m为1〜4的整数,n和p各自独立地为0.1〜1.9的数,n与p的和为2,q为1〜5的整数, M是聚合物基质,其制备方法及其用途,特别是在湿法冶金和电镀中的应用。
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公开(公告)号:US20110091365A1
公开(公告)日:2011-04-21
申请号:US12919846
申请日:2009-02-27
IPC分类号: C08F212/08 , C01G13/00 , C01G49/00 , C01G3/00 , C01G9/00 , C01G21/00 , C01G11/00 , C01G45/00 , C01G56/00 , C01G31/00 , C01G55/00 , C01G51/00 , C01G53/00 , C01G5/00 , C01G7/00
CPC分类号: C22B3/42 , B01J45/00 , C08F8/30 , C08F8/34 , C08F8/40 , C08F8/44 , C22B11/04 , C22B23/00 , Y02P10/234 , C08F212/08
摘要: The present application relates to novel gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is —CH2—S—CH2COOR3 or —CH2—S—C1-C4-alkyl or —CH2—S—CH2CH(NH2)COOR3 or —CH2—S—CH2—CH(OH)—CH2(OH) or or derivatives thereof or —C═S(NH2), R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式(I)的结构中含有叔氮原子的新型凝胶型或大孔吡甲基胺树脂 )作为官能团,其中R 1是由吡啶基,甲基喹啉和甲基哌啶组成的组中的任意取代的基团,R 2是-CH 2 -S-CH 2 COOR 3或-CH 2 -S-C 1 -C 4烷基或-CH 2 -S-CH 2 CH( NH 2)COOR 3或-CH 2 -S-CH 2 -CH(OH)-CH 2(OH)或其衍生物或-C≡S(NH 2),R 3是由H,Na和K组成的组中的基团,m是 1〜4的整数,n和p各自独立地为0.1〜1.9的数,n和p的和为2,M为聚合物基质,其制备方法及其制备方法 尤其用于湿法冶金和电镀。
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公开(公告)号:US08562922B2
公开(公告)日:2013-10-22
申请号:US12919846
申请日:2009-02-27
CPC分类号: C22B3/42 , B01J45/00 , C08F8/30 , C08F8/34 , C08F8/40 , C08F8/44 , C22B11/04 , C22B23/00 , Y02P10/234 , C08F212/08
摘要: The present application relates to novel gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is —CH2—S—CH2COOR3 or —CH2—S—C1-C4-alkyl or —CH2—S—CH2CH(NH2)COOR3 or —CH2—S—CH2—CH(OH)—CH2(OH) or or derivatives thereof or —C═S(NH2), R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.
摘要翻译: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式(I)的结构中含有叔氮原子的新型凝胶型或大孔吡甲基胺树脂 )作为官能团,其中R 1是由吡啶基,甲基喹啉和甲基哌啶组成的组中的任意取代的基团,R 2是-CH 2 -S-CH 2 COOR 3或-CH 2 -S-C 1 -C 4烷基或-CH 2 -S-CH 2 CH( NH 2)COOR 3或-CH 2 -S-CH 2 -CH(OH)-CH 2(OH)或其衍生物或-C = S(NH 2),R 3是由H,Na和K组成的组的基团,m是 1〜4的整数,n和p各自独立地为0.1〜1.9的数,n和p的和为2,M为聚合物基质,其制备方法及其制备方法 尤其用于湿法冶金和电镀。
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公开(公告)号:US20090022638A1
公开(公告)日:2009-01-22
申请号:US11879814
申请日:2007-07-19
CPC分类号: C22B3/42 , B01J41/04 , B01J41/05 , B01J47/014 , C22B60/0265 , Y02P10/234
摘要: The present invention relates to the use of monodisperse, macroporous anion exchangers of type I or type II in hydrometallurgical processes for winning metals of value.
摘要翻译: 本发明涉及在湿法冶金工艺中使用I型或II型单分散大孔阴离子交换剂来获得有价值的金属。
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