公开(公告)号：US20150110710A1

公开(公告)日：2015-04-23

申请号：US14396397

申请日：2013-03-29

申请人： E I DU PONT DE NEMOURS AND COMPANY

发明人： Timothy Allan Bell ,  David Richard Corbin ,  Scott Hutchison ,  Eugene Michael Mccarron, III ,  Thomas G. Calvarese

IPC分类号： C01G23/08 ,  C09C1/36

CPC分类号： C01G23/08 ,  C01P2006/10 ,  C01P2006/12 ,  C01P2006/19 ,  C09C1/36 ,  C09C1/3653 ,  C09C1/3669

摘要： The present invention relates to a process for manufacturing low-dusting, smoothly-discharging, easily dispersible, powders such as pigmentary titanium dioxide that resist compaction, aging, lumping, and/or caking. Particularly, the present invention relates to a process for treating powders such as pigmentary titanium dioxide with ammonia or a similarly basic substance prior to or during agglomeration to produce a powder with improved bulk handling properties.

摘要翻译： 本发明涉及一种制造低粉尘，平滑排放，容易分散的粉末的方法，例如可以压实，老化，结块和/或结块的颜料二氧化钛。 特别地，本发明涉及一种在凝聚之前或期间用氨或类似碱性物质处理粉末的颜料二氧化钛的方法，以产生具有改进的散装处理性能的粉末。

公开(公告)号：US20130303363A1

公开(公告)日：2013-11-14

申请号：US13942768

申请日：2013-07-16

申请人： E I Du Pont De Nemours and Company

发明人： PAUL JOSEPH FAGAN ,  Thomas G. Calvarese ,  Ronald James Davis ,  Ronnie Ozer

IPC分类号： B01J27/182 ,  B01J27/18 ,  B01J27/185 ,  C07C29/34

CPC分类号： B01J27/182 ,  B01J27/1806 ,  B01J27/1853 ,  B01J27/186 ,  B01J27/198 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  C07C29/34 ,  C07C31/12

摘要： Catalytic processes to produce a reaction product comprising 1-butanol by contacting a reactant comprising ethanol with a catalyst composition under suitable reaction conditions are provided. The catalyst to composition may comprise a hydroxyapatite of the Formula (MwM′xM′yM′″z)5(PO4)3(OH), wherein M is Mg; M′ is Ca; M″ is Sr; M′″ is Ba; w is any number between 0 and 1 inclusive; x is any number from 0 to less than 0.5; y is any number between 0 and 1 inclusive; z is any number between 0 and 1 inclusive; and w+x+y+z=1. Base-treated catalyst compositions may be used. Also provided are processes for contacting an initial catalyst composition comprising the hydroxyapatite with a base to produce a base-treated catalyst composition, and the base-treated catalyst compositions so obtained.

摘要翻译： 提供了在合适的反应条件下通过使包含乙醇的反应物与催化剂组合物接触来生产包含1-丁醇的反应产物的催化方法。 组成的催化剂可以包含式（MwM'xM'yM“z）5（PO4）3（OH）的羟基磷灰石，其中M是Mg; M'是Ca; M“是Sr; M“”是Ba; w是0和1之间的任何数字; x是从0到小于0.5的任何数字; y是0和1之间的任何数字; z是0和1之间的任何数字; 并且w + x + y + z = 1。 可以使用碱处理的催化剂组合物。 还提供了使包含羟基磷灰石的初始催化剂组合物与碱反应以制备碱处理的催化剂组合物的方法，以及如此获得的碱处理的催化剂组合物。

公开(公告)号：US20130303362A1

公开(公告)日：2013-11-14

申请号：US13942759

申请日：2013-07-16

申请人： E I Du Pont De Nemours and Company

发明人： Paul Joseph Fagan ,  Thomas G. Calvarese ,  Ronald James Davis ,  Ronnie Ozer

IPC分类号： B01J27/182 ,  B01J27/18 ,  C07C29/34

CPC分类号： B01J27/182 ,  B01J27/1806 ,  B01J27/1853 ,  B01J27/186 ,  B01J27/198 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  C07C29/34 ,  C07C31/12

摘要： Catalytic processes to produce a reaction product comprising 1-butanol by contacting a reactant comprising ethanol with a catalyst composition under suitable reaction conditions are provided. The catalyst composition may comprise a hydroxyapatite of the Formula (MwM′xM″yM′″z)5(PO4)3(OH), wherein M is Mg; M′ is Ca; M″ is Sr; M′″ is Ba; w is any number between 0 and 1 inclusive; x is any number from 0 to less than 0.5; y is any number between 0 and 1 inclusive; z is any number between 0 and 1 inclusive; and w+x+y+z=1. Base-treated catalyst compositions may be used. Also provided are processes for contacting an initial catalyst composition comprising the hydroxyapatite with a base to produce a base-treated catalyst composition, and the base-treated catalyst compositions so obtained.

摘要翻译： 提供了在合适的反应条件下通过使包含乙醇的反应物与催化剂组合物接触来生产包含1-丁醇的反应产物的催化方法。 催化剂组合物可以包含式（MwM'xM'yM“z）5（PO4）3（OH）的羟基磷灰石，其中M是Mg; M'是Ca; M“是Sr; M“”是Ba; w是0和1之间的任何数字; x是从0到小于0.5的任何数字; y是0和1之间的任何数字; z是0和1之间的任何数字; 并且w + x + y + z = 1。 可以使用碱处理的催化剂组合物。 还提供了使包含羟基磷灰石的初始催化剂组合物与碱反应以制备碱处理的催化剂组合物的方法，以及如此获得的碱处理的催化剂组合物。